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This work investigates the real-time estimation of the state-of-charge (SoC) of Lithium-ion (Li-ion) cells for reliable, safe and efficient utilization. A novel attractive ellipsoid based sliding-mode observer (AESMO) algorithm is designed…

Systems and Control · Electrical Eng. & Systems 2020-08-18 Anirudh Nath , Raghvendra Gupta , Rohit Mehta , Supreet Singh Bahga , Amit Gupta , Shubhendu Bhasin

Despite significant potential as energy storage materials for electric vehicles due to their combination of high energy density per unit cost and reduced environmental and ethical concerns, Co-free lithium ion batteries based off layered Mn…

Transition-metal compounds pose serious challenges to first-principles calculations based on density-functional theory (DFT), due to the inability of most approximate exchange-correlation functionals to capture the localization of valence…

Materials Science · Physics 2019-03-13 Matteo Cococcioni , Nicola Marzari

Development of energy storage technologies that can exhibit higher energy densities, better safety, and lower supply-chain constraints than the current state-of-the-art Li-ion batteries (LIBs) is crucial for our transition into sustainable…

Materials Science · Physics 2025-10-13 Vijay Choyal , Debsundar Dey , Gopalakrishnan Sai Gautam

Fast scanning-speed and low-power-consumption are becoming progressively more and more important in realizing high-performance chiplet optical phased arrays (OPAs). Here, we establish an integrated OPA based on thin-film lithium…

All-solid-state Li-ion batteries promise safer electrochemical energy storage with larger volumetric and gravimetric energy densities. A major concern is the limited electrochemical stability of solid electrolytes and related detrimental…

Unraveling the atomistic and the electronic structure of solid-liquid interfaces is the key to the design of new materials for many important applications, from heterogeneous catalysis to battery technology. Density functional theory (DFT)…

Materials Science · Physics 2022-01-25 Marco Eckhoff , Jörg Behler

A 3D mechanical stable scaffold is shown to accommodate the volume change of a high specific capacity nickel-tin nanocomposite Li-ion battery anode. When the nickel-tin anode is formed on an electrochemically inactive conductive scaffold…

Materials Science · Physics 2015-04-28 Huigang Zhang , Tan Shi , Paul V. Braun

A simple method has been used to synthesize nanostructured La0.5Ba0.5CoO3 (LBCO) powders, by confining chemical precursors into the pores of polycarbonate filters. The proposed method allows us to obtain powders formed by crystallites of…

Applied Physics · Physics 2019-09-25 Augusto E. Mejía Gómez , Diego G. Lamas , Ana Gabriela Leyva , Joaquín Sacanell

Recently, considerable efforts have been made on research and improvement for Ni-rich lithium-ion batteries to meet the demand from vehicles and grid-level large-scale energy storage. Development of next-generation high-performance…

The rapid spread of Lithium-ions batteries (LiBs) for electric vehicles calls for the development of accurate physical models for Battery Management Systems (BMSs). In this work, the electrochemical Single Particle Model (SPM) for a…

Systems and Control · Electrical Eng. & Systems 2023-11-30 Andrea Trivella , Matteo Corno , Stefano Radrizzani , Sergio M. Savaresi

Li-ion batteries contain excess anode area to improve manufacturability and prevent Li plating. These overhang areas in graphite electrodes are active but experience decreased Li+ flux during cycling. Over time, the overhang and the anode…

Micro-solid oxide fuel cells based on thin films have strong potential for use in portable power devices. However, devices based on silicon substrates typically involve thin-film metallic electrodes which are unstable at high temperatures.…

Superior stability and safety are key promises attributed to all-solid-state batteries (ASSBs) containing solid-state electrolyte (SSE) compared to their conventional counterparts utilizing liquid electrolyte. To unleash the full potential…

Materials Science · Physics 2020-01-23 Tobias Binninger , Aris Marcolongo , Matthieu Mottet , Valéry Weber , Teodoro Laino

Van der Waals (vdW) heterostructures have attracted intense interest worldwide as they offer several routes to design materials with novel features and wide-ranging applications. Unfortunately, at present, vdW heterostructures are…

Computational Physics · Physics 2024-05-14 Amreen Bano , Dan T Major

La0.6Sr0.4Fe0.8Mn0.2O3 (LSFM) compound is synthesized by Sol-gel method and evaluated as a cathode material for the intermediate temperature solid oxide fuel cell (IT-SOFC). X-ray diffraction (XRD) indicates that the LSFM has a Rhombohedral…

Applied Physics · Physics 2019-10-22 F. Yadollahi Farsani , M. Jafari , E. Shahsavari , H. Salamati

Lithium ion batteries (LIB) can feature reactive anodes that operate at low potentials, such as lithium metal or silicon, passivated by solid electrolyte interphase (SEI) films. SEI is known to evolve over time as cycling proceeds. In this…

Materials Science · Physics 2016-05-24 Kevin Leung , Fernando Soto , Kie Hankins , Perla B. Balbuena , Katharine L. Harrison

We report the electrochemical sodium-ion kiinetics and distribution of relaxation time (DRT) analysis of a newly designed mixed polyanionic NaFe$_{1.6}$V$_{0.4}$(PO$_{4}$)(SO$_{4}$)$_{2}$@CNT composite as a cathode. The specific capacity of…

Chemical Physics · Physics 2024-04-22 Jayashree Pati , Rajendra S. Dhaka

We develop a continuum phase-field model for the simulation of diffusion limited solid-solid phase transformations during lithium insertion in LiFePO4-nano-particles. The solid-solid phase boundary between the LiFePO4 (LFP)-phase and the…

Materials Science · Physics 2018-07-20 Michael Fleck , Holger Federmann , Evgeny Pogorelov

An in situ study of deformation, fracture, and fatigue behavior of silicon as a lithium-ion battery electrode material is presented. Thin films (100-200 nm) of silicon are cycled in a half-cell configuration with lithium metal foil as…

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