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Nanobubbles formed in monolayers of transition metal dichalcogenides (TMDCs) on top of a substrate feature localized potentials, in which electrons can be captured. We show that the captured electronic density can exhibit a non-trivial…

Mesoscale and Nanoscale Physics · Physics 2021-12-22 Roberto Rosati , Frank Lengers , Christian Carmesin , Matthias Florian , Tilmann Kuhn , Frank Jahnke , Michael Lorke , Doris E. Reiter

Water is a ubiquitous liquid with unique physico-chemical properties, whose nature has shaped our planet and life as we know it. Water in restricted geometries has different properties than in bulk. Confinement can prevent low-temperature…

Electric double-layer capacitors (EDLCs), consisting of an ionic fluid between two metallic electrodes, are electrochemical energy storage devices complementary to batteries, allowing for a faster charge/discharge. The charging dynamics in…

Soft Condensed Matter · Physics 2026-05-19 Megh Dutta , Ivan Palaia , Emmanuel Trizac , Benjamin Rotenberg

The recent geopolitical crisis resulted in a gas price surge. Although lithium-ion batteries represent the best available rechargeable battery technology, a significant energy and power density gap exists between LIBs and petrol/gasoline.…

Computational Engineering, Finance, and Science · Computer Science 2023-09-06 Dibakar Datta

Deep Inelastic Neutron Scattering provides a means of directly and accurately measuring the momentum distribution of protons in water, which is determined primarily by the protons ground state wavefunction. We find that in water confined on…

Mesoscale and Nanoscale Physics · Physics 2011-01-27 G. F. Reiter , A. I. Kolesnikov , S. J. Paddison , P. M. Platzman , A. P. Moravsky , M. A. Adams , J. Mayers

Designing and fabricating self-assembled open colloidal crystals have become one major direction in soft matter community because of many promising applications associated with open colloidal crystals. However, most of the self-assembled…

Soft Condensed Matter · Physics 2019-04-16 Krongtum Sankaewtong , Qun-li Lei , Ran Ni

In molecular simulations, neural network force fields aim at achieving \emph{ab initio} accuracy with reduced computational cost. This work introduces enhancements to the Deep Potential network architecture, integrating a message-passing…

Computational Physics · Physics 2024-04-09 Ruiqi Gao , Yifan Li , Roberto Car

We present the first application of phase field modeling to electrochemistry. A free energy functional that includes the electrostatic effect of charged particles leads to rich interactions between concentration, electrostatic potential,…

Materials Science · Physics 2007-05-23 J. E. Guyer , W. J. Boettinger , J. A. Warren , G. B. McFadden

Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly-interacting environment, leading to the formation of discrete layers of charges at interfaces. Here, we propose a continuum theory that captures the…

A major challenge in modelling interfacial processes in electrochemical (EC) devices is performing simulations at constant potential. This requires an open-boundary description of the electrons, so that they can enter and leave the…

Chemical Physics · Physics 2023-11-07 Margherita Buraschi , Andrew P. Horsfield , Clotilde S. Cucinotta

We perform computational investigations of electrolyte-mediated interactions of charged colloidal particles confined within nanochannels. We investigate the role of discrete ion effects, valence, and electrolyte strength on colloid-wall…

Soft Condensed Matter · Physics 2023-02-28 Inderbir S. Sidhu , Amalie L. Frischknecht , Paul J. Atzberger

The distribution of electric fields within the electrochemical double layer depends on both the electrode and electrolyte in complex ways. These fields strongly influence chemical dynamics in the electrode-electrolyte interface, but cannot…

Ionic fluids under conductive confinement are central to technologies such as batteries, supercapacitors, and fuel cells. Their interfacial behavior governs energy storage and electrochemical processes. Despite their importance, the…

Soft Condensed Matter · Physics 2025-12-02 Philipp Stärk , Alexander Schlaich

We report the presence of a correlation between the bulk and interfacial properties of electrostatic coacervate complexes. Complexes were obtained by co-assembly between cationic-neutral diblocks and oppositely charged surfactant micelles…

Soft Condensed Matter · Physics 2007-10-12 Ling Qi , Jean-Paul Chapel , Jean-Christophe Castaing , Jerome Fresnais , Jean-Francois Berret

Supercapacitors, based on the fast ion transportation, are specialized to provide high power, long stability, and efficient energy storage with highly porous electrode materials. However, their low energy density and specific capacitance…

Materials Science · Physics 2013-11-07 Hao Yang , Santhakumar Kannappan , Amaresh S. Pandian , Jae-Hyung Jang , Yun Sung Lee , Wu Lu

Hypothesis: Generating multi-layer cargo using conventional methods is challenging. We hypothesize that incorporating a Y-junction compound droplet generator to encase a target core inside a second liquid can circumvent the kinetic energy…

Fluid Dynamics · Physics 2024-08-20 Utsab Banerjee , Sirshendu Misra , Sushanta K. Mitra

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…

Soft Condensed Matter · Physics 2009-11-10 Martin Z. Bazant , Katsuyo Thornton , Armand Ajdari

Understanding ion relaxation dynamics in overlapping electric double layers (EDLs) is critical for the development of efficient nanotechnology based electrochemical energy storage, electrochemomechanical energy conversion and…

Chemical Physics · Physics 2014-11-04 Vaibhav Thakore , James J. Hickman

The electron flux diverts electrons from optimal hydrogen production pathways to competitive pathways, which overall reduces the efficiency of the photo fermentation hydrogen production (PFHP) system. For tackling electron flux and…

Biological Physics · Physics 2025-12-05 Muhammad Shahzaib

In order to detect the effect of the surface charge discreteness on the properties at the solid-liquid interface, molecular dynamics simulation model taking consideration of the vibration of wall atoms was used to investigate the ion and…

Chemical Physics · Physics 2016-12-20 Yinghua Qiu , Yunfei Chen