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The low-frequency limit of the electrical conductivity (d.c. conductivity) of differently flexible polyions in aqueous solutions has been measured over an extended polyion concentration range, covering both the dilute and semidilute…

Soft Condensed Matter · Physics 2008-06-16 D. Truzzolillo , F. Bordi , C. Cametti , S. Sennato

Passivating solid-electrolyte interphase (SEI) films arising from electrolyte decomposition on low-voltage lithium ion battery anode surfaces are critical for battery operations. We review the recent theoretical literature on electrolyte…

Chemical Physics · Physics 2013-07-12 Kevin Leung

Besides the dominant NaCl, natural seawater/river water contains trace multivalent ions, which can provide effective screening to surface charges. Here, in both negatively and positively charged nanopores, influences from divalent ions as…

Chemical Physics · Physics 2024-02-08 Fenhong Song , Xuan An , Long Ma , Jiakun Zhuang , Yinghua Qiu

Electrolyte theories enable to describe the structural and dynamical properties of simple electrolytes in solution, such as sodium chloride in water. Using these theories for aqueous solutions of charged nanoparticles is a straightforward…

Soft Condensed Matter · Physics 2020-02-03 Vincent Dahirel , Olivier Bernard , Marie Jardat

A molten carbonate fuel cell (MCFC) is an electro-chemical energy conversion technology that runs on natural gas and employs a molten salt electrolyte. In order to keep the electrolyte in this state, the cell must be kept at a temperature…

Materials Science · Physics 2009-09-04 Peter Berg , Justin Findlay

We predict that electrons in an ion channel can gain ultra-relativistic energies by simultaneously interacting with a laser pulse and, counter-intuitively, with a decelerating electric field. The crucial role of the decelerating field is to…

Plasma Physics · Physics 2016-11-01 Vladimir Khudik , Xi Zhang , Gennady Shvets

An in-principle exact working equation to compute electronic affinity and ionization Fukui functions is derived within the $N$-centered (Nc) ensemble extension of density functional theory (DFT). It circumvents the kernel derivative…

Chemical Physics · Physics 2026-02-12 Lucien Dupuy , Emmanuel Fromager

Water is routinely exposed to external electric fields (EFs). Whether, e.g., at physiological conditions, in contact with biological systems, or at the interface of polar surfaces in countless technological and industrial settings, water…

Chemical Physics · Physics 2023-08-10 Giuseppe Cassone , Fausto Martelli

High-concentration aqueous electrolytes have shown promise as candidates for a safer, lower-cost battery system. Ionic conductivity is a key property required in high performing electrolytes; the Advanced Electrolyte Model (AEM) has…

The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-H\"{u}ckel-Onsager theory to provide a detailed description of the electrical conductivity in strong electrolyte solutions. The theory…

Soft Condensed Matter · Physics 2024-09-27 N. N. Kalikin , Yu. A. Budkov

Executing flow estimation using Deep Learning (DL)-based soft sensors on resource-limited IoT devices has demonstrated promise in terms of reliability and energy efficiency. However, its application in the field of wastewater flow…

Signal Processing · Electrical Eng. & Systems 2026-04-22 Tianheng Ling , Chao Qian , Gregor Schiele

With the advancement of nanoscience, silver/silver chloride (Ag/AgCl) electrodes have become widely utilised in microscale and nanoscale fluidic experiments, because of their stability. However, our findings reveal that the dissolution of…

The integration of the coupling effects of intrinsic wettability and surface charge in a nanochannel can cause non-intuitive behavior in the electrokinetic energy conversion processes. We demonstrate that in a nanofluidic device the energy…

Fluid Dynamics · Physics 2015-11-12 Chirodeep Bakli , Suman Chakraborty

Is it possible to design a supramolecular cage that would "solvate" the excess electron in the same fashion in which several solvent molecules do that co-operatively in polar liquids? Two general strategies are outlined for "electron…

Chemical Physics · Physics 2016-09-28 Ilya A. Shkrob , Myran C. Sauer,

Theoretical modeling of electroosmosis through conducting (ideally polarizable) nanochannels is reported. Based on the theory of induced charge electrokinetics, a novel nanofluidic system which possesses both adjustable ion selective…

Fluid Dynamics · Physics 2015-07-23 Cunlu Zhao , Chun Yang

We present a new polarizable force field for aqueous ions (Li+, Na+, K+, Rb+, Cs+, Mg2+, Ca2+, Sr2+ and Cl-) derived from condensed phase ab-initio calculations. We use Maximally Localized Wannier Functions together with a generalized force…

Low temperature water electrolyzers (LTWEs) and low temperature hydrogen fuel cells (LTFCs) present a promising technological strategy for the productions and usages of green hydrogen energy towards a net-zero world. However, the…

Drift-diffusion plasma fluid models are commonly used to simulate electric discharges. Such models can computationally be very efficient if they are combined with explicit time integration. This paper deals with two issues that often arise…

Computational Physics · Physics 2020-02-19 Jannis Teunissen

Harnessing natural evaporation offers a sustainable and untapped pathway for next-generation energy technologies. Here, we present a unified physical and experimental framework for evaporation-driven hydrovoltaic (EDHV) systems that…

Chemical Physics · Physics 2025-11-18 Tarique Anwar , Giulia Tagliabue

Supercapacitors (aka electrostatic double-layer capacitors -- EDLCs) offer excellent power storage capacity and kinetics, but suffer under rapid self-discharge. We introduced a zeolite framework into the active capacitor electrode, with the…

Chemical Physics · Physics 2020-06-04 Samuel Devese , Thomas Nann
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