Related papers: Deuterated ammonia in Galactic massive star-formin…
Observations of deuterium fractionation in the solar system, and in interstellar and circumstellar material, are commonly used to constrain the formation environment of volatiles. Toward protoplanetary disks, this approach has been limited…
Aims. We aim to develop a chemical model that contains a consistent description of spin-state chemistry in reactions involving chemical species with multiple deuterons. We apply the model to the specific case of deuterated ammonia, to…
High levels of deuterium fractionation of $\rm N_2H^+$ (i.e., $\rm D_{frac}^{N_2H^+} \gtrsim 0.1$) are often observed in pre-stellar cores (PSCs) and detection of $\rm N_2D^+$ is a promising method to identify elusive massive PSCs. However,…
We present an analysis of gas densities in the central R=300 parsecs of the Milky Way, focusing on three clouds: GCM-0.02-0.07 (the 50 km/s cloud), GCM-0.13-0.08 (the 20 km/s cloud), and GCM0.25+0.01 (the "Brick"). Densities are determined…
H2S is thought to be the main sulphur reservoir in the ice, being therefore a key molecule to understand sulphur chemistry in the star formation process and to solve the missing sulphur problem. The H2S deuterium fraction can be used to…
We present observations of the (1,1), (2,2), (4,4) and (5,5) inversion transitions of para-ammonia (NH3) and 24 GHz continuum, taken with the Australia Telescope Compact Array toward 21 southern Galactic hot molecular cores traced by 6.7…
Deuterium fractionation in the closest vicinity of a protostar is important in understanding its potential heritage to a planetary system. Here, we have detected the spectral line emission of CH3OH and its three deuterated species, CH2DOH,…
We present 12 mm Mopra observations of the dense (>10^3 cm^-3 ) molecular gas towards the north-east (NE) of the W28 supernova remnant (SNR). This cloud is spatially well-matched to the TeV gamma-ray source HESS J1801-233 and is known to be…
We present the results of on-the-fly mapping observations of 44 fields containing 107 SCUBA-2 cores in the emission lines of molecules, N$_2$H$^+$, HC$_3$N, and CCS at 82$-$94 GHz using the Nobeyama 45-m telescope. This study aimed at…
(Abridged) The water deuterium fractionation (HDO/H$_2$O abundance ratio) has traditionally been used to infer the amount of water brought to Earth by comets. Measuring this ratio in deeply-embedded low-mass protostars makes it possible to…
We determine the ortho/para ratios of NH2D and NHD2 in two dense, starless cores, where their formation is supposed to be dominated by gas-phase reactions, which, in turn, is predicted to result in deviations from the statistical spin…
Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA,…
We present the results of NH3 (1,1), (2,2) and (3,3) and H2O maser simultaneous mapping observations toward the high-mass star-forming region W33 with the Nobeyama 45-m radio telescope. W33 has six dust clumps and one of which, W33 Main, is…
We have undertaken a survey of N2H+ and N2D+ towards 31 low-mass starless cores using the IRAM 30m telescope. Our main objective has been to determine the abundance ratio of N2D+ and N2H+ towards the nuclei of these cores and thus to obtain…
We report on the detection of deuterated molecular hydrogen, HD, at $z = 0.18$. HD and H$_{\rm 2}$ are detected in HST/COS data of a low metallicity ($Z \sim 0.07Z_\odot$) damped Ly$\alpha$ system at $z = 0.18562$ toward QSO B0120$-$28,…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Aims. The purpose of this study is to examine the prediction that the deuterated H3+ ion, H2D+, can be found exclusively in the coldest regions of molecular cloud cores. This is also a feasibility study for the detection of the ground-state…
We present a detailed analysis of the H_2 and HD absorption lines detected in the Damped Lyman-alpha (DLA) system at z_abs=2.3377 towards the quasar Q1232+082. We show that this intervening cloud has a covering factor smaller than unity and…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…
Deuterium enhancement of monodeuterated species has been recognized for more than 30 years as a result of the chemical fractionation that results from the difference in zero point energies of deuterated and hydrogenated molecules. The key…