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Jarzynski's equality sets a strong bound on the probability of violating the second law of thermodynamics by extracting work beyond the free energy difference. We derive finite-time refinements to this bound for driven systems in contact…

Statistical Mechanics · Physics 2023-04-19 Harry J. D. Miller , Martí Perarnau-Llobet

When a reciprocating heat engine is started it eventually settles to a stable mode of operation. The approach of a first principle quantum heat engine toward this stable limit cycle is studied. The engine is based on a working medium…

Quantum Physics · Physics 2016-09-08 Tova Feldmann , Ronnie Kosloff

Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…

Statistical Mechanics · Physics 2015-10-28 Hao Ge

Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It…

Statistical Mechanics · Physics 2011-11-10 Gavin E. Crooks

We develop the stochastic approach to thermodynamics based on the stochastic dynamics, which can be discrete (master equation) continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of…

Statistical Mechanics · Physics 2015-06-11 Tânia Tomé , Mário J. de Oliveira

We apply the adiabatic approximation to slow but finite-time thermodynamic processes and obtain the full counting statistics of work. The average work consists of change in free energy and the dissipated work, and we identify each term as a…

Statistical Mechanics · Physics 2023-02-16 Jie Gu

Underlying the classical thermodynamic principles are analogous microscopic laws, arising from the fundamental axioms of quantum mechanics. These define quantum thermodynamic variables such as quantum work and heat and characterize the…

Quantum Physics · Physics 2023-05-03 Roie Dann , Ronnie Kosloff

Thermodynamic length is a metric distance between equilibrium thermodynamic states that asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. By means of thermodynamic length, we first…

Statistical Mechanics · Physics 2022-01-27 Carlo Cafaro , Orlando Luongo , Stefano Mancini , Hernando Quevedo

The deep problems caused from the limitations of theoretical framework itself can only be clarified by extending and reconstructing of the theoretical framework, we extend classical theoretical framework of thermodynamics, break through the…

Chemical Physics · Physics 2025-01-17 Tang Suye

In this study, we advance the understanding of non-equilibrium systems by deriving thermodynamic relations for a heat engine operating under an exponentially decreasing temperature profile. Such thermal configurations closely mimic…

Statistical Mechanics · Physics 2025-04-01 Mesfin Taye

We present a comprehensive theory of heat engines (HE) based on a quantum-mechanical "working fluid" (WF) with periodically-modulated energy levels. The theory is valid for any periodicity of driving Hamiltonians that commute with…

Quantum Physics · Physics 2016-12-07 Victor Mukherjee , Wolfgang Niedenzu , Abraham G. Kofman , Gershon Kurizki

We prove that the transport of any differentiable scalar observable in $d$-dimensional non-equilibrium systems is bounded from above by the total entropy production scaled by the amount the observation "stretches" microscopic coordinates.…

Statistical Mechanics · Physics 2024-10-10 Cai Dieball , Aljaž Godec

In discrete-state Markovian systems, many important properties of correlations functions and relaxation dynamics depend on the spectrum of the rate matrix. Here we demonstrate the existence of a universal trade-off between thermodynamic and…

Statistical Mechanics · Physics 2024-01-24 Artemy Kolchinsky , Naruo Ohga , Sosuke Ito

A simple expression for the non-equilibrium distribution function in ultra-fast transient processes is proposed. Postulating its dependence on temporal derivatives of the equilibrium integrals of motion, non-equilibrium analogues of the…

Statistical Mechanics · Physics 2025-02-18 K. S. Glavatskiy

It is believed that thermodynamic laws are associated with random processes occurring in the system and, therefore, deterministic mechanical systems cannot be described within the framework of the thermodynamic approach. In this paper, we…

Classical Physics · Physics 2020-09-28 Sergey Rashkovskiy

The pursuit of achieving the maximum power in microscopic thermal engines has gained increasing attention in recent studies of stochastic thermodynamics. We employ the optimal control theory to study the performance of Brownian heat engines…

Statistical Mechanics · Physics 2024-10-31 Jin-Fu Chen , H. T. Quan

Landauer's bound is the minimum thermodynamic cost for erasing one bit of information. As this bound is achievable only for quasistatic processes, finite-time operation incurs additional energetic costs. We find a tight finite-time…

Statistical Mechanics · Physics 2022-10-05 Jae Sung Lee , Sangyun Lee , Hyukjoon Kwon , Hyunggyu Park

Time remains one of the least well understood concepts in physics, most notably in quantum mechanics. A central goal is to find the fundamental limits of measuring time. One of the main obstacles is the fact that time is not an observable…

Quantum Physics · Physics 2017-08-08 Paul Erker , Mark T. Mitchison , Ralph Silva , Mischa P. Woods , Nicolas Brunner , Marcus Huber

The speed-gradient variational principle (SG-principle) is formulated and applied to thermodynamical systems. It is shown that Prigogine's principle of minimum entropy production and Onsager's symmetry relations can be interpreted in terms…

General Physics · Physics 2007-05-23 Alexander L. Fradkov

In this work, we examine the impact of time-varying temperature and force on the thermodynamic features of active Brownian motor that moves with velocity against the force as well as passive Brownian motor. By deriving analytical…

Statistical Mechanics · Physics 2025-09-10 Mesfin Taye