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The interactions between electrons and lattice vibrational modes play the key role in determining the carrier transport properties, thermoelectric performance and other physical quantities related to phonons in semiconductors. However, for…

The lattice thermal conductivity of the candidate thermoelectric material Mg$_3$Sb$_2$ is studied from first principles, with the inclusion of anharmonic, isotope, and boundary scattering processes, and via an accurate solution of the…

Materials Science · Physics 2018-12-11 Maria Barbara Maccioni , Roberta Farris , Vincenzo Fiorentini

We perform an ab initio computational investigation of the electronic and thermoelectric transport properties of one of the best performance half-Heusler (HH) alloys, NbFeSb. We use Boltzmann Transport equation while taking into account the…

Materials Science · Physics 2025-10-28 Bhawna Sahni , Yao Zhao , Zhen Li , Rajeev Dutt , Patrizio Graziosi , Neophytos Neophytou

The temperature-dependent phonons are a generalization of interatomic force constants varying in T, which as found widespread use in computing the thermal transport of materials. A formal justification for using this combination to access…

Materials Science · Physics 2025-01-31 Aloïs Castellano , J. P. Alvarinhas Batista , Olle Hellman , Matthieu J. Verstraete

Understanding heat transport in semiconductors and insulators is of fundamental importance because of its technological impact in electronics and renewable energy harvesting and conversion. Anharmonic Lattice Dynamics provides a powerful…

Materials Science · Physics 2020-10-13 Giuseppe Barbalinardo , Zekun Chen , Nicholas W. Lundgren , Davide Donadio

Point defects exist widely in engineering materials and are known to scatter vibrational modes to reduce thermal conductivity. The Klemens description of point defect scattering is the most prolific analytical model for this effect. This…

Materials Science · Physics 2020-03-11 Ramya Gurunathan , Riley Hanus , Maxwell Dylla , Ankita Katre , G. Jeffrey Snyder

High-performance thermoelectric (TE) materials are crucial for efficient waste-heat recovery and solid-state cooling technologies. A persistent challenge in TE materials design arises from the strong interdependence among the electrical…

Materials Science · Physics 2026-04-28 Zhonghao Xia , Michele Reticcioli , Yateng Wang , Yali Yang , Alessandro Stroppa , Jiangang He

In spite of their relatively high lattice thermal conductivity $\kappa_{\ell}$, the XNiSn (X=Ti, Zr or Hf) half-Heusler compounds are good thermoelectric materials. Previous studies have shown that $\kappa_{\ell}$ can be reduced by…

PbTe, one of the most promising thermoelectric materials, has recently demonstrated thermoelectric figure of merit ($ZT$) of above 2.0 when alloyed with group II elements. The improvements are due mainly to significant reduction of lattice…

Materials Science · Physics 2018-05-04 Yi Xia , James M. Hodges , Mercouri G. Kanatzidis , Maria K. Y. Chan

Complex electronic band structures, with multiple valleys or bands at the same or similar energies can be beneficial for thermoelectric performance, but the advantages can be offset by inter-valley and inter-band scattering. In this paper,…

Materials Science · Physics 2017-11-22 Evan Witkoske , Xufeng Wang , Vahid Askarpour , Mark Lundstrom , Jesse Maassen

Electron-crystal and phonon-glass are regarded as two essential factors for ideal thermoelectric materials, which require both an enhanced electronic transport and a depressed phononic transport. These two characteristics usually can not…

Materials Science · Physics 2016-06-29 Guangqian Ding , Guoying Gao , KailunYao

The thermoelectric properties of 54 different group 4 half-Heusler (HH) alloys have been studied from first principles. Electronic transport was studied with density functional theory using hybrid functionals facilitated by the $\mathbf{k}…

Materials Science · Physics 2020-01-08 Kristian Berland , Nina Shulumba , Olle Hellman , Clas Persson , Ole Martin Løvvik

A thorough understanding of the microscopic picture of heat conduction in solids is critical to a broad range of applications, from thermal management of microelectronics to more efficient thermoelectric materials. The transport properties…

Materials Science · Physics 2021-02-04 Yujie Quan , Shengying Yue , Bolin Liao

Intervalley collisions, which scatter electrons from one valley or band to another, can be detrimental to thermoelectric performance in materials with multiple valleys/bands. In this study, density functional theory is used to investigate…

Materials Science · Physics 2023-02-08 Vahid Askarpour , Jesse Maassen

We propose a novel design principle for achieving ultralow thermal conductivity in crystalline materials via a "heavy-light and soft-stiff" structural motif. By combining heavy and light atomic species with soft and stiff bonding networks,…

Materials Science · Physics 2025-08-26 Yu Wu , Ying Chen , Shuming Zeng , Hao Zhang , Liujiang Zhou , Chenhan Liu , Su-Huai Wei

High entropy carbides ceramics with randomly-distributed multiple principal cations have shown high temperature stability, low thermal conductivity, and possible radiation tolerance. While chemical disorder has been shown to suppress…

Materials Science · Physics 2022-05-23 Cody A. Dennett , Zilong Hua , Eric Lang , Fei Wang , Bai Cui

The cross-plane (across-layers) phonon thermal transport of five diverse, layered semiconductors is investigated by accounting for higher-order four-phonon scattering, phonon renormalization, and multi-channel thermal transport. For…

Materials Science · Physics 2023-11-07 Amey G. Gokhale , Ankit Jain

The phonon thermal transport properties of eight ternary intermetallic semiconductors are investigated by accounting for higher-order four-phonon scattering, phonon renormalization, and multi-channel thermal transport. The commonly used…

Materials Science · Physics 2022-08-17 Ankit Jain

MgAgSb, a promising thermoelectric material, undergoes reversible phase transitions that drastically alter its thermal transport behavior. Using first-principles calculations, we systematically investigate the lattice thermal conductivity…

Materials Science · Physics 2026-03-17 Luman Shang , Yu Wu , Yufan Liu , Shuming Zeng , Gang Tang , Chenhan Liu

Controlling thermal transport in insulators and semiconductors is crucial for many technological fields such as thermoelectrics and thermal insulation, for which a low thermal conductivity ($\kappa$) is desirable. A major obstacle for…

Materials Science · Physics 2023-08-22 Simon Thébaud , Lucas Lindsay , Tom Berlijn
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