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Path integral Monte Carlo (PIMC) simulations are used to calculate the momentum distribution of the homogeneous electron gas at finite temperature. This is done by calculating the off-diagonal elements of the real-space density matrix,…

Statistical Mechanics · Physics 2007-05-23 B. Militzer , E. L. Pollock , D. M. Ceperley

The uniform electron gas (UEG) at finite temperature is of key relevance for many applications in the warm dense matter regime, e.g. dense plasmas and laser excited solids. Also, the quality of density functional theory calculations…

Strongly Correlated Electrons · Physics 2016-02-10 S. Groth , T. Schoof , T. Dornheim , M. Bonitz

We present extensive \emph{ab initio} path integral Monte Carlo (PIMC) results for the dynamic properties of the finite temperature uniform electron gas (UEG) over a broad range of densities, $2\leq r_s\leq300$. We demonstrate that the…

We develop an all-electron path integral Monte Carlo (PIMC) method with free-particle nodes for warm dense matter and apply it to water and carbon plasmas. We thereby extend PIMC studies beyond hydrogen and helium to elements with core…

Materials Science · Physics 2012-03-22 Kevin Driver , Burkhard Militzer

The static density response of the uniform electron gas is of fundamental importance for numerous applications. Here, we employ the recently developed \textit{ab initio} permutation blocking path integral Monte Carlo (PB-PIMC) technique…

Strongly Correlated Electrons · Physics 2017-08-23 Tobias Dornheim , Simon Groth , Jan Vorberger , Michael Bonitz

The uniform electron gas (UEG) at finite temperature has recently attracted substantial interest due to the epxerimental progress in the field of warm dense matter. To explain the experimental data accurate theoretical models for high…

Strongly Correlated Electrons · Physics 2015-03-25 V. S. Filinov , V. E. Fortov , M. Bonitz , Zh. Moldabekov

We combine ab initio path integral Monte Carlo (PIMC) simulations with fixed ion configurations from density functional theory molecular dynamics (DFT-MD) simulations to solve the electronic problem for hydrogen under warm dense matter…

Plasma Physics · Physics 2023-02-01 Maximilian Böhme , Zhandos A. Moldabekov , Jan Vorberger , Tobias Dornheim

A path integral Monte Carlo method (PIMC) based on Feynman-Kac formula for mixed boundary conditions of elliptic equations is proposed to solve the forward problem of electrical impedance tomography (EIT) on the boundary to obtain…

Numerical Analysis · Mathematics 2019-08-01 Yijing Zhou , Wei Cai

We address the issue of determining an effective two-body interaction for mean-field calculations of energies of many-body systems. We show that the effective interaction is proportional to the phase shift, and demonstrate this result in…

Other Condensed Matter · Physics 2007-05-23 A. Collin , P. Massignan , C. J. Pethick

We systematically investigate finite-size effects in the dynamic structure factor $S(q,\omega)$ of the uniform electron gas obtained via the analytic continuation of \textit{ab initio} path integral Monte-Carlo (PIMC) data for the…

Strongly Correlated Electrons · Physics 2020-12-30 Tobias Dornheim , Jan Vorberger

Understanding the dynamic properties of the uniform electron gas (UEG) is important for numerous applications ranging from semiconductor physics to exotic warm dense matter. In this work, we apply the maximum entropy method (MEM), as…

Strongly Correlated Electrons · Physics 2025-09-19 Thomas Chuna , Nicholas Barnfield , Jan Vorberger , Michael P. Friedlander , Tim Hoheisel , Tobias Dornheim

The quasiparticle effective mass is a key quantity in the physics of electron gases, describing the renormalization of the electron mass due to electron-electron interactions. Two-dimensional electron gases are of fundamental importance in…

Quantum Gases · Physics 2013-02-01 N. D. Drummond , R. J. Needs

The discrete time path integral Monte Carlo (PIMC) with a one-particle density matrix approximation is applied to study the quantum phase transition in the coupled double-well chain. To improve the convergence properties, the exact action…

Statistical Mechanics · Physics 2015-06-25 Dong-Hee Kim , Yu-Cheng Lin , Heiko Rieger

The \emph{ab initio} path integral Monte Carlo (PIMC) method is one of the most successful methods in statistical physics, quantum chemistry and related fields, but its application to quantum degenerate Fermi systems is severely hampered by…

Computational Physics · Physics 2023-08-14 Tobias Dornheim , Panagiotis Tolias , Simon Groth , Zhandos Moldabekov , Jan Vorberger , Barak Hirshberg

We develop a \pi-electron effective field theory (\pi-EFT) wherein the two-body Hamiltonian for a \pi-electron system is expressed in terms of three effective parameters: the \pi-orbital quadrupole moment, the on-site repulsion, and a…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Joshua D. Barr , Justin P. Bergfield , Charles A. Stafford

A path-integral hybrid Monte Carlo approach with enveloping bridging potentials (PIHMC-EBP) is proposed for calculating numerically exact tunneling splittings in molecular systems. The central idea is to construct an approximately…

Chemical Physics · Physics 2026-04-15 Yu-Chen Wang , Jeremy O. Richardson

We combine the recent $\eta-$ensemble path integral Monte Carlo (PIMC) approach to the free energy [T.~Dornheim \textit{et al.}, \textit{Phys.~Rev.~B} \textbf{111}, L041114 (2025)] with a recent fictitious partition function technique based…

In a recent Letter [T.~Dornheim \textit{et al.}, Phys. Rev. Lett. \textbf{117}, 156403 (2016)], we presented the first \textit{ab initio} quantum Monte-Carlo (QMC) results of the warm dense electron gas in the thermodynamic limit. However,…

In a recent Letter [T. Dornheim et al., Phys. Rev. Lett. 121, 255001 (2018)] we have presented the first ab initio results for the dynamic structure factor $S(\mathbf{q},\omega)$ of the uniform electron gas for conditions ranging from the…

Plasma Physics · Physics 2019-06-19 Simon Groth , Tobias Dornheim , Jan Vorberger

We compute quasi-exact \emph{ab initio} path-integral Monte Carlo results for the Matsubara Green's function of the uniform electron gas (UEG) at finite temperature over a broad range of coupling strengths ($r_s=1,\dots,10)$. This allows us…

Quantum Gases · Physics 2026-01-22 Paul Hamann , Michael Bonitz , Jan Vorberger , Tobias Dornheim