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Lead sulfide is an important semiconductor that has found technological applications for over a century. Raman spectroscopy, a standard tool for the investigation and characterization of semiconductors, has limited application to this…

Materials Science · Physics 2015-05-13 P. G. Etchegoin , M. Cardona , R. Lauck , R. J. H. Clark , J. Serrano , A. H. Romero

We report Raman spectra measurements on a MoS2 monolayer supported on SiO2 as a function of temperature. Unlike in previous studies, the positions of the two main Raman modes, E2g1 and A1g exhibited nonlinear temperature dependence.…

Mesoscale and Nanoscale Physics · Physics 2014-06-13 Andrzej Taube , Jarosław Judek , Cezariusz Jastrzębski , Anna Duzynska , Krzysztof Świtkowski , Mariusz Zdrojek

High quality single crystals of Bi2Se3 were grown using a modified Bridgman technique, the detailed study were carried out using Raman spectroscopy and characterized by Laue diffraction and high resolution transmission electron microscopy.…

We report a comprehensive Raman study of the phonon behaviour in PdSe$_2$ in the temperature range of 5 K to 300 K. A remarkable change in the Raman spectrum is observed at 120 K: a significant enhancement of the out-of-plane phonon…

Polarized Raman scattering spectra of superconducting K$_x$Fe$_{2-y}$Se$_2$ and nonsuperconducting K$_{0.8}$Fe$_{1.8}$Co$_{0.2}$Se$_2$ single crystals were measured in a temperature range from 10 K up to 300 K. Two Raman active modes from…

Materials Science · Physics 2016-09-20 M. Opačić , N. Lazarević , M. Šćepanović , Hyejin Ryu , Hechang Lei , C. Petrovic , Z. V. Popović

The temperature dependence of the asymmetry between Stokes and anti-Stokes Raman scattering can be exploited for self-calibrating, optically-based thermometry. In the context of cavity optomechanics, we observe the cavity-enhanced…

Quantum Physics · Physics 2015-09-16 T. P. Purdy , P. -L. Yu , N. S. Kampel , R. W. Peterson , K. Cicak , R. W. Simmonds , C. A. Regal

Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…

We present a Raman study of ZrAs_{2} single crystals, a nodal line semimetal with symmetry-enforced Dirac-like band crossings. We identified the symmetry of phonon modes by polarized light measurements and comparison with calculated phonon…

Materials Science · Physics 2024-05-16 R. Bacewicz , C. Jastrzębski , K. Zberecki , A. S. Wadge , D. Jastrzębski , A. Wiśniewski

We demonstrate the generation of coherent Stokes pulses with randomized linear-polarization in diamond, when the pump wave-vector and linear polarization were oriented along the $[110]$ and $[1\bar{1}0]$ axes respectively. In this…

We report plane-polarized Raman scattering spectra of iron oxypnictide superconductor NdFeAsO$_{1-x}$F$_x$ single crystals with varying fluorine $x$ content. The spectra exhibit sharp and symmetrical phonon lines with a weak dependence on…

Superconductivity · Physics 2009-11-13 Y. Gallais , A. Sacuto , M. Cazayous , P. Cheng , L. Fang , H. H. Wen

Resonance Raman scattering, a very effective and sensitive technique for atomically thin semiconducting transition metal dichalcogenide, can be used to observe the phonons from the entire Brillouin zone. In addition to the significance of…

Materials Science · Physics 2023-02-06 Deepu Kumar , Nasaru Khan , Rahul Kumar , Mahesh Kumar , Pradeep Kumar

A technique to measure the decoherence time of optical phonons in a solid is presented. Phonons are excited with a pair of time delayed 80 fs, near infrared pulses via spontaneous, transient Raman scattering. The fringe visibility of the…

Due to their sub picosecond temporal resolution, coherent Raman spectroscopies have been proposed as a viable extension of Spontaneous Raman (SR) thermometry, to determine dynamics of mode specific vibrational energy content during out of…

We report an investigation of perovskite-type LaNiO3 thin films by Raman scattering in both various scattering configurations and as a function of temperature. The room-temperature Raman spectra and the associated phonon mode assignment…

Materials Science · Physics 2010-07-30 N. Chaban , M. Weber , S. Pignard , J. Kreisel

We demonstrate a novel technique of coherent Raman spectroscopy with a femtosecond laser. We apply to a molecular sample a sequence of pairs of ultrashort excitation and probe pulses, with a linearly increasing time delay between the two…

We report a Raman study of the effect of temperature on the self-energies of optical phonons in a number of transition metals with hexagonal-close-packed structure. Anisotropic softening of phonon energies and narrowing of phonon linewidths…

Materials Science · Physics 2017-01-04 Yu. S. Ponosov , S. V. Streltsov

Molybdenum sulfides are in the spotlight of materials science thanks to their interesting properties for applications in optoelectronics, nanocomposites, lubricants, and catalysis. The structural characterization of Molybdenum sulfides is a…

Materials Science · Physics 2026-04-10 Samuel Longo , Aloïs Castellano , Matthieu J. Verstraete

We have carried out temperature-dependent x-ray diffraction and Raman scattering experiments on powder $Cs_3Bi_2Br_9$. Trigonal to monoclinic structural transition at around 95 K is discussed and shown to be driven by the softening of the…

Raman spectra from silicon nanostructures, recorded using excitation laser power density of 1.0 kW/cm^2, is employed here to reveal the dominance of thermal effects at temperatures higher than the room temperature. Room temperature Raman…

Mesoscale and Nanoscale Physics · Physics 2012-01-25 Rajesh Kumar , Vivek Kumar , A. K. Shukla

We have carried out temperature and pressure-dependent Raman and x-ray measurements on single crystals of Tb$_2$Ti$_2$O$_7$. We attribute the observed anomalous temperature dependence of phonons to phonon-phonon anharmonic interactions. The…

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