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Metal organic frameworks (MOFs) are promising photocatalytic materials due to their high surface area and tuneability of their electronic structure. We discuss here how to engineer the band structures and optical properties of a family of…

Search for a new quantum state of matter emerging in a crystal is one of recent trends in condensed matter physics. For magnetic materials, geometrical frustration and high magnetic field are two key ingredients to realize it: a…

Strongly Correlated Electrons · Physics 2019-03-19 R. Okuma , D. Nakamura , T. Okubo , A. Miyake , A. Matsuo , K. Kindo , M. Tokunaga , N. Kawashima , S. Takeyama , Z. Hiroi

Electrocatalytic CO2 reduction technology is key to mitigating greenhouse gas emissions and the energy crisis. However, controlling the selectivity of CO2RR products at low overpotential remains a challenge. In this paper, we predicted five…

Materials Science · Physics 2024-03-05 Ran Wang , Chaozheng He , Weixing Chen , Qingquan Kong , Thomas Frauenheimac

Anisotropic magnetic properties of a layered kagome-like system Cu3Bi(SeO3)2O2Br have been studied by bulk magnetization and magnetic susceptibility measurements as well as powder and single-crystal neutron diffraction. At T_N = 27.4 K the…

Strongly Correlated Electrons · Physics 2012-10-16 M. Pregelj , O. Zaharko , A. Günther , A. Loidl , V. Tsurkan , S. Guerrero

The kagome Hubbard model (KHM) is a paradigmatic example of a frustrated two-dimensional model. While its strongly correlated regime, described by a Heisenberg model, is of topical interest due to its enigmatic prospective spin-liquid…

Strongly Correlated Electrons · Physics 2021-11-04 Josef Kaufmann , Klaus Steiner , Richard T. Scalettar , Karsten Held , Oleg Janson

Altermagnetism has recently emerged as a new class of spin compensated magnetic materials that exhibit momentum dependent spin splitting despite having zero net magnetization. The origin of these electronic signatures lies in symmetry…

Materials Science · Physics 2026-03-06 Diego López-Alcalá , Andrei Shumilin , José J. Baldoví

We investigate the existence of linear magnetism in the metal organic framework materials MOF-74-Fe, MOF-74-Co, and MOF-74-Ni, using first-principles density functional theory. MOF-74 displays regular quasi-linear chains of open-shell…

Materials Science · Physics 2013-03-08 Pieremanuele Canepa , Yves J. Chabal , T. Thonhauser

In this work we analyze the magnetization properties of an antiferromagnetic Kagom\'e stripe lattice, motivated by the recent synthesis of materials exhibiting this structure. By employing a variety of techniques that include numerical…

Strongly Correlated Electrons · Physics 2020-09-10 S. Acevedo , C. A. Lamas , M. Arlego , P. Pujol

Strongly interacting electrons in layered materials give rise to a plethora of emergent phenomena, such as unconventional superconductivity. heavy fermions, and spin textures with non-trivial topology. Similar effects can also be observed…

Mesoscale and Nanoscale Physics · Physics 2022-08-23 Soroush Arabi , Taner Esat , Aizhan Sabitova , Yuqi Wang , Hovan Lee , Cedric Weber , Klaus Kern , F. Stefan Tautz , Ruslan Temirov , Markus Ternes

We report on the successful on-surface synthesis of metal-organic covalent coordination networks with a dense Kagome lattice of metallic centers. In the case of Mn centers ab-initio calculations show that the adsorbed monolayer on Ag(111)…

Electronic flat band systems are a fertile platform to host correlation-induced quantum phenomena such as unconventional superconductivity, magnetism and topological orders. While flat band has been established in geometrically frustrated…

A recently discovered kagome antiferromagnet $\rm{Y}_3\rm{Cu}_9(\rm{OH})_{19}\rm{Cl}_8$ has attracted significant interest due to its unique kagome lattice structure and magnetic properties. The kagome lattice has three types of exchange…

Strongly Correlated Electrons · Physics 2024-09-27 Kazu Bodaiji , Katsuhiro Morita , Yoshiyuki Fukumoto

The discovery of a charge density wave in FeGe extends the discussion of the nature of charge order in kagome metals to a magnetic compound. Motivated by this observation, we combine density functional theory (DFT) and…

Strongly Correlated Electrons · Physics 2024-11-19 Pietro M. Bonetti , Yi Jiang , Haoyu Hu , Dumitru Călugăru , Michael M. Scherer , B. Andrei Bernevig , Laura Classen

Spin-1/2 magnets with kagome geometry, being for years a generic object of theoretical investigations, have few real material realizations. Recently, a DFT-based microscopic model for two such materials, kapellasite Cu3Zn(OH)6Cl2 and…

Strongly Correlated Electrons · Physics 2009-02-17 O. Janson , J. Richter , H. Rosner

The competition between interactions in frustrated magnets allows a wide variety of new ground states, often exhibiting emergent physics and unique excitations. Expanding the suite of lattices available for study enhances our chances of…

Strongly Correlated Electrons · Physics 2017-01-24 Darren C. Peets , Hasung Sim , Seongil Choi , Maxim Avdeev , Seongsu Lee , Su Jae Kim , Hoju Kang , Docheon Ahn , Je-Geun Park

Achieving large-area uniform two-dimensional (2D) metal-organic frameworks (MOFs) and controlling their electronic properties on inert surfaces is a big step towards future applications in electronic devices. Here we successfully fabricated…

We investigate the cooperative behavior of regular monolayers of driven two-level dipoles, using classical electrodynamics simulations. The dipolar response results from the interference of many cooperative eigenmodes, each…

Atomic Physics · Physics 2015-12-17 Robert J. Bettles , Simon A. Gardiner , Charles S. Adams

In metal-organic-framework (MOF) perovskites, both magnetic and ferroelectric orderings can be readily realized by compounding spin and charge degrees of freedom. The hydrogen bonds that bridge the magnetic framework and organic molecules…

The formation of two-dimensional metal-organic frameworks (MOFs) on an inert surface of a topological insulator (TI) is a pathway to engineer quantum materials with exotic properties. MOFs featuring ferromagnetically coupled metal atoms are…

Recently, the superconductivity in a metal-organic framework (MOF) has been discovered for the first time in copper(II) benzenehexathiolate ([Cu$_3$(C$_6$S$_6$)]$_n$, Cu-BHT). The Cu atoms form a two-dimensional perfect Kagome lattice,…

Superconductivity · Physics 2020-09-21 T. Takenaka , K. Ishihara , Y. Miao , X. Huang , W. Xu , D. Zhu , N. Su , J. -G. Cheng , T. Shibauchi