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We present the Trust Region Adversarial Functional Subdifferential (TRAFS) algorithm for constrained optimization of nonsmooth convex Lipschitz functions. Unlike previous methods that assume a subgradient oracle model, we work with the…

Optimization and Control · Mathematics 2024-01-30 Kai Jia , Martin Rinard

Convex and nonconvex finite-sum minimization arises in many scientific computing and machine learning applications. Recently, first-order and second-order methods where objective functions, gradients and Hessians are approximated by…

Optimization and Control · Mathematics 2020-05-12 Stefania Bellavia , Natasa Krejic , Benedetta Morini

We design a dynamically-weighted state-averaged constrained CASSCF to treat \ul{e}lectrons or \ul{h}oles moving between $n$ molecular fragments (where $n$ can be larger than 2). Within such a so-called eDSCn/hDSCn approach, we consider…

Computational Physics · Physics 2025-09-01 Tian Qiu , Joseph E. Subotnik

We present a Gaussian-basis implementation of orbital-free density-functional theory (OF-DFT) in which the trust-region image method (TRIM) is used for optimization. This second-order optimization scheme has been constructed to provide…

Chemical Physics · Physics 2021-09-15 Matthew S. Ryley , Michael Withnall , Tom J. P. Irons , Trygve Helgaker , Andrew M. Teale

In many important machine learning applications, the standard assumption of having a globally Lipschitz continuous gradient may fail to hold. This paper delves into a more general $(L_0, L_1)$-smoothness setting, which gains particular…

Optimization and Control · Mathematics 2025-02-07 Chenghan Xie , Chenxi Li , Chuwen Zhang , Qi Deng , Dongdong Ge , Yinyu Ye

Historically speaking, it is hard to balance the global and local efficiency of second-order optimization algorithms. For instance, the classical Newton's method possesses excellent local convergence but lacks global guarantees, often…

Optimization and Control · Mathematics 2025-11-11 Yuntian Jiang , Chuwen Zhang , Bo Jiang , Yinyu Ye

While the superior performance of second-order optimization methods such as Newton's method is well known, they are hardly used in practice for deep learning because neither assembling the Hessian matrix nor calculating its inverse is…

Machine Learning · Computer Science 2020-09-16 Siyuan Shen , Tianjia Shao , Kun Zhou , Chenfanfu Jiang , Feng Luo , Yin Yang

Optimizing tensor networks with standard first-order methods often leads to slow convergence and entrapment in local minima. Although second-order optimization offers enhanced robustness, explicitly constructing the full Hessian matrix is…

Quantum Physics · Physics 2026-04-23 Isabel Nha Minh Le , Roeland Wiersema , Christian B. Mendl

Under interpolation-type assumptions such as the strong growth condition, stochastic optimization methods can attain convergence rates comparable to full-batch methods, but their performance, particularly for SGD, remains highly sensitive…

Optimization and Control · Mathematics 2026-04-16 Aike Yang , Hao Wang

We consider trust-region methods for solving optimization problems where the objective is the sum of a smooth, nonconvex function and a nonsmooth, convex regularizer. We extend the global convergence theory of such methods to include…

Optimization and Control · Mathematics 2025-01-10 Minh N. Dao , Hung M. Phan , Lindon Roberts

We propose a stochastic first-order trust-region method with inexact function and gradient evaluations for solving finite-sum minimization problems. Using a suitable reformulation of the given problem, our method combines the inexact…

Optimization and Control · Mathematics 2022-10-25 Stefania Bellavia , Natasa Krejic , Benedetta Morini , Simone Rebegoldi

The complete active space self-consistent field (CASSCF) method is the principal approach employed for studying strongly correlated systems. However, exact CASSCF can only be performed on small active spaces of ~20 electrons in ~20 orbitals…

Computational Physics · Physics 2021-12-22 Daniel S. Levine , Diptarka Hait , Norm M. Tubman , Susi Lehtola , K. Birgitta Whaley , Martin Head-Gordon

The convergence property of a stochastic algorithm for the self-consistent field (SCF) calculations of electron structures is studied. The algorithm is formulated by rewriting the electron charges as a trace/diagonal of a matrix function,…

Numerical Analysis · Mathematics 2023-04-20 Taehee Ko , Xiantao Li

In this work, we introduce a novel stochastic second-order method, within the framework of a non-monotone trust-region approach, for solving the unconstrained, nonlinear, and non-convex optimization problems arising in the training of deep…

Optimization and Control · Mathematics 2024-01-18 Natasa Krejic , Natasa Krklec Jerinkic , Angeles Martinez , Mahsa Yousefi

We develop a trust-region method for minimizing the sum of a smooth term $f$ and a nonsmooth term $h$), both of which can be nonconvex. Each iteration of our method minimizes a possibly nonconvex model of $f + h$ in a trust region. The…

Optimization and Control · Mathematics 2021-08-04 Aleksandr Y. Aravkin , Robert Baraldi , Dominique Orban

This paper presents strong worst-case iteration and operation complexity guarantees for Riemannian adaptive regularized Newton methods, a unified framework encompassing both Riemannian adaptive regularization (RAR) methods and Riemannian…

Optimization and Control · Mathematics 2025-05-14 Chenyu Zhang , Rujun Jiang

We present a new second order complete active space self-consistent field implementation to converge wavefunctions for both large active spaces and large atomic orbital (AO) bases. Our algorithm decouples the active space wavefunction…

Chemical Physics · Physics 2017-08-23 Qiming Sun , Jun Yang , Garnet Kin-Lic Chan

We introduce a new sequential methodology to calibrate the fixed parameters and track the stochastic dynamical variables of a state-space system. The proposed method is based on the nested hybrid filtering (NHF) framework of [1], that…

Computation · Statistics 2021-03-24 Sara Pérez-Vieites , Joaquín Míguez

We target the problem of finding a local minimum in non-convex finite-sum minimization. Towards this goal, we first prove that the trust region method with inexact gradient and Hessian estimation can achieve a convergence rate of order…

Optimization and Control · Mathematics 2019-03-06 Zebang Shen , Pan Zhou , Cong Fang , Alejandro Ribeiro

Adaptive cubic regularization (ARC) methods for unconstrained optimization compute steps from linear systems involving a shifted Hessian in the spirit of the Levenberg-Marquardt and trust-region methods. The standard approach consists in…

Optimization and Control · Mathematics 2021-04-01 Jean-Pierre Dussault , Dominique Orban