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Over the past decade, a combinatorial framework for discrete, finite, and irreversibly aggregating systems has emerged. This work reviews its progress, practical applications, and limitations. We outline the approach's assumptions and…

Statistical Mechanics · Physics 2026-01-06 Michał Łepek , Agata Fronczak , Piotr Fronczak

This work outlines an exact combinatorial approach to finite coagulating systems through recursive equations and use of generating function method. In the classic approach the mean-field Smoluchowski coagulation is used. However, the…

Statistical Mechanics · Physics 2021-04-16 Michał Łepek , Paweł Kukliński , Agata Fronczak , Piotr Fronczak

The paper outlines an exact combinatorial approach to finite coagulating systems. In this approach, cluster sizes and time are discrete, and the binary aggregation alone governs the time evolution of the systems. By considering the growth…

Statistical Mechanics · Physics 2018-02-21 Agata Fronczak , Anna Chmiel , Piotr Fronczak

We establish nearly optimal rates of convergence to self-similar solutions of Smoluchowski's coagulation equation with kernels $K = 2$, $x + y$, and $xy$. The method is a simple analogue of the Berry-Ess\'een theorem in classical…

Adaptation and Self-Organizing Systems · Physics 2011-04-26 Ravi Srinivasan

We report a number of exact solutions for temperature-dependent Smoluchowski equations. These equations quantify the ballistic agglomeration, where the evolution of densities of agglomerates of different size is entangled with the evolution…

Statistical Mechanics · Physics 2022-11-09 Alexander Osinsky , Nikolay Brilliantov

We present in a detailed manner the scaling theory of irreversible aggregation characterized by the set of reaction rates $K(k,l)=1/k+1/l$, as well as a minor generalisation thereof. In this case, it is possible to evaluate the scaling…

Statistical Mechanics · Physics 2021-02-17 Francois Leyvraz

Temperature-dependent Smoluchowski equations describe the ballistic agglomeration. In contrast to the standard Smoluchowski equations for the evolution of cluster densities with constant rate coefficients, the temperature-dependent…

Statistical Mechanics · Physics 2022-10-11 A. I. Osinsky , N. V. Brilliantov

We consider the mass-dependent aggregation process (k+1)X -> X, given a fixed number of unit mass particles in the initial state. One cluster is chosen proportional to its mass and is merged into one either with k-neighbors in one…

Data Analysis, Statistics and Probability · Physics 2011-11-02 Seung-Woo Son , Claire Christensen , Golnoosh Bizhani , Peter Grassberger , Maya Paczuski

In this paper we compute new reaction rates of the Smoluchowski equation which takes into account correlations. The new rate K = KMF + KC is the sum of two terms. The first term is the known Smoluchowski rate with the mean-field…

Statistical Mechanics · Physics 2009-11-13 Lionel Sittler

In this paper we show how the method of Zakharov transformations may be used to analyze the stationary solutions of the Smoluchowski aggregation equation for arbitrary homogeneous kernel. The resulting massdistributions are of Kolmogorov…

Statistical Mechanics · Physics 2009-11-10 Colm Connaughton , R. Rajesh , Oleg Zaboronski

The model of binary aggregation with constant kernel is subjected to stochastic resetting: aggregates of any size explode into monomers at independent stochastic times. These resetting times are Poisson distributed, and the rate of the…

Statistical Mechanics · Physics 2021-08-11 Pascal Grange

The time evolution of a system of coagulating particles under the product kernel and arbitrary initial conditions is studied. Using the improved Marcus-Lushnikov approach, the master equation is solved for the probability $W(Q,t)$ to find…

Statistical Mechanics · Physics 2019-01-09 Agata Fronczak , Michał Łepek , Paweł Kukliński , Piotr Fronczak

We derive a satisfying rate of convergence of the Marcus-Lushnikov process toward the solution to Smoluchowski's coagulation equation. Our result applies to a class of homogeneous-like coagulation kernels with homogeneity degree ranging in…

Probability · Mathematics 2011-03-10 Eduardo Cepeda , Nicolas Fournier

Reactions in solution require "contact" between the reagents. We can predict the rate at which reagents come into "contact" (at least in dilute conditions), but if the initial collision does not lead to reaction, what happens then? The…

Chemical Physics · Physics 2024-07-30 Manuel Dedola , Gaia Cassarà-Airoldi , Ludovico Cademartiri

We investigate a class of stochastic aggregation processes involving two types of clusters: active and passive. The mass distribution is obtained analytically for several aggregation rates. When the aggregation rate is constant, we find…

Statistical Mechanics · Physics 2007-05-23 P. L. Krapivsky , E. Ben-Naim

It has been established that there is an inherent limit to the accuracy of the reaction-diffusion master equation. Specifically, there exists a fundamental lower bound on the mesh size, below which the accuracy deteriorates as the mesh is…

Numerical Analysis · Mathematics 2016-01-27 Stefan Hellander , Linda Petzold

We examine the classic problem of homogeneous nucleation and growth by deriving and analyzing a fully discrete stochastic master equation. Upon comparison with results obtained from the corresponding mean-field Becker-D\"{o}ring equations…

Statistical Mechanics · Physics 2015-06-03 M. R. D'Orsogna , G. Lakatos , T. Chou

We propose an efficient and fast numerical algorithm of finding a \emph{stationary} solution of large systems of aggregation-fragmentation equations of Smoluchowski type for concentrations of reacting particles. This method is applicable…

Computational Physics · Physics 2015-04-13 Vladimir Stadnichuk , Anna Bodrova , Nikolai Brilliantov

We develop an action formalism to calculate probabilities of rare events in cluster-cluster aggregation for arbitrary collision kernels and establish a pathwise large deviation principle with total mass being the rate. As an application,…

Statistical Mechanics · Physics 2024-05-10 R. Rajesh , V. Subashri , Oleg Zaboronski

We consider the numbers arising in the problem of normal ordering of expressions in canonical boson creation and annihilation operators. We treat a general form of a boson string which is shown to be associated with generalizations of…

Quantum Physics · Physics 2010-12-30 M A Mendez , P Blasiak , K A Penson
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