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A very popular ab-initio scheme to calculate electronic properties in solids is the use of hybrid functionals in density functional theory (DFT) that mixes a portion of Fock exchange with DFT functionals. In spite of their success, a major…

Materials Science · Physics 2015-05-20 Miguel A. L. Marques , Julien Vidal , Micael J. T. Oliveira , Lucia Reining , Silvana Botti

One of the central problems in quantum mechanics is to determine the ground state properties of a system of electrons interacting via the Coulomb potential. Since its introduction by Hohenberg, Kohn, and Sham, Density Functional Theory…

Quantum Physics · Physics 2010-09-28 Norbert Schuch , Frank Verstraete

A degenerate perturbation $k\cdot p$ approach for effective mass calculations is implemented in the all-electron density functional theory (DFT) package WIEN2k. The accuracy is tested on major group IVA, IIIA-VA, and IIB-VIA semiconductor…

Materials Science · Physics 2022-01-06 Oleg Rubel , Fabien Tran , Xavier Rocquefelte , Peter Blaha

The aim of this review article is to assess the descriptive capabilities of the Hubbard-rooted LDA+U method and to clarify the conditions under which it can be expected to be most predictive. The paper illustrates the theoretical foundation…

Materials Science · Physics 2013-09-17 Burak Himmetoglu , Andrea Floris , Stefano de Gironcoli , Matteo Cococcioni

High performance computing (HPC) is a powerful tool to accelerate the Kohn-Sham density functional theory (KS-DFT) calculations on modern heterogeneous supercomputers. Here, we describe a massively extreme-scale parallel and portable…

Computational Physics · Physics 2020-04-20 Wei Hu , Xinming Qin , Caiqing Jiang , Junshi Chen , Hong An , Weile Jia , Fang Li , Xin Liu , Dexun Chen , Jinlong Yang

The Hubbard model, which augments independent-electron band theory with a single parameter to describe electron-electron correlations, is widely regarded to be the `standard model' of condensed matter physics. The model has been remarkably…

Strongly Correlated Electrons · Physics 2016-02-17 S. M. Griffin , P. Staar , T. C. Schulthess , M. Troyer , N. A. Spaldin

This study introduces the Homotopy Perturbation Sumudu Transform Method (HPSTM), a novel hybrid approach combining the Sumudu transform with homotopy perturbation to solve nonlinear fractional partial differential equations (FPDEs),…

Numerical Analysis · Mathematics 2025-07-18 Maryam Jalili

Theoretical material investigation based on density functional theory (DFT) has been a breakthrough in the last century. Nevertheless, the optical properties calculated by DFT generally show poor agreement with experimental results…

Materials Science · Physics 2019-07-17 Mitsutoshi Nishiwaki , Hiroyuki Fujiwara

We present an efficient computational approach to perform real-space electronic structure calculations using an adaptive higher-order finite-element discretization of Kohn-Sham density-functional theory (DFT). To this end, we develop an…

Computational Physics · Physics 2015-06-05 Phani Motamarri , Michael R Nowak , Kenneth Leiter , Jaroslaw Knap , Vikram Gavini

Density-corrected density functional theory (DC-DFT) is enjoying substantial success in improving semilocal DFT calculations in a wide variety of chemical problems. This paper provides the formal theoretical framework and assumptions for…

Chemical Physics · Physics 2019-08-19 Stefan Vuckovic , Suhwan Song , John Kozlowski , Eunji Sim , Kieron Burke

In this article, we propose p and hp least-squares spectral element methods for one-dimensional elliptic boundary layer problems. Stability estimates are derived and we design numerical schemes based on minimizing the residuals in the sense…

Numerical Analysis · Mathematics 2025-08-26 Akhlaq Husain , Aliya Kazmi , Subhashree Mohapatra , Ziya Uddin

The efficient computation of observables beyond the total energy is a key challenge and opportunity for fault-tolerant quantum computing approaches in quantum chemistry. Here we consider the symmetry-adapted perturbation theory (SAPT)…

Multisite local orbitals, which are formed from linear combinations of pseudo-atomic orbitals from a target atom and its neighbor atoms, have been introduced in the large-scale density functional theory calculation code CONQUEST. Multisite…

Materials Science · Physics 2014-11-11 Ayako Nataka , David R. Bowler , Tsuyoshi Miyazaki

Recently we proposed an information entropy based method for electronic structure calculations within the density-matrix functional theory(DMFT) (Phys. Rev. Lett. 128, 013001), dubbed as $i$-DMFT. Comments have been raised regarding the…

Quantum Physics · Physics 2022-07-07 Jian Wang , Evert Jan Baerends

We present a density matrix approach for computing global solutions of restricted open-shell Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems.…

Chemical Physics · Physics 2014-04-22 Srikant Veeraraghavan , David A. Mazziotti

This paper studies the computational and statistical aspects of quantile and pseudo-Huber tensor decomposition. The integrated investigation of computational and statistical issues of robust tensor decomposition poses challenges due to the…

Statistics Theory · Mathematics 2023-09-07 Yinan Shen , Dong Xia

Most realistic calculations of moderately correlated materials begin with a ground-state density functional theory (DFT) calculation. While Kohn-Sham DFT is used in about 40,000 scientific papers each year, the fundamental underpinnings are…

Strongly Correlated Electrons · Physics 2022-09-26 Kieron Burke , John Kozlowski

Computing with high-dimensional (HD) vectors, also referred to as $\textit{hypervectors}$, is a brain-inspired alternative to computing with scalars. Key properties of HD computing include a well-defined set of arithmetic operations on…

Signal Processing · Electrical Eng. & Systems 2018-04-25 Fabio Montagna , Abbas Rahimi , Simone Benatti , Davide Rossi , Luca Benini

Density functional theory (DFT) is an efficient instrument for describing a wide range of nanoscale phenomena: wetting transition, capillary condensation, adsorption, etc. In this paper, we suggest a method for obtaining the equilibrium…

Computational Physics · Physics 2021-06-18 Yuriy Kanygin , Irina Nesterova , Pavel Lomovitskiy , Aleksey Khlyupin

We present the extension of the Tinker-HP package (Lagard\`ere et al., Chem. Sci., 2018,9, 956-972) to the use of Graphics Processing Unit (GPU) cards to accelerate molecular dynamics simulations using polarizable many-body force fields.…

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