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The insulator-metal transition, accompanying the structural phase transition from 2H to 1T$^\prime$ structure, has been reported in two-dimensional W-S-Te and W-Se-Te systems. It is also reported that Te atoms tend to occupy a specific site…

Materials Science · Physics 2026-01-28 Shota Ono , Ryotaro Ohse

There has been considerable interest in chalcogenide alloys with high concentrations of native vacancies that lead to properties desirable for thermoelectric and phase-change materials. Recently, vacancy ordering has been identified as the…

Materials Science · Physics 2015-06-18 Najeb Abdul-Jabbar , Peter Ercius , Ronald Gronsky , Edith Bourret-Courchesne , Brian Wirth

Despite the rapid pace of computationally and experimentally discovering new two-dimensional layered materials, a general criteria for a given compound to prefer a layered structure over a non-layered one remains unclear. Articulating such…

Materials Science · Physics 2023-07-25 Roberto Prado-Rivera , Daniela Radu , Vincent H. Crespi , Yuanxi Wang

High entropy metal nitrides are an important material class in a variety of applications, and the role of nitrogen vacancies is of great importance for understanding their stability and mechanical properties. We study six different high…

Materials Science · Physics 2026-01-05 Charith R. DeSilva , Matthew D. Witman , Dallas R. Trinkle

Two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, possess unique physical and chemical properties, enabling diverse applications in fields ranging from energy storage to communication, catalysis, sensing,…

Impurities play an important role during recombination processes in semiconductors. Their important role is sharpened in atomically-thin transition-metal dichalcogenides whose two-dimensional character renders electrons and holes highly…

Mesoscale and Nanoscale Physics · Physics 2019-04-11 Dinh Van Tuan , Hanan Dery

Chalcogen vacancies in monolayer transition metal dichalcogenides (TMDs), such as WS$_{2}$, play a crucial role in various applications ranging from optoelectronics and catalysis to quantum information science (QIS), making their…

Hyperuniform many-body systems in $d$-dimensional Euclidean space are characterized by completely suppressed (normalized) infinite-wavelength density fluctuations, and appear to be endowed with novel exotic physical properties. In this…

Soft Condensed Matter · Physics 2021-06-09 Duyu Chen , Yu Zheng , Chia-Hao Lee , Sangmin Kang , Wenjuan Zhu , Houlong Zhuang , Pinshane Y. Huang , Yang Jiao

Increasing demands for renewable sources of energy has been a major driving force for developing efficient thermoelectric materials. Two-dimensional (2D) transition-metal dichalcogenides (TMDC) have emerged as promising candidates for…

Materials Science · Physics 2023-05-24 Sathwik Bharadwaj , Ashwin Ramasubramaniam , L. R. Ram-Mohan

Single- and few-layer transition metal dichalcogenides have recently emerged as a new family of layered crystals with great interest, not only from the fundamental point of view, but also because of their potential application in ultrathin…

Materials Science · Physics 2014-10-14 R. Roldán , J. A. Silva-Guillén , M. P. López-Sancho , F. Guinea , E. Cappelluti , P. Ordejón

Two-dimensional (2D) materials, such as transition metal dichalcogenides (TMDCs) in the 2H or 1T crystal phases, are promising (electro)catalyst candidates due to their high surface to volume ratio and composition of low-cost, abundant…

Materials Science · Physics 2025-02-11 Mohammad Amin Akhound , Karsten Wedel Jacobsen , Kristian Sommer Thygesen

Defect engineering in two-dimensional semiconductors has been exploited to tune the optoelectronic properties and introduce new quantum states in the band gap. Chalcogen vacancies in transition metal dichalcogenides in particular have been…

Two-dimensional (2D) semiconducting transition metal dichalcogenides such as MoS$_2$ have attracted extensive research interests for potential applications in optoelectronics, spintronics, photovoltaics, and catalysis. To harness the…

Materials Science · Physics 2020-07-01 Anne Marie Z. Tan , Christoph Freysoldt , Richard G. Hennig

Layered inorganic materials, such as the transition metal dichalcogenides (TMDs), have attracted much attention due to their exceptional electronic and optical properties. Reliable synthesis and characterization of these materials must be…

Materials Science · Physics 2016-02-08 Maria OBrien , Niall McEvoy , Damien Hanlon , Toby Hallam , Jonathan N. Coleman , Georg S. Duesberg

We explore the direct to indirect band gap transitions in MX$_2$ (M= Mo/W, X= S/Se) transition metal dichalcogenides heterobilayers for different system compositions, strains, and twist angles based on first principles density functional…

Assessing atomic defect states and their ramifications on the electronic properties of two dimensional van der Waals semiconducting transition metal dichalcogenides (SC TMDs) is the primary task to expedite multi disciplinary efforts in the…

The two-dimensional character and reduced screening in monolayer transition-metal dichalcogenides (TMDs) lead to the ubiquitous formation of robust excitons with binding energies orders of magnitude larger than in bulk semiconductors.…

Materials Science · Physics 2017-09-26 Benedikt Scharf , Gaofeng Xu , Alex Matos-Abiague , Igor Žutić

Semiconducting transition metal dichalcogenides (TMDs), such as MoSe$_2$ and WSe$_2$, exhibit unique optical and electronic properties. Vertical stacking of layers of one or more TMDs, to create heterostructures, has expanded the fields of…

Transition metal dichalcogenide monolayers provide an emerging material system to implement quantum photonics with intrinsic two-dimensional excitons or embedded zero-dimensional localized states. Here we demonstrate the mesoscopic…

The properties of two-dimensional (2D) materials have been extensively studied and applied in various applications. Our interest is to theoretically investigate the thermal transport and thermoelectric properties of the 2D transition metal…

Materials Science · Physics 2024-02-16 Radityo Wisesa , Anugrah Azhar , Edi Suprayoga