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We report a comprehensive characterization of the magnetic, electrical transport, spectral, and thermal properties of single-crystalline Zintl-type material EuIn2P2. The compound crystallizes with a hexagonal unit cell (space group P63/mmc)…

Eu-based Zintl-phase materials EuA$_2$Pn$_2$ (A = Mg, In, Cd, Zn; Pn = Bi, Sb, As, P) have generated significant recent interest owing to the complex interplay of magnetism and band topology. Here, we investigated the electronic, magnetic,…

Strongly Correlated Electrons · Physics 2022-07-27 Santanu Pakhira , Farhan Islam , Evan O'Leary , M. A. Tanatar , Thomas Heitmann , R. Prozorov , Adam Kaminski , David Vaknin , D. C. Johnston

The intermetallic compound Eu$_5$In$_2$Sb$_6$, an antiferromagnetic material with nonsymmorphic crystalline structure, is investigated by magnetic, electronic transport and specific heat measurements. Being a Zintl phase, insulating…

Eu$_5$In$_2$Sb$_6$ is an orthorhombic non-symmorphic small band gap semiconductor with three distinct Eu$^{2+}$ sites and two low-temperature magnetic phase transitions. The material displays one of the greatest (negative)…

We report magnetic and transport properties of single-crystalline EuZn$_{2}$P$_{2}$, which has trigonal CaAl$_2$Si$_2$-type crystal structure and orders antiferromagnetically at $\approx$23~K. Easy $ab$-plane magneto-crystalline anisotropy…

Materials Science · Physics 2023-08-14 Karan Singh , Shovan Dan , A. Ptok , T. A. Zaleski , O. Pavlosiuk , P. Wiśniewski , D. Kaczorowski

Strong electron correlations underlie a plethora of electronic and magnetic components and devices and are often used to identify and probe novel ground states in quantum materials. Herein we report a magnetic phase crossover in EuMn2P2, an…

Narrow-gap rare-earth Zintl phases frequently exhibit fascinating physical phenomena due to their various crystal structures, complex magnetic properties, and tunable transport behaviors. Here we report the synthesis, magnetic,…

Materials Science · Physics 2024-11-27 Zhiyu Zhou , Ziwen Wang , Xiyu Chen , Jia-Yi Lu , Junchao Zhang , Xiong Luo , Guang-Han Cao , Shuai Dong , Zhi-Cheng Wang

Various topological phases, including topological insulators, topological semimetals, and topological superconductors, along with the controllable topological phase transitions, have attracted considerable attention due to their promising…

Materials Science · Physics 2025-02-28 Bo-Xuan Li , Ziyin Song , Zhong Fang , Zhijun Wang , Hongming Weng

We investigate single crystals of the trigonal antiferromagnet EuZn$_2$P$_2$ ($P\overline{3}m1$) by means of electrical transport, magnetization measurements, X-ray magnetic scattering, optical reflectivity, angle-resolved photoemission…

We report results of a magneto-optical investigation of the Zintl-phase compound EuIn$_2$P$_2$. The compound orders magnetically at $T_C$=24 K and exhibits concomitant large magnetoresistance effects. For $T\le$50 K and increasing magnetic…

Strongly Correlated Electrons · Physics 2012-01-11 F. Pfuner , L. Degiorgi. H. R. Ott , A. D. Bianchi , Z. Fisk

Colossal magnetoresistance (CMR) has been observed across many Eu$^{2+}$-based materials; however, its origin is not completely understood. Here we investigate the antiferromagnetic insulator EuZn$_2$P$_2$ through single crystal x-ray…

Magnetic topological materials are a class of compounds which can host massless electrons controlled by the magnetic order. One such compound is EuZn$_2$Sb$_2$, which has recently garnered interest due to its strong interplay between the Eu…

Strongly Correlated Electrons · Physics 2026-02-17 Yu Wei Soh , Hsiang Lee , Eugen Weschke , Shinichi Nishihaya , Mikhael T. Sayat , Masaki Uchida , Jian-Rui Soh

The magnetic and electronic properties of the layered Zintl-phase compound EuAl$_2$Ge$_2$ crystallizing in the trigonal CaAl$_2$Si$_2$-type structure are reported. Our neutron-diffraction measurements show that EuAl$_2$Ge$_2$ undergoes…

While $\sim$30% of materials are reported to be topological, topological insulators are rare. Magnetic topological insulators (MTI) are even harder to find. Identifying crystallographic features that can host the coexistence of a…

EuZn$_2$P$_2$ was reported to be an insulating antiferromagnet with $T_\mathrm{N}$ of 23.5 K. In this study, single crystals of EuZn$_2$P$_2$ exhibiting metallic behavior and a ferromagnetic order of 72 K ($T_\mathrm{C}$) are successfully…

Materials Science · Physics 2024-06-11 Xiyu Chen , Wuzhang Yang , Jia-Yi Lu , Zhiyu Zhou , Zhi Ren , Guang-Han Cao , Shuai Dong , Zhi-Cheng Wang

Magnetic topological insulator provide a prominent material platform for quantum anomalous Hall physics and axion electrodynamics. However, the lack of material realizations with cleanly gapped surfaces hinders technological utilization of…

Materials Science · Physics 2022-06-28 Nicodemos Varnava , Tanya Berry , Tyrel M. McQueen , David Vanderbilt

We report on the thermodynamic and transport properties of the rare-earth Zintl compound Eu$_5$Sn$_2$As$_6$, which orders as a canted antiferromagnetic magnetic semiconductor at 10.3~K. The system also displays a complex cascade of magnetic…

Strongly Correlated Electrons · Physics 2024-07-09 R. P. Day , K. Yamakawa , L. Pritchard Cairns , J. Singleton , Monica Allen , Joel E. Moore , James G. Analytis

We report a comprehensive high-pressure study on the antiferromagnetic topological insulator EuSn2As2 up to 21.1 GPa through measurements of synchrotron x-ray diffraction, electrical resistance, magnetic resistance, and Hall transports…

Strongly Correlated Electrons · Physics 2021-10-08 Hualei Sun , Cuiqun Chen , Yusheng Hou , Yu Gong , Mengwu Huo , Lisi Li , Jia Yu , Wanping Cai , Naitian Liu , Ruqian Wu , Dao-Xin Yao , Meng Wang

The rational combination of existing magnetic topological compounds presents a promising route for designing new topological materials. We report the synthesis and comprehensive characterization of the layered quaternary intergrowth…

We report the design, synthesis, crystal structure, and physical properties of a layered intergrowth compound, Eu$_2$CuMn$_2$P$_3$. The structure of Eu$_2$CuMn$_2$P$_3$ features an alternating arrangement of hexagonal EuCuP block layers and…

Materials Science · Physics 2025-06-03 Xiyu Chen , Ziwen Wang , Wuzhang Yang , Jia-Yi Lu , Zhiyu Zhou , Zhi Ren , Guang-Han Cao , Shuai Dong , Zhi-Cheng Wang
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