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I consider a specially designed simple mechanical problem where "particle acceleration" due to an external force creates sound waves. Theoretical description of this phenomenon should provide the total energy conservation. To introduce…

General Physics · Physics 2013-08-06 Vladimir Kalitvianski

For the large and chemically diverse GMTKN55 benchmark suite, we have studied the performance of density-corrected density functional theory (HF-DFT), compared to self-consistent DFT, for several pure and hybrid GGA and meta-GGA…

Chemical Physics · Physics 2021-03-29 Golokesh Santra , Jan M. L. Martin

he contact angle of a liquid droplet on a surface under partial wetting conditions differs for a nanoscopically rough or periodically corrugated surface from its value for a perfectly flat surface. Wenzel's relation attributes this…

Soft Condensed Matter · Physics 2020-06-24 Sergei A. Egorov , Kurt Binder

We combine density-functional theory with density-matrix functional theory to get the best of both worlds. This is achieved by range separation of the electronic interaction which permits to rigorously combine a short-range density…

Chemical Physics · Physics 2015-05-19 Daniel R. Rohr , Julien Toulouse , Katarzyna Pernal

Adiabatic connection models (ACMs), which interpolate between the limits of weak and strong interaction, are powerful tools to build accurate exchange-correlation functionals. If the exact weak-interaction expansion from second-order…

Chemical Physics · Physics 2022-09-08 S. Śmiga , F. Della Sala , P. Gori-Giorgi , E. Fabiano

The basis-set correction method based on density-functional theory consists in correcting the energy calculated by a wave-function method with a given basis set by a density functional. This basis-set correction density functional…

Chemical Physics · Physics 2023-07-05 Diata Traore , Emmanuel Giner , Julien Toulouse

In this tutorial presentation, we give a comprehensive introduction into the Gutzwiller variational approach and its merger with the density functional theory. The merits of this method are illustrated by a discussion of results for…

Strongly Correlated Electrons · Physics 2012-07-30 Jörg Bünemann

In the framework of the Density Functional Theory for superconductors, we study the restoration of the particle number symmetry by means of the projection technique. Conceptual problems are outlined and numerical difficulties are discussed.…

Nuclear Theory · Physics 2008-12-18 J. Dobaczewski , M. V. Stoitsov , W. Nazarewicz , P. -G. Reinhard

Over the past two decades, many studies in the Density Functional Theory context revealed new aspects and properties of strongly correlated superfluid quantum systems in numerous configurations that can be simulated in experiments. This was…

Quantum Gases · Physics 2022-07-08 Antoine Boulet , Gabriel Wlazłowski , Piotr Magierski

The nonrelativistic reduction of the self-consistent covariant density functional theory is realized for the first time with the similarity renormalization group (SRG) method. The reduced nonrelativistic Hamiltonian and densities are…

Nuclear Theory · Physics 2020-08-19 Z. X. Ren , P. W. Zhao

We consider an analytically solvable model of two interacting electrons that allows for the calculation of the exact exchange-correlation kernel of time-dependent density functional theory. This kernel, as well as the corresponding density…

Strongly Correlated Electrons · Physics 2017-05-04 Luis Cort , Daniel Karlsson , Giovanna Lani , Robert van Leeuwen

The accurate prediction of electronic response properties of extended molecular systems has been a challenge for conventional, explicit density functionals. We demonstrate that a self-interaction correction implemented rigorously within…

Materials Science · Physics 2009-11-13 T. Körzdörfer , M. Mundt , S. Kümmel

We present a formally exact van der Waals inclusive electronic structure theory, called FDE-vdW, based on the Frozen Density Embedding formulation of subsystem Density-Functional Theory. In subsystem DFT, the energy functional is composed…

Chemical Physics · Physics 2015-06-19 Ruslan Kevorkyants , Henk Eshuis , Michele Pavanello

We prove an adiabatic theorem for general densities of observables that are sums of local terms in finite systems of interacting fermions, without periodicity assumptions on the Hamiltonian and with error estimates that are uniform in the…

Mathematical Physics · Physics 2019-01-08 Domenico Monaco , Stefan Teufel

The thorough treatment of electron-lattice interactions from first principles is one of the main goals in condensed matter physics. While the commonly applied adiabatic Born-Oppenheimer approximation is sufficient for describing many…

In their famous paper Kohn and Sham formulated a formally exact density-functional theory (DFT) for the ground-state energy and density of a system of $N$ interacting electrons, albeit limited at the time by certain troubling…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Miquel Huix-Rotllant , Mark E. Casida

The charge delocalization error, besides nondynamic correlation, has been a major challenge to density functional theory. Contemporary functionals undershoot the dissociation of symmetric charged dimers A2+, a simple but stringent test,…

Chemical Physics · Physics 2021-07-26 Emil Proynov , Jing Kong

In recent years we have witnessed a growing interest in various non-equilibrium systems described in terms of stochastic non-linear field theories. In some of those systems like the KPZ and related models, the interesting behavior is in the…

Disordered Systems and Neural Networks · Physics 2008-04-21 Moshe Schwartz , Eytan Katzav

Practical density functional theory (DFT) owes its success to the groundbreaking work of Kohn and Sham that introduced the exact calculation of the non-interacting kinetic energy of the electrons using an auxiliary mean-field system.…

Chemical Physics · Physics 2023-11-17 P. del Mazo-Sevillano , J. Hermann

The consistency relations in large scale structure relate the lower-order correlation functions with their higher-order counterparts. They are direct outcome of the underlying symmetries of a dynamical system and can be tested using data…

Cosmology and Nongalactic Astrophysics · Physics 2017-06-23 Dipak Munshi , Donough Regan