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Harnessing short-lived photoexcited electron-hole pairs in metal nanostructures has the potential to define a new phase of optoelectronics, enabling control of athermal mechanisms for light harvesting, photodetection and photocatalysis. To…

Hot carriers are energetic photo-excited carriers driving a large range of chemico-physical mechanisms. At the nanoscale, an efficient generation of these carriers is facilitated by illuminating plasmonic antennas. However, the ultrafast…

Harvesting non-equilibrium hot carriers from photo-excited metal nanoparticles has enabled plasmon-driven photochemical transformations and tunable photodetection with resonant nanoantennas. Despite numerous studies on the ultrafast…

Realizing the potential of plasmonic hot carrier harvesting for energy conversion and photodetection requires new materials that resolve the bottleneck of extracting carriers prior to energy relaxation within the metal. Using…

Materials Science · Physics 2022-12-12 Sushant Kumar , Christian Multunas , Ravishankar Sundararaman

The relaxation dynamics of hot carriers in silicon (100) is studied via a novel holistic approach based on phase-resolved transient absorption spectroscopy with few-cycle optical pulses. After excitation by a sub-5 fs light pulse, strong…

Materials Science · Physics 2021-07-21 Martin Wörle , Alexander W. Holleitner , Reinhard Kienberger , Hristo Iglev

Understanding the dynamics of photoexcited carriers is essential for advancing photoelectronic device design. Photon absorption generates electron-hole pairs, and subsequent scatterings can induce ultrafast thermalization within a…

Materials Science · Physics 2025-01-14 Zhuoqun Wen , Haiyu Zhu , Wenhao Liu , Zhi Wang , Wen Xiong , Xingzhan Wei

Surface plasmon mediated hot carrier generation is widely utilized for the manipulation of the electron-photon interactions in many types of optoelectronic devices including solar cells, photodiodes, and optical modulators. A diversity of…

We employ nonlinear autocorrelation measurements to investigate plasmon-assisted hot carrier dynamics generated in optical gold antennas. We demonstrate that surface plasmons enable a nonlinear formation of hot carriers, providing thus a…

Hot electrons generated from the decay of localized surface plasmons in metallic nanostructures have the potential to transform photocatalysis, photodetection and other optoelectronic applications. However, the understanding of hot-carrier…

The coherent oscillations of mobile charge carriers near the surface of good conductors-surface plasmons-are been exploited in many applications in information technologies, clean energy, high-density data storage, photovoltaics, chemistry,…

Mesoscale and Nanoscale Physics · Physics 2023-12-20 Jacob Khurgin , Anton Yu. Bykov , Anatoly V. Zayats

Generation of energetic (hot) electrons is an intrinsic property of any plasmonic nanostructure under illumination. Simultaneously, a striking advantage of metal nanocrystals over semiconductors lies in their very large absorption cross…

Mesoscale and Nanoscale Physics · Physics 2017-08-31 Lucas V. Besteiro , Xiang-Tian Kong , Zhiming Wang , Gregory V. Hartland , Alexander O. Govorov

Hot carrier generation in metals, where high-energy electron-hole pairs are produced via plasmon excitation, has emerged as a promising mechanism for photoelectric conversion and photocatalysis. However, conventional theories often describe…

Optics · Physics 2025-05-27 Soshun Inoue , Takeshi Inaoka , Hajime Ishihara

Direct measurements of photoexcited carrier dynamics in nickel are made using few-femtosecond extreme ultraviolet (XUV) transient absorption spectroscopy at the nickel M$_{2,3}$ edge. It is observed that the core-level absorption lineshape…

A physically transparent unified theory of optically and plasmon induced hot carrier generation in metals is developed with all the relevant mechanisms included. Analytical expressions that estimate the carrier generation rates, their…

Optics · Physics 2019-06-19 Jacob B Khurgin

Extraction of non-equilibrium hot carriers generated by plasmon decay in metallic nanostructures is an increasingly exciting prospect for utilizing plasmonic losses, but the search for optimum plasmonic materials with long-lived carriers is…

Materials Science · Physics 2018-05-29 Adela Habib , Fred Florio , Ravishankar Sundararaman

Harnessing non-equilibrium hot carriers from plasmonic metal nanostructures constitutes a vibrant research field. It promises to enable control of activity and selectivity of photochemical reactions, especially for solar fuel generation.…

For many of the envisioned optoelectronic applications of graphene it is crucial to understand the sub-picosecond carrier dynamics immediately following photoexcitation, as well as the effect on the electrical conductivity - the…

The hot carrier cooling occurs in most photoexcitation-induced phase transitions (PIPTs), but its role has often been neglected in many theoretical simulations as well as in proposed mechanisms. Here, by including the previously ignored hot…

Computational Physics · Physics 2021-08-05 Wen-Hao Liu , Jun-Wei Luo , Shu-Shen Li , Lin-Wang Wang

Understanding the interplay between illumination and the electron distribution in metallic nanostructures is a crucial step towards developing applications such as plasmonic photo-catalysis for green fuels, nano-scale photo-detection and…

Optics · Physics 2019-07-23 Yonatan Dubi , Yonatan Sivan

Above-threshold light emission from plasmonic tunnel junctions, when emitted photons have energies significantly higher than the energy scale of the incident electrons, has attracted much recent interest in nano-optics, while the underlying…

Mesoscale and Nanoscale Physics · Physics 2020-12-08 Longji Cui , Yunxuan Zhu , Mahdiyeh Abbasi , Arash Ahmadivand , Burak Gerislioglu , Peter Nordlander , Douglas Natelson
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