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Time-dependent and constituent-specific spectral changes in soft near edge X-ray spectroscopy (XAS) of an [Fe/MgO]$_8$ metal/insulator heterostructure upon laser excitation are analyzed at the O K-edge with picosecond time resolution. The…

Phase Resolved Optical Emission Spectroscopy (PROES) measurements combined with 1d3v Particle-in-Cell/Monte Carlo Collision (PIC/MCC) simulations are performed to investigate the excitation dynamics in low-pressure capacitively coupled…

Plasma Physics · Physics 2023-07-21 Aranka Derzsi , Mate Vass , Ranna Masheyeva , Benedek Horvath , Zoltan Donko , Peter Hartmann

Strongly correlated materials such as transition metal oxides (TMOs) often exhibit large satellites in their x-ray photoemission (XPS) and x-ray absorption spectra (XAS). These satellites arise from localized charge-transfer (CT)…

Strongly Correlated Electrons · Physics 2015-06-17 E. Klevak , J. J. Kas , J. J. Rehr

This chapter introduces the use of X-ray absorption spectroscopy (XAS) in studying the local electronic and atomic structure of high-entropy materials. The element selectivity of XAS makes it particularly suitable to address the challenges…

Materials Science · Physics 2024-11-12 Alexei Kuzmin

Exploring and understanding ultrafast processes at the atomic level is a scientific challenge. Femtosecond X-ray Absorption Spectroscopy (XAS) is an essential experimental probing technic, as it can simultaneously reveal both electronic and…

A novel method and experimental configuration are proposed that allow the collection of high-quality X-ray absorption spectroscopy (XAS) data in transmission mode on a standard laboratory diffractometer. This configuration makes use of…

Instrumentation and Detectors · Physics 2025-09-23 Milen Gateshki , Charalampos Zarkadas , Detlef Beckers

A deep understanding of molecular photo-transformations is challenging because of the complex interaction between the configurations of electrons and nuclei. An initial optical excitation dissipates energy into electronic and structural…

Time- and angle-resolved photoelectron spectroscopy with 13 fs temporal resolution is used to follow the different stages in the formation of a Fermi-Dirac distributed electron gas in graphite after absorption of an intense 7 fs laser…

A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas…

Chemical Physics · Physics 2014-12-05 Y. Fu , S. Poizeau , A. Bertei , C. Qi , A. Mohanram , J. D. Pietras , M. Z. Bazant

In this study, we present a well-defined methodology for conducting Operando X-ray absorption near-edge structure spectroscopy (XANES) in conjunction with transmission X-ray nano computed tomography (TXM-nanoCT) experiments on the…

Time-resolved X-ray absorption spectroscopy (TR-XAS), based on laser-pump/X-ray probe method, is powerful in capturing the change of geometrical and electronic structure of the absorbing atom upon excitation. TR-XAS data analysis is…

Chemical Physics · Physics 2017-03-08 Fei Zhan , Ye Tao , Haifeng Zhao

A method of using X-ray absorption spectroscopy (XAS) together with resolved grazing incidence geometry for depth profiling atomic, electronic, chemical or magnetic local structures in thin films is presented. The quantitative deconvolution…

Advanced X-ray spectroscopic techniques are widely recognized as state-of-the-art tools for probing the electronic structure, bonding, and chemical environments of the heaviest elements in the periodic table. In this study, we employ X-ray…

Oxygen vacancies, especially their distribution, are directly coupled to the electromagnetic properties of oxides and related emergent functionalities that have implication in device applications. Here using a homoepitaxial strontium…

Strongly Correlated Electrons · Physics 2017-09-22 Saikat Das , Bo Wang , Ye Cao , Myung Rae Cho , Yeong Jae Shin , Sang Mo Yang , Lingfei Wang , Minu Kim , Sergei V. Kalinin , Long-Qing Chen , Tae Won Noh

While image generation with diffusion models has achieved a great success, generating images of higher resolution than the training size remains a challenging task due to the high computational cost. Current methods typically perform the…

Computer Vision and Pattern Recognition · Computer Science 2025-02-28 Zhengqiang Zhang , Ruihuang Li , Lei Zhang

X-ray absorption spectroscopy (XAS) has gained popularity in recent years as it probes matter with high spatial and elemental sensitivity. However, the theoretical modelling of XAS is a challenging task since XAS spectra feature a fine…

Chemical Physics · Physics 2023-02-03 Lukas Konecny , Stanislav Komorovsky , Jan Vicha , Kenneth Ruud , Michal Repisky

X-ray absorption fine structure (XAFS) and x-ray emission spectroscopy (XES) are advanced x-ray spectroscopies that impact a wide range of disciplines. However, unlike the majority of other spectroscopic methods, XAFS and XES are…

Key technologies in energy conversion and storage, sensing and chemical synthesis rely on a detailed knowledge about charge transfer processes at electrified solid-liquid interfaces. However, these interfaces continuously evolve as a…

Materials Science · Physics 2022-12-12 Reshma R. Rao , Iris C. G. van den Bosch , Christoph Baeumer

Freestanding oxide films offer significant potential for integrating exotic quantum functionalities with semiconductor technologies. However, their performance is critically limited by surface roughness and interfacial imperfection caused…

Materials Science · Physics 2025-11-04 Huaicheng Yuan , Yu-Chen Liu , Li-Shu Wang , Zehao Dong , Jan-Chi Yang , Zhen Chen

Resonant inelastic x-ray scattering (RIXS) is a widely used spectroscopic technique, providing access to the electronic structure and dynamics of atoms, molecules, and solids. However, RIXS requires a narrow bandwidth x-ray probe to achieve…