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We make the first study the optical energy level structure and interactions of pairs of single rare earth ions using a hybrid electro-optical detection method applied to Er-implanted silicon. Two examples of Er3+ pairs were identified in…

In many important situations the dominant dephasing mechanism in cryogenic rare-earth-ion doped systems is due to magnetic field fluctuations from spins in the host crystal. Operating at a magnetic field where a transition has a zero…

Atomic Physics · Physics 2015-06-03 D. L. McAuslan , J. G. Bartholomew , M. J. Sellars , J. J. Longdell

Rare-earth ion doped crystals are promising systems for quantum communication and quantum information processing. In particular, paramagnetic rare-earth centres can be utilized to realize quantum coherent interfaces simultaneously for…

High-resolution Zeeman spectroscopy of electronic-nuclear hyperfine levels of ${^5\mathrm{I}_8}\rightarrow{^5\mathrm{I}_7}$ transitions in Ho$^{3+}$:Y$_2$SiO$_5$ is reported. Crystal-field parameters determined for the two $C_1$ symmetry…

We present polarization-resolved optical absorption measurements on Er3+ ions in CaWO4 under vector magnetic fields, focusing on charge-compensated sites arising from local Ca2+ vacancies. While the known axial Er3+ site displays a single…

We report microwave spectroscopy of $^{167}$Er$^{3+}$ doped in CaWO$_4$ which reveals the hyperfine splitting of the erbium electronic ground state ($Z_1$, $J_\mathrm{eff.}$=15/2) induced by the $I$=7/2 nuclear spin. From spectra measured…

Erbium implanted silicon as a quantum technology platform has both telecommunications and integrated circuit (IC) processing compatibility. The electron spin coherence time of Er implanted Si with an Er concentration of 3X1017 cm-3 is…

We report on the development and application of a parametrized crystal-field model for both C$_{1}$ symmetry centers in trivalent erbium-doped Y$_{2}$SiO$_{5}$. High resolution Zeeman and temperature dependent absorption spectroscopy was…

Materials Science · Physics 2022-06-22 N. L. Jobbitt , J. -P. R. Wells , M. F. Reid , S. P. Horvath , P. Goldner , A. Ferrier

We report the first observation of electromagnetically induced transparency (EIT) in an isotopically purified Nd$^{3+}$:YLiF$_4$ crystal. This crystal demonstrates inhomogeneous broadening of optical transitions of about 35 MHz. EIT is…

Rare earth doped crystals are promising systems for quantum information processing. In particular paramagnetic rare earths could be used to build coherent interfaces with optical and microwave photons. In addition, isotopes with non zero…

Materials Science · Physics 2016-10-19 Sacha Welinski , Alban Ferrier , Mikael Afzelius , Philippe Goldner

Erbium implanted silicon (Er:Si) is a promising platform for quantum networking applications, but a major obstacle is the formation of multiple Er centres. We show that the previously identified cubic centre (Er-C) has C2v or lower…

Applied Physics · Physics 2024-08-20 Mark A. Hughes , Huan Liu , Adam Brookfield , Tianrui Wang , Iain F. Crowe , Yaping Dan

Computational crystal-field models have provided consistent models of both electronic and Zeeman-hyperfine structure for several rare earth ions. These techniques have not yet been applied to the Zeeman-hyperfine structure of Eu$^{3+}$…

Materials Science · Physics 2022-04-13 Kieran M. Smith , Michael F. Reid , Matthew J. Sellars , Rose L. Ahlefeldt

We report Zeeman infra-red spectroscopy of electronic-nuclear levels of $^5$I$_8 \rightarrow ^5$I$_7$ transitions of Ho$^{3+}$ in the C$_{\rm 4v}$(F$^-$) centre in CaF$_2$ with the magnetic field along the $\langle 111\rangle$ direction of…

Materials Science · Physics 2025-10-20 Kieran M. Smith , Michael F. Reid , Jon-Paul R. Wells

We present a comprehensive spectroscopic study of C$_{2v}$ point-group symmetry sites in Sm$^{3+}$:CaF$_2$/SrF$_2$ codoped with either NaF or LiF. Data includes electron paramagnetic resonance measurements of Zeeman and hyperfine…

Materials Science · Physics 2018-12-05 Sebastian P Horvath , Jon-Paul R Wells , Michael F Reid , Mitsuo Yamaga , Makoto Honda

We show that crystal-field calculations for $C_1$ point-group symmetry are possible, and that such calculations can be performed with sufficient accuracy to have substantial utility for rare-earth based quantum information applications. In…

Erbium ions (Er3+) provide a telecom-band optical transition with strong magnetic-dipole character, making them attractive for quantum communication and spin-photon interfaces. Identifying host environments that combine low decoherence with…

Mesoscale and Nanoscale Physics · Physics 2026-03-24 Guadalupe Garcia-Arellano , Gabriel I. Lopez-Morales , Johannes Flick , Cyrus E. Dreyer , Carlos A. Meriles

We present an all-electron calculation of the hyperfine parameters for conduction electrons in Si, showing that: (i) all parameters scale linearly with the spin density at a $^{29}$Si site; (ii) the isotropic term is over 30 times larger…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Lucy V. C. Assali , Helena M. Petrilli , Rodrigo B. Capaz , Belita Koiller , Xuedong Hu , S. Das Sarma

Ion trap quantum computers often store qubits on field-sensitive S_1/2 ground state Zeeman levels of the valence electron, such as in 40Ca+, 88Sr+, and 138Ba+ atomic systems. We experimentally synthesize magnetically insensitive qubit…

Quantum Physics · Physics 2026-04-21 Ksenia Sosnova , Martin Lichtman , Allison Carter , Nora Crocker , Christopher Monroe

The first observation of the resolved Mims electron-nuclear double resonance (ENDOR) spectra from the nearby and remote nuclei of 19F and 7Li nuclei on impurity Ce3+ ions in LiYF4 crystal is reported. It shows that LiYF4:Ce3+ system can be…

Materials Science · Physics 2017-12-27 M. R. Gafurov , G. V Mamin , I. N. Kurkin , A. A. Rodionov , S. B. Orlinskii

We produced optical waveguides in the 167Er3+ :7LiYF4 crystal with diameters ranging from 30 to 100 mkm by using the depressed-cladding approach with femtosecond laser. These waveguides were studied (both inside and outside) by stationary…

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