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Related papers: Quantum Davidson Algorithm for Excited States

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Accurate computation of multiple eigenvalues of quantum Hamiltonians is essential in quantum chemistry, materials science, and molecular spectroscopy. Estimating excited-state energies is challenging for classical algorithms due to…

Quantum Physics · Physics 2026-05-22 Grzegorz Rajchel-Mieldzioć , Szymon Pliś , Emil Zak

Despite the successful enhancement to the Harrow-Hassidim-Lloyd algorithm by Childs et al., who introduced the Fourier approach leveraging linear combinations of unitary operators, our research has identified non-trivial redundancies within…

Quantum Physics · Physics 2024-05-13 Rui-Bin Xu , Zhu-Jun Zheng , Zheng Zheng

We apply the recently proposed Sample-based Krylov Quantum Diagonalization (SKQD) method to lattice gauge theories, using the Schwinger model with a $\theta$-term as a benchmark. SKQD approximates the ground state of a Hamiltonian,…

Quantum computers are expected to perform the full-configuration interaction calculations with less computational resources compared to classical ones, thanks to the use of the quantum phase estimation (QPE) algorithms. However, only a…

Quantum Physics · Physics 2024-12-05 Yusuke Ino , Misaki Yonekawa , Hideto Yuzawa , Yuichiro Minato , Kenji Sugisaki

The accurate computation of Hamiltonian ground, excited, and thermal states on quantum computers stands to impact many problems in the physical and computer sciences, from quantum simulation to machine learning. Given the challenges posed…

Quantum computers promise a great computational advantage over classical computers, yet currently available quantum devices have only a limited amount of qubits and a high level of noise, limiting the size of problems that can be solved…

Quantum Physics · Physics 2026-01-21 Ittay Alfassi , Dekel Meirom , Tal Mor

Excited electronic states of molecules and solids play a fundamental role in fields such as catalysis and electronics. In electronic structure calculations, excited states typically correspond to saddle points on the surface described by…

A milestone in the field of quantum computing will be solving problems in quantum chemistry and materials faster than state-of-the-art classical methods. The current understanding is that achieving quantum advantage in this area will…

Quantum Physics · Physics 2023-11-08 Guoming Wang , Daniel Stilck França , Ruizhe Zhang , Shuchen Zhu , Peter D. Johnson

We propose a variational framework for solving ground-state problems of open quantum systems governed by quantum stochastic differential equations (QSDEs). This formulation naturally accommodates bosonic operators, as commonly encountered…

Quantum Physics · Physics 2025-12-17 Yunyan Lee , Ian R. Petersen , Daoyi Dong

The spreading of quantum states in Krylov space under unitary dynamics provides a natural framework for characterizing quantum complexity. Quantifiers of this spreading, such as the spread complexity and the inverse participation ratio,…

Quantum Physics · Physics 2026-03-30 Swati Choudhary , Sukrut Mondkar , Ujjwal Sen

We present an algorithm that uses block encoding on a quantum computer to exactly construct a Krylov space, which can be used as the basis for the Lanczos method to estimate extremal eigenvalues of Hamiltonians. While the classical Lanczos…

Quantum Physics · Physics 2023-05-24 William Kirby , Mario Motta , Antonio Mezzacapo

Computing the excited states of a given Hamiltonian is computationally hard for large systems, but methods that do so using quantum computers scale tractably. This problem is equivalent to the PCA problem where we are interested in…

Quantum Physics · Physics 2025-03-19 David Quiroga , Jason Han , Anastasios Kyrillidis

Ground state counting plays an important role in several applications in science and engineering, from estimating residual entropy in physical systems, to bounding engineering reliability and solving combinatorial counting problems. While…

Quantum state discrimination (QSD) is a fundamental task in quantum information processing with numerous applications. We present a variational quantum algorithm that performs the minimum-error QSD, called the variational quantum state…

Quantum Physics · Physics 2024-08-12 Dongkeun Lee , Kyunghyun Baek , Joonsuk Huh , Daniel K. Park

We introduce a method for analyzing ground state properties of quantum many body systems, based on the characterization of separability and entanglement by single subsystem unitary operations. We apply the method to the study of the ground…

Quantum Physics · Physics 2008-01-19 S. M. Giampaolo , F. Illuminati , P. Verrucchi , S. De Siena

Quantum chemistry simulations offer a cost-effective way for computational design of BODIPY photosensitizers with potential use in photodynamic therapy (PDT). However, accurate predictions of photophysical properties, such as excitation…

Harnessing the full power of nascent quantum processors requires the efficient management of a limited number of quantum bits with finite lifetime. Hybrid algorithms leveraging classical resources have demonstrated promising initial results…

We propose a quantum algorithm, inspired by ADAPT-VQE, to variationally prepare the ground state of a quantum Hamiltonian, with the desirable property that if it fails to find the ground state, it still yields a physically meaningful…

Quantum Physics · Physics 2025-05-16 Shuchen Zhu , Yu Tong

Computing vacuum states of lattice gauge theories (LGTs) containing fermionic degrees of freedom can present significant challenges for classical computation using Monte-Carlo methods. Quantum algorithms may offer a pathway towards more…

Quantum Physics · Physics 2025-03-26 Lewis W. Anderson , Martin Kiffner , Tom O'Leary , Jason Crain , Dieter Jaksch

Level spectroscopy stands as a powerful method for identifying the transition point that delineates distinct quantum phases. Since each quantum phase exhibits a characteristic sequence of excited states, the crossing of energy levels…

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