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Density functional theory (DFT) has greatly expanded our ability to affordably compute and understand electronic ground states, by replacing intractable {\em ab initio} calculations by models based on paradigmatic physics from high- and…

Chemical Physics · Physics 2023-03-29 Tim Gould , Derk P. Kooi , Paola Gori-Giorgi , Stefano Pittalis

Model Hamiltonians with long-range interaction yield energies that are corrected taking into account the universal behavior of the electron-electron interaction at short range. Although the intention of the paper is to explore the…

Chemical Physics · Physics 2020-10-28 Andreas Savin

The classic density-functional theory (DFT) formalism introduced by Hohenberg, Kohn, and Sham in the mid-1960s, is based upon the idea that the complicated N-electron wavefunction can be replaced with the mathematically simpler 1-electron…

Chemical Physics · Physics 2015-05-30 M. E. Casida , M. Huix-Rotllant

A new variational method for studying the equilibrium states of an interacting particles system has been proposed. The statistical description of the system is realized by means of a density matrix. This method is used for description of…

General Physics · Physics 2014-12-19 Boris Bondarev

A strong-coupling-perturbation theory around the Atomic Limit of the Anderson model with large $U$ for a localized $f$-orbital coupled to a conduction-electron band is presented. Although an auxiliary-particle representation is {\em not}…

Condensed Matter · Physics 2009-10-28 Jan Brinckmann

In this paper we consider the {\it Density Functional Theory} (DFT) framework, where a functional of the form $$F_\eps(\rho)=\eps T(\rho)+bC(\rho)-U(\rho)$$ has to be minimized in the class of non-negative measures $\rho$ which have a…

Mathematical Physics · Physics 2025-07-02 Guy Bouchitté , Giuseppe Buttazzo , Thierry Champion , Luigi De Pascale

Current-density-functional theory is used to calculate ionization energies of current-carrying atomic states. A perturbative approximation to full current-density-functional theory is implemented for the first time, and found to be…

Materials Science · Physics 2009-11-10 E. Orestes , T. Marcasso , K. Capelle

The goal of the present account is to review our efforts to obtain and apply a ``collective'' Hamiltonian for a few, approximately decoupled, adiabatic degrees of freedom, starting from a Hamiltonian system with more or many more degrees of…

Nuclear Theory · Physics 2009-09-25 G. Do Dang , A. Klein , N. R. Walet

The self-consistent theory of Anderson localization of quantum particles or classical waves in disordered media is reviewed. After presenting the basic concepts of the theory of Anderson localization in the case of electrons in disordered…

Disordered Systems and Neural Networks · Physics 2015-05-18 P. Wölfle , D. Vollhardt

We adapt the Goldstone theorem to study spontaneous symmetry breaking in relativistic theo- ries at finite charge density. It is customary to treat systems at finite density via non-relativistic Hamiltonians. Here we highlight the…

High Energy Physics - Theory · Physics 2013-01-10 Alberto Nicolis , Federico Piazza

A density functional theory is developed for fermions in one dimension, interacting via a delta-function. Such systems provide a natural testing ground for questions of principle, as the local density approximation should work well for…

Other Condensed Matter · Physics 2007-05-23 R. J. Magyar , K. Burke

We introduced a new electron density n({\epsilon}) by projecting the spatial electron density n(r) onto the energy coordinate {\epsilon} defined with the external potential \upsion (r) of interest. Then, a density functional theory (DFT)…

Chemical Physics · Physics 2018-02-20 Hideaki Takahashi

A fermion ground state energy functional is set up in terms of particle density, relative pair density, and kinetic energy tensor density. It satisfies a minimum principle if constrained by a complete set of compatibility conditions. A…

Chemical Physics · Physics 2009-10-17 Bin Liu , Jerome K. Percus

A new perturbational approach to spectral and thermal properties of strongly correlated electron systems is presented: The Anderson model is reexamined for $U\to\infty$\,, and it is shown that an expansion of Green's functions with respect…

Condensed Matter · Physics 2009-10-22 Jan Brinckmann

An explicit expression for the quadratic density-response function of a many-electron system is obtained in the framework of the time-dependent density-functional theory, in terms of the linear and quadratic density-response functions of…

Materials Science · Physics 2009-11-10 V. U. Nazarov , J. M. Pitarke , C. S. Kim , Y. Takada

Density functional theory (DFT) is the de facto approach for predicting self-consistent-field electronic structures of ground-state configurations of complex atoms, molecules, and solids and providing their property data for materials…

Materials Science · Physics 2024-01-30 Zi-Kui Liu

An extension of the relativistic density functional approach to the equation of state for strongly interacting matter is suggested which generalizes a recently developed modified excluded-volume mechanism to the case of temperature and…

Nuclear Theory · Physics 2018-02-16 Stefan Typel , David Blaschke

We present and discuss some ideas concerning an ``average-pair-density functional theory'', in which the ground-state energy of a many-electron system is rewritten as a functional of the spherically and system-averaged pair density. These…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

A novel approach to the description of superconductors in thermal equilibrium is developed within a formally exact density-functional framework. The theory is formulated in terms of three ``densities'': the ordinary electron density, the…

Exact density functionals for the exchange and correlation energies are approximated in practical calculations for the ground-state electronic structure of a many-electron system. An important exact constraint for the construction of…

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