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The counterintuitive Mpemba effect, wherein a hotter system cools faster, critically lacks a general macroscopic theory. Here, starting from linear irreversible thermodynamics, we formulate a generalized Newton's cooling law,…

Statistical Mechanics · Physics 2026-05-21 Yun-Qian Lin , Z. C. Tu , Yu-Han Ma

As the temperature of a cooling object decreases as it relaxes to thermal equilibrium, it is intuitively assumed that a hot object should take longer to cool than a warm one. Yet, some 2,300 years ago, Aristotle observed that "to cool hot…

Statistical Mechanics · Physics 2020-08-07 Avinash Kumar , John Bechhoefer

The Mpemba effect refers to the surprising observation where, under certain conditions, a far-from-equilibrium state can relax toward equilibrium faster than a state closer to equilibrium. A paradigmatic example is provided by the curious…

Quantum Physics · Physics 2025-03-25 Stefano Longhi

The Mpemba effect occurs when a hot system cools faster than an initially colder one, when both are refrigerated in the same thermal reservoir. Using the custom built supercomputer Janus II, we study the Mpemba effect in spin glasses and…

The Mpemba effect, an example of anomalous thermal relaxations, occurs when a system prepared at a hot temperature overtakes an identical system prepared at a warm temperature and cools down faster to the environment's temperature. We study…

Statistical Mechanics · Physics 2023-08-10 Saikat Bera , Matthew R. Walker , Marija Vucelja

Loosely speaking, the Mpemba effect appears when hotter systems cool sooner or, in a more abstract way, when systems further from equilibrium relax faster. In this paper, we investigate the Mpemba effect in a molecular gas with nonlinear…

Soft Condensed Matter · Physics 2022-05-31 Alberto Megías , Andrés Santos , Antonio Prados

Water exhibits many unique properties compared to other liquids, with some of these explained and others remaining enigmatic. Among them, it was proposed and extensively debated that hot water would freeze faster than cold water. Numerous…

Chemical Physics · Physics 2025-12-02 James D. Brownridge , Matthieu Zinet , Paul Sotta , Francois Ganachaud

The highly complicated nature of far from equilibrium systems can lead to a complete breakdown of the physical intuition developed in equilibrium. A famous example of this is the Mpemba effect, which states that non-equilibrium states may…

Statistical Mechanics · Physics 2024-07-03 Colin Rylands , Katja Klobas , Filiberto Ares , Pasquale Calabrese , Sara Murciano , Bruno Bertini

The Mpemba effect occurs when two samples at different initial temperatures evolve in such a way that the temperatures cross each other during the relaxation towards equilibrium. In this paper we show the emergence of a Mpemba-like effect…

Statistical Mechanics · Physics 2021-05-17 Rubén Gómez González , Nagi Khalil , Vicente Garzó

We demonstrate the quantum Mpemba effect in a quantum dot coupled to two reservoirs, described by the Anderson model. We show that the system temperatures starting from two different initial values (hot and cold), cross each other at finite…

Statistical Mechanics · Physics 2023-08-25 Amit Kumar Chatterjee , Satoshi Takada , Hisao Hayakawa

The behavior of systems far from equilibrium is often complex and unpredictable, challenging and sometimes overturning the physical intuition derived from equilibrium scenarios. One striking example of this is the Mpemba effect, which…

Quantum Physics · Physics 2025-04-02 Stefano Longhi

We study the time evolution of thermodynamic observables that characterise the dissipative nature of thermal relaxation after an instantaneous temperature quench. Combining tools from stochastic thermodynamics and large-deviation theory, we…

Statistical Mechanics · Physics 2023-03-06 Jan Meibohm , Massimiliano Esposito

In a recent paper in Scientific Reports, Burridge \& Linden misinterpret the Mpemba effect as a statement about the rate of cooling of liquid water, when it is in fact a statement about the rate of freezing of water. Debunking an obviously…

Popular Physics · Physics 2017-01-30 J. I. Katz

We consider the thermal relaxation of a particle in a piecewise-constant potential landscape subject to thermal fluctuations in the overdamped limit. We study the connection between the occurrence of the Mpemba effect, the presence of…

Statistical Mechanics · Physics 2021-12-08 Matthew Walker , Marija Vucelja

We review the Mpemba effect, where intially hot water freezes faster than initially cold water. While the effect appears impossible at first sight, it has been seen in numerous experiments, was reported on by Aristotle, Francis Bacon, and…

History and Philosophy of Physics · Physics 2011-11-10 Monwhea Jeng

We demonstrate the existence, as well as determine the conditions, of a Mpemba effect - a counterintuitive phenomenon where a hotter system equilibrates faster than a cooler system when quenched to a cold temperature - in anisotropically…

Statistical Mechanics · Physics 2022-03-14 Apurba Biswas , V. V. Prasad , R. Rajesh

We report the emergence of a giant Mpemba effect in the uniformly heated gas of inelastic rough hard spheres: The initially hotter sample may cool sooner than the colder one, even when the initial temperatures differ by more than one order…

Despite decades of research, the Mpemba Effect challenges scientists, prompting further investigation and refinement of existing hypotheses. This work uses optical tools such as thermography to analyze and study the Mpemba effect on drops.…

The Mpemba effect refers to the anomalous relaxation of a quantum state that, despite being initially farther from equilibrium, relaxes faster than a closer counterpart. Detecting such a quantum Mpemba effect typically requires full…

Statistical Mechanics · Physics 2025-12-03 Pitambar Bagui , Arijit Chatterjee , Bijay Kumar Agarwalla

The classical Mpemba effect is the counterintuitive phenomenon where hotter water freezes faster than colder water due to the breakdown of Newton's law of cooling after a sudden temperature quench. The genuine nonequilibrium post-quench…

Quantum Physics · Physics 2026-05-01 Marco Peluso , Reinhold Egger , Andrea Nava