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Adding porosity to battery electrodes is believed to be universally useful for adding space to accommodate volumetric expansion, electrolyte access to all active materials, helping to mitigate poor C-rate performance for thicker electrodes…

Applied Physics · Physics 2020-08-26 Sally O'Hanlon , David McNulty , Ruiyuan Tian , Jonathan Coleman , Colm O'Dwyer

Silicon is a promising anode material for next-generation lithium-ion batteries. However, the volume change and the voltage hysteresis during lithiation and delithiation are two substantial drawbacks to their lifetime and performance. We…

Chemical Physics · Physics 2024-02-19 Lukas Köbbing , Arnulf Latz , Birger Horstmann

The mechanisms of lithium electrodeposition, which overwhelmingly affect lithium metal battery performance and safety, remain insufficiently understood due to its electrochemical complexity. Novel, non-destructive and in situ techniques to…

Applied Physics · Physics 2023-07-19 Runqing Yang , Harrison Szeto , Brandon Zou , Emily Spitaleri , Bolin Liao , Yangying Zhu

The kinetic performance of graphite particles is difficult to deconvolute from half-cell experiments, where the influences of the working electrode porosity and the counter electrode contribute nonlinearly to the electrochemical re-sponse.…

Materials Science · Physics 2015-03-13 Michael Heß , Petr Novák

Silicon is one of the most promising anode materials for Lithium-ion batteries. Silicon endures volume changes upon cycling, which leads to subsequent pulverization and capacity fading. These drawbacks lead to a poor lifespan and hamper the…

Materials Science · Physics 2022-12-23 Mariam Ezzedine , Fatme Jardali , Ileana Florea , Mihai-robert Zamfir , Costel-sorin Cojocaru

In this work a 1D finite volume based model using coupled meshes is introduced to capture potential and species distribution throughout the discharge process in a lithium bismuth liquid metal battery while neglecting hydrodynamic effects,…

Chemical Physics · Physics 2023-05-30 Carolina Duczek , Norbert Weber , Omar E. Godinez-Brizuela , Tom Weier

We demonstrate that photoacoustic microscopy (PAM) can be a potential novel imaging tool to investigate the Li metal dendrite growth, a critical issue leading to short circuit and even explosion of Li metal batteries. Our results suggest…

Applied Physics · Physics 2019-10-02 Huihui Liu , Yibo Zhao , Jiasheng Zhou , Ping Li , Shou-Hang Bo , Sung-Liang Chen

Solid-state batteries (SSBs) can offer a paradigm shift in battery safety and energy density. Yet, the promise hinges on the ability to integrate high-performance electrodes with state-of-the-art solid electrolytes. For example, lithium…

Materials Science · Physics 2021-08-03 Christian Hänsel , Baltej Singh , David Kiwic , Pieremanuele Canepa , Dipan Kundu

Li-ion batteries contain excess anode area to improve manufacturability and prevent Li plating. These overhang areas in graphite electrodes are active but experience decreased Li+ flux during cycling. Over time, the overhang and the anode…

Cell inconsistency within a lithium-ion battery system poses a significant challenge in maximizing the system operational time. This study presents an optimization-driven active balancing method to minimize the effects of cell inconsistency…

Systems and Control · Electrical Eng. & Systems 2024-05-03 Yiming Xu , Xiaohua Ge , Ruohan Guo , Weixiang Shen

Nanostructured Si is the most promising high-capacity anode material to substantially increase the energy density of Li-ion batteries. Among the remaining challenges is its low rate capability as compared to conventional materials. To…

Disordered Systems and Neural Networks · Physics 2019-01-29 Nongnuch Artrith , Alexander Urban , Yan Wang , Gerbrand Ceder

In Li-ion batteries the electrochemical potential drives the redox reactions occurring at the interface between electrolyte and storage material, typically active particles for porous electrodes, allowing Li ions intercalation/extraction…

Applied Physics · Physics 2022-03-15 M. Magri , B. Boz , L. Cabras , A. Salvadori

The current rechargeable battery technologies have a failure in their performance at high pressure and temperature. In this article, we have brought theoretical insights on using boron nitride flakes as a protecting layer for a lithium-ion…

Applied Physics · Physics 2021-02-15 Narjes Kheirabadi , Azizollah Shafiekhani

All-solid-state batteries hold great promise for electric vehicle applications due to their enhanced safety and higher energy density. However, further performance optimization requires a deeper understanding of their degradation…

The demand for lithium ion batteries (LIBs) on the market has gradually risen, with production increasing every year. To meet industrial needs, the development of digital twins designed to optimize LIB manufacturing processes is essential.…

An analysis of the dependence of electric potential on the state of stress of a lithiated-silicon electrode is presented. Based on the Larch\'e and Cahn chemical potential for a solid solution, a thermodynamic argument is made for the…

Materials Science · Physics 2011-08-02 Vijay A. Sethuraman , Venkat Srinivasan , Allan F. Bower , Pradeep R. Guduru

The rechargeable aprotic Li-air (O2) battery is a promising potential technology for next generation energy storage, but its practical realization still faces many challenges. In contrast to the standard Li-O2 cells, which cycle via the…

Chemical Physics · Physics 2018-05-09 Tao Liu , Michal Leskes , Wanjing Yu , Amy J. Moore , Lina Zhou , Paul M. Bayley , Gunwoo Kim , Clare P. Grey

Identifying overpotential components of electrochemical systems enables quantitative analysis of polarization contributions of kinetic processes under practical operating conditions. However, the inherently coupled kinetic processes lead to…

Chemical Physics · Physics 2022-07-25 Ruoyu Xiong , Yue Yu , Shuyi Chen , Maoyuan Li , Longhui Li , Mengyuan Zhou , Wen Zhang , Bo Yan , Dequn Li , Hui Yang , Yun Zhang , Huamin Zhou

The use of liquid metal batteries is considered as one promising option for electric grid stabilisation. While large versions of such batteries are preferred in view of the economies of scale, they are susceptible to various…

Fluid Dynamics · Physics 2021-11-29 Norbert Weber , Vladimir Galindo , Frank Stefani , Tom Weier

Understand the nature of liquid structure and its evolution under different conditions is a major challenge in condensed physics and materials science. Here, we report a pressure-induced structure change spanning a wide pressure range in…

Materials Science · Physics 2025-01-28 X. Z. Yan , Y. M. Chen , Hua Y. Geng , Y. F. Wang , Y. Sun , L. L. Zhang , H. Wang , Y. L. Xu