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We develop a systematic framework for the spin adaptation of the cumulants of p-particle reduced density matrices (RDMs), with explicit constructions for p = 1 to 3. These spin-adapted cumulants enable rigorous treatment of both S_z and S^2…

Chemical Physics · Physics 2025-10-31 Julia Liebert , Christian Schilling , David A. Mazziotti

The ground state energy of a many-electron system can be approximated by an variational approach in which the total energy of the system is minimized with respect to one and two-body reduced density matrices (RDM) instead of many-electron…

Optimization and Control · Mathematics 2017-09-01 Yongfeng Li , Zaiwen Wen , Chao Yang , Yaxiang Yuan

Fermionic reduced density matrices summarize the key observables in fermionic systems. In electronic systems, the two-particle reduced density matrix (2-RDM) is sufficient to determine the energy and most physical observables of interest.…

Quantum Physics · Physics 2023-06-12 Linqing Peng , Xing Zhang , Garnet Kin-Lic Chan

The N-representability problem consists in determining whether, for a given p-body matrix, there exists at least one N-body density matrix from which the p-body matrix can be obtained by contraction, that is, if the given matrix is a p-body…

In this paper we discuss the properties of the reduced density matrix of quantum many body systems with permutational symmetry and present basic quantification of the entanglement in terms of the von Neumann (VNE), Renyi and Tsallis…

Statistical Mechanics · Physics 2015-06-03 V. Popkov , Mario Salerno

The systems with small binding energies and widely distributed in space bound-state wave functions are considered. Because the interaction potential is weak and rather localized compared to the characteristic sizes of wave functions of…

Atomic Physics · Physics 2021-07-07 V. A. Timoshenko , E. A. Yarevsky

In order to extend the density-matrix renormalization-group (DMRG) method to two-dimensional systems, we formulate two alternative methods to prepare the initial states. We find that the number of states that is needed for accurate energy…

Condensed Matter · Physics 2007-05-23 Shoudan Liang , Hanbin Pang

In many of the approximate functionals in one-body reduced density matrix (1RDM) functional theory, the approximate two-body reduced density matrix (2RDM) in the natural orbital representation only depends on the natural occupation numbers.…

Chemical Physics · Physics 2020-11-24 Klaas J. H. Giesbertz

The methods of quantum chemistry and solid state theory to solve the many-body problem are reviewed. We start with the definitions of reduced density matrices, their properties (contraction sum rules, spectral resolutions, cumulant…

Strongly Correlated Electrons · Physics 2007-05-23 P. Ziesche , F. Tasnadi

The two-body t-matrix is calculated directly as function of two vector momenta for different Malfliet-Tjon type potentials. At a few hundred MeV projectile energy the total amplitude is quite a smooth function showing only a strong peak in…

Nuclear Theory · Physics 2019-08-17 Ch. Elster , J. H. Thomas , W. Gloeckle

Many-body wavefunctions usually lie in high-dimensional Hilbert spaces. However, physically relevant states, i.e, the eigenstates of the Schr\"odinger equation are rare. For many-body systems involving only pairwise interactions, these…

Quantum Physics · Physics 2023-01-05 Chaoming Song

Out-of-equilibrium quantum many-body systems exhibit rapid correlation buildup that underlies many emerging phenomena. Exact wave-function methods to describe this scale exponentially with particle number; simpler mean-field approaches…

Machine Learning · Computer Science 2026-05-06 Patrick Egenlauf , Iva Březinová , Sabine Andergassen , Miriam Klopotek

We consider a variational problem for the two-dimensional (2D) Heisenberg and XY models, using a trial state which is constructed as a 2D product of local weights. Variational energy is calculated by use of the the corner transfer matrix…

Statistical Mechanics · Physics 2007-05-23 Y. Nishio , N. Maeshima , A. Gendiar , T. Nishino

Recently, it has been shown, that the pair density of the homogeneous electron gas can be parametrized in terms of 2-body wave functions (geminals), which are scattering solutions of an effective 2-body Schr\"odinger equation. For the…

Strongly Correlated Electrons · Physics 2015-10-28 P. Ziesche , F. Tasnadi

We present here a formulation of the electronic ground-state energy in terms of the second order reduced density matrix, using a duality argument. It is shown that the computation of the ground-state energy reduces to the search of the…

Quantum Physics · Physics 2009-11-13 Eric Cances , Gabriel Stoltz , Mathieu Lewin

This paper is concerned with the pure-state $N$-representability problem for systems under a magnetic field. Necessary and sufficient conditions are given for a spin-density $2 \times 2$ matrix $R$ to be representable by a Slater…

Quantum Physics · Physics 2024-11-19 David Gontier

Classical shadow tomography offers a scalable route to estimating properties of quantum states, but the resulting reduced density matrices (RDMs) often violate constraints that ensure they represent $N$-electron states -- known as…

A new universality class distinct from the standard Wigner-Dyson ones is identified. This class is realized by putting a metallic quantum dot in contact with a superconductor, while applying a magnetic field so as to make the pairing field…

Condensed Matter · Physics 2009-10-28 Alexander Altland , Martin R. Zirnbauer

A summary is presented of the properties of the coefficient matrices formed by expanding the two-body reduced density matrix in a complete set of two-electron wave functions. Calculating the relationship between the many electron wave…

Quantum Physics · Physics 2022-03-02 Nicholas Cox

Random matrix theory is used to represent generic loss of coherence of a fixed central system coupled to a quantum-chaotic environment, represented by a random matrix ensemble, via random interactions. We study the average density matrix…

Quantum Physics · Physics 2009-09-30 T. Gorin , C. Pineda , H. Kohler , T. H. Seligman