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Although the classical density functional theory (DFT) of inhomogeneous fluids was formulated more than four decades ago, its application to broken symmetry phases of molecular systems remained a challenge. Approximate free energy…

Statistical Mechanics · Physics 2026-05-19 Yashwant Singh

Theory can provide important support at all the stages of spectroscopic experiments, from planning the measurements to the interpretation of the results. Such support is particularly valuable for the challenging experiments on heavy,…

Atomic Physics · Physics 2025-09-19 L. F. Pašteka , E. Eliav , M. L. Reitsma , A. Borschevsky

In this project we are interested in performing clustering of observations such that the cluster membership is influenced by a set of predictors. To that end, we employ the Bayesian nonparameteric Common Atoms Model, which is a nested…

Methodology · Statistics 2025-12-11 Md Yasin Ali Parh , Jeremy T. Gaskins

High-throughput spectrometers are capable of producing data sets containing thousands of spectra for a single biological sample. These data sets contain a substantial amount of redundancy from peptides that may get selected multiple times…

Data Structures and Algorithms · Computer Science 2013-01-08 Fahad Saeed , Trairak Pisitkun , Mark A. Knepper , Jason D. Hoffert

Quantum computing promises potential for science and industry by solving certain computationally complex problems faster than classical computers. Quantum computing systems evolved from monolithic systems towards modular architectures…

Quantum Physics · Physics 2023-08-15 Nishant Saurabh , Shantenu Jha , Andre Luckow

The performance of quantum algorithms for ground-state energy estimation is directly impacted by the quality of the initial state, where quality is traditionally defined in terms of the overlap of the input state with the target state. An…

We present the development and implementation of the relativistic coupled cluster linear response theory (CC-LR) which allows the determination of molecular properties arising from time-dependent or time-independent electric, magnetic, or…

In this paper we propose a framework inspired by interacting particle physics and devised to perform clustering on multidimensional datasets. To this end, any given dataset is modeled as an interacting particle system, under the assumption…

Statistical Mechanics · Physics 2012-07-26 Giuliano Armano , Marco Alberto Javarone

A Cholesky decomposition (CD)-based implementation of relativistic two-component coupled-cluster (CC) and equation-of-motion CC (EOM-CC) methods using an exact two-component Hamiltonian augmented with atomic-mean-field spin-orbit integrals…

Chemical Physics · Physics 2023-09-19 Chaoqun Zhang , Filippo Lipparini , Stella Stopkowicz , Jürgen Gauss , Lan Cheng

Pyqcm is a Python/C++ library that implements a few quantum cluster methods with an exact diagonalization impurity solver. Quantum cluster methods are used in the study of strongly correlated electrons to provide an approximate solution to…

Strongly Correlated Electrons · Physics 2024-01-10 Théo N. Dionne , Alexandre Foley , Moïse Rousseau , David Sénéchal

It is observed that the Cauchy integral formula (CIF) can be used to represent holomorphic functions of diagonalizable operators on a finite domain. This forms the theoretical foundation for applying various operators in the form of a…

Chemical Physics · Physics 2025-07-09 Ke Liao

Covalent-organic frameworks (COFs) are intriguing platforms for designing functional molecular materials. Here, we present a computational study based on van der Waals dispersion-corrected hybrid density functional theory (DFT-D) to design…

Materials Science · Physics 2017-09-07 Srimanta Pakhira , Kevin P. Lucht , Jose L. Mendoza-Cortes

Efficient computation of molecular integrals and Hartree-Fock energy remains a central topic in quantum-chemistry algorithm development. Although many sophisticated open-source packages are available, understanding their implementations…

Chemical Physics · Physics 2025-10-30 Mario Hernández Vera

We present our experience of porting the code used in the wave-packet convergent-close-coupling (WP-CCC) approach to run on NVIDIA V100 and AMD MI250X GPUs. The WP-CCC approach is a method used in the field of ion-atom collision physics to…

Computational Physics · Physics 2024-03-08 I. B. Abdurakhmanov , N. W. Antonio , M. Cytowski , A. S. Kadyrov

Simulating quantum circuits (QC) on high-performance computing (HPC) systems has become an essential method to benchmark algorithms and probe the potential of large-scale quantum computation despite the limitations of current quantum…

Generalized gradient approximated (GGA) density functional theory (DFT) typically overestimates polarizability and bond-lengths, and underestimates force constants of covalent bonds. To overcome this problem we show that one can use…

Chemical Physics · Physics 2016-06-29 O. Anatole von Lilienfeld

We propose a network of open-dissipative quantum oscillators with optical error correction circuits. In the proposed network, the squeezed/anti-squeezed vacuum states of the constituent optical parametric oscillators below the threshold…

Quantum Physics · Physics 2021-08-18 Sam Reifenstein , Satoshi Kako , Farad Khoyratee , Timothée Leleu , Yoshihisa Yamamoto

Practical knowledge about troubleshooting and error handling in trapped-ion systems remains largely undocumented and held within individual labs, creating a barrier to cross-disciplinary collaboration towards engineering scalable systems.…

Quantum Physics · Physics 2025-05-05 Monet Tokuyama Friedrich , Alto Osada , Rodney Van Meter , Shota Nagayama

An efficient approach to calculate approximate pure-state and transition reduced density matrices in the framework of the multireference relativistic Fock-space coupled cluster (FS CC) theory is proposed. The method is based on the…

Computational Physics · Physics 2025-06-12 Alexander V. Oleynichenko , Andrei Zaitsevskii , Leonid V. Skripnikov , Ephraim Eliav

Unitary coupled cluster (UCC), originally developed as a variational alternative to the popular traditional coupled cluster method, has seen a resurgence as a functional form for use on quantum computers. However, the number of excitors…

Chemical Physics · Physics 2021-01-07 Maria-Andreea Filip , Alex J. W. Thom