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A geometrically nonlinear continuum mechanical theory is formulated for deformation and failure behaviors of amorphous polymers. The model seeks to capture material response over a range of loading rates, temperatures, and stress states…
Constitutive equations are derived for the time-dependent behavior of particle-reinforced elastomers at isothermal loading with finite strains. A rubbery polymer is modelled as a network of macromolecules bridged by junctions which can slip…
In this work we will derive an anisotropic generalisation of the finitely extensible chain model, due to Kuhn and Gr\"un, which is well known in rubber elasticity. This provides a chain energy that couples elastic behaviour to a probability…
The stretching of a polymer chain by a large scale chaotic flow is considered. The steady state which emerges as a balance of the turbulent stretching and anharmonic resistance of the chain is quantitatively described, i.e. the dependency…
A constitutive relation between stress and strain relative to a reference state is the basic assumption of elasticity theory. However, in living matter, force generation is governed by motor molecule activity, which does not depend on…
We develop a geometric formulation of thermodynamic response in the classical Ising model by defining a curvature field over the control manifold spanned by inverse temperature $\beta$ and magnetic field $h$. We show that the existence of…
The black hole entropy formula applied to local Rindler horizon at each spacetime point has been used in the literature to derive the Einstein field equation as an equation of state of a thermodynamical system of spacetime. In the present…
Thermodynamics unavoidably contains fluctuation theory, expressible in terms of a unique thermodynamic information metric. This metric produces an invariant thermodynamic Riemannian curvature scalar $R$ which, in fluid and spin systems,…
Stochastic thermodynamics provides a useful set of tools to analyze and constrain the behavior of far from equilibrium systems. In this paper, we report an application of ideas from stochastic thermodynamics to the problem of membrane…
In this paper we formulate a geometric theory of thermal stresses. Given a temperature distribution, we associate a Riemannian material manifold to the body, with a metric that explicitly depends on the temperature distribution. A change of…
We address the physics of nematic liquid crystalline elastomers randomly crosslinked in the isotropic state. To do this, we construct a phenomenological effective replica Hamiltonian in terms of two order-parameter fields: one for the…
We present a thermodynamic theory of the Kovacs effect based on the idea that the configurational degrees of freedom of a glass-forming material are driven out of equilibrium with the heat bath by irreversible thermal contraction and…
The isotropic Hencky strain energy appears naturally as a distance measure of the deformation gradient to the set SO(n) of rigid rotations in the canonical left-invariant Riemannian metric on the general linear group GL(n). Objectivity…
In frameworks of scaling theory of phase transitions and critical phenomena the structure of melt-crystallized polymers is discussed. The model constructed follows drawing polymeric materials and dissipating the energy during the transition…
The origin of equilibrium gravitational configurations is sought in terms of the stability of their trajectories, as described by the curvature of their Lagrangian configuration manifold. We focus on the case of spherical systems, which are…
The thermal and phase properties of a multifragmentation model which uses clusters as degrees of freedom, are explored as a function of isospin. A good qualitative agreement is found with the phase diagram of asymmetric nuclear matter as…
In this work we consider conformal gauge transformations of the geometric structure of thermodynamic fluctuation theory. In particular, we show that the Thermodynamic Phase Space is naturally endowed with a non-integrable connection,…
We present an isothermal fluctuating nonlinear hydrodynamic theory of crystallization in molecular liquids. A dynamic coarse-graining technique is used to derive the velocity field, a phenomenology, which allows a direct coupling between…
It is shown here that fracture after a brief plastic strain, typically of a few percents, is a necessary consequence of the polycrystalline nature of the materials. The polycrystal undergoing plastic deformation is modeled as a flowing…
We investigate the stability of bounded self-gravitating systems in the canonical ensemble by using a thermodynamical approach. Our study extends the earlier work of Padmanabhan [Astrophys. J. Supp. 71, 651 (1989)] in the microcanonical…