Related papers: A new protonated molecule discovered in TMC-1: HCC…

Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated…

We report the first detection of HC$_{5}$$^{15}$N with the $J=9-8$ rotational line from the cyanopolyyne peak in Taurus Molecular Cloud-1 (TMC-1 CP) using the 45-m radio telescope of the Nobeyama Radio Observatory. The column density of…

Almost 200 different species have been detected in the interstellar medium (ISM) during the last decades, revealing not only simple species but complex molecules with more than 6 atoms. Other exotic compounds, like the weakly-bound dimer…

Two consecutive rotational transitions of the long cyanopolyyne HC11N, J=39-38, and J=38-37, have been detected in the cold dust cloud TMC-1 at the frequencies expected from recent laboratory measurements by Travers et al. (1996), and at…

Using radio observations with the Green Bank Telescope, evidence has now been found for a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based on additional observations of an ongoing, large-scale,…

The protonated form of CO2, HOCO+, is assumed to be an indirect tracer of CO2 in the millimeter/submillimeter regime since CO2 lacks a permanent dipole moment. Here, we report the detection of two rotational emission lines (4 0,4-3 0,3) and…

Using the QUIJOTE line survey in the 32.0-50.4 GHz range, we report the discovery of the molecule CH2CCHC4H towards the prestellar cold core TMC-1 in the Taurus region. We also present a rigorous detection of CH2CCHC3N, along with its…

Supernova remnants (SNRs) can exert strong influence on molecular clouds (MCs) through interaction by shock wave and cosmic rays. In this paper, we present our mapping observation of HCO+ and HCN 1-0 lines towards 13 SNRs interacting with…

We present the first detection of HCNS (thiofulminic acid) in space with the QUIJOTE line survey in the direction of TMC-1. We performed a complete study of the isomers of CHNS and CHNO, including NCO and NCS. The derived column densities…

We review the reactions involving HCN and HNC in dark molecular clouds to elucidate new chemical sources and sinks of these isomers. We find that the most important reactions for the HCN-HNC system are Dissociative Recombination (DR)…

We present the first identification in interstellar space of the propargyl radical (CH2CCH). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. The six strongest hyperfine components of the 2,0,2-1,0,1…

We have carried out CO J=2-1 and CO J=3-2 observations toward Tycho's supernova remnant (SNR) using the KOSMA 3m-Telescope. From these observations we identified three molecular clouds (MCs) around the SNR. The small cloud in the southwest…

We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and…

We have observed HNC 1-0, CN 1-0 and 2-1 line emission in a sample of 13 IR luminous (LIRGs, L_IR > 10E11 Lo) starburst and Seyfert galaxies. HNC 1-0 is detected in 9, CN 1-0 is detected in 10 and CN 2-1 in 7 of the galaxies. We also report…

We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight towards the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H35Cl and H37Cl, are observed using…

Complex (iso-)nitrile molecules, such as CH3CN and HC3N, are relatively easily detected in our Galaxy and in other galaxies. We constrain their chemistry through observations of two positions in the Horsehead edge: the photo-dissociation…

We report the detection of methyl ketene towards TMC-1 with the QUIJOTE line survey. Nineteen rotational transitions with rotational quantum numbers ranging from J = 3 up to J = 5 and Ka =< 2 were identified in the frequency range 32.0-50.4…

We investigated the chemistry of nitrogen--containing species, principally isotopomers of CN, HCN, and HNC, in a sample of pre-protostellar cores. We used the IRAM 30 m telescope to measure the emission in rotational and hyperfine…

We report the detection of the sulfur-bearing species NCS, HCCS, H2CCS, H2CCCS, and C4S for the first time in space. These molecules were found towards TMC-1 through the observation of several lines for each species. We also report the…

HNC and HCN, typically used as dense gas tracers in molecular clouds, are a pair of isomers that have great potential as a temperature probe because of temperature dependent, isomer-specific formation and destruction pathways. Previous…