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Reactions at solid-water interfaces play a foundational role in water treatment systems, catalysis, chemical separations, and in predicting chemical fate and transport in the environment. Over the last century, experimental measurements and…

Chemical Physics · Physics 2022-12-14 Anastasia G. Ilgen , Kevin Leung , Louise J. Criscenti , Jeffery A. Greathouse

With molecular simulation for water and a tunable hydrophobic substrate, we apply the instantaneous interface construction [A. P. Willard and D. Chandler, J. Phys. Chem. B, 114, 1954 (2010)] to examine the similarity between a water-vapor…

Soft Condensed Matter · Physics 2015-01-21 Adam P. Willard , David Chandler

We investigate the interfacial dynamics involved in the impact of a droplet on a liquid-liquid system, which involves the impingement of an immiscible core liquid drop from a vertical separation onto an interfacial shell liquid layer…

Fluid Dynamics · Physics 2024-08-20 Akash Chowdhury , Sirshendu Misra , Sushanta K. Mitra

Performing molecular dynamics simulations, we investigate the enormous slowdowns of water dynamics when approaching a glass transition or a solid interface. We show that both effects can be described on common grounds within a theoretical…

Soft Condensed Matter · Physics 2015-06-19 Felix Klameth , Michael Vogel

We present a coarse-grained model for ionic surfactants in explicit aqueous solutions, and study by computer simulation both the impact of water content on the morphology of the system, and the consequent effect of the formed interfaces on…

Soft Condensed Matter · Physics 2015-03-16 Samuel Hanot , Sandrine Lyonnard , Stefano Mossa

Hydrophobic solid-water interfaces underpin processes in nanofluidics, electrochemistry, and energy technologies. Microscopic insights into these systems are often inferred from our understanding of the air-water interface, which is assumed…

We study the mobility of extended objects (rods) on a spherical liquid-liquid interface to show how this quantity is modified in a striking manner by both the curvature and the topology of the interface. We present theoretical calculations…

Soft Condensed Matter · Physics 2009-11-13 Mark L. Henle , R. McGorty , A. D. Dinsmore , Alex J. Levine

Water/solid interfaces are relevant to a broad range of physicochemical phenomena and technological processes such as corrosion, lubrication, heterogeneous catalysis and electrochemistry. Although many fields have contributed to rapid…

Materials Science · Physics 2013-01-31 Javier Carrasco , Andrew Hodgson , Angelos Michaelides

We study the structure and dynamics of liquid water in contact with Pd and Au (111) surfaces using \emph{ab initio} molecular dynamics simulations with and without van der Waals interactions. Our results show that the structure of water at…

Chemical Physics · Physics 2014-03-27 Luana S. Pedroza , Adrien Poissier , M. -V. Fernández-Serra

Nanofluidics is an emerging field offering innovative solutions for energy harvesting and desalination. The efficiency of these applications depends strongly on liquid-solid slip, arising from a favorable ratio between viscosity and…

Soft Condensed Matter · Physics 2022-08-16 Cecilia Herrero , Gabriele Tocci , Samy Merabia , Laurent Joly

Water is essential for the activity of proteins. However, the effect of the properties of water on the behavior of proteins is only partially understood. Recently, several experiments have investigated the relation between the dynamics of…

Biological Physics · Physics 2015-03-17 Giancarlo Franzese , Valentino Bianco , Svilen Iskrov

We perform molecular dynamics simulations of 512 water-like molecules that interact via the TIP5P potential and are confined between two smooth hydrophobic plates that are separated by 1.10 nm. We find that the anomalous thermodynamic…

Soft Condensed Matter · Physics 2009-11-11 Pradeep Kumar , Sergey V. Buldyrev , Francis W. Starr , Nicolas Giovambattista , H. Eugene Stanley

The air-water interface plays a crucial role in many aspects of science, because of its unique properties, such as a two-dimensional hydrogen bond (HB) network and completely different HB dynamics compared to bulk water. However, accurately…

Materials Science · Physics 2024-10-01 Gang Huang , Jie Huang

Transport of material across liquid interfaces is ubiquitous for living cells and is also a crucial step in drug delivery and in many industrial processes. The fluids that are present on either side of the interfaces will usually have…

Soft Condensed Matter · Physics 2023-05-24 Chao Feng , John J. Molina , Matthew S. Turner , Ryoichi Yamamoto

The air-water interface is a highly prevalent phase boundary with a far-reaching impact on natural and industrial processes. Water molecules behave differently at the interface compared to the bulk, exhibiting anisotropic orientational…

In this work, we conducted molecular dynamics simulations to study the fracture mechanism of ice crystals in a bulk phase and at ice-ice interfaces at the atomistic scale. We show that there exists a narrow disordered interfacial layer…

Chemical Physics · Physics 2019-07-23 A. Afshar , J. Zhong , D. S. Thompson , D. Meng

Vibrations can dynamically stabilize otherwise unstable liquid interfaces and produce new dynamic equilibria, called vibro-equilibria. Typically, the vibrations are homogeneous in the liquid and the liquid interface remains approximately…

Fluid Dynamics · Physics 2022-05-04 Benjamin Apffel , Christian Wilkinson , Emmanuel Fort

Platinum-water interfaces underpin many electrochemical energy conversion processes. However, despite decades of research, the real-space liquid structure of these interfaces remains elusive. Using three-dimensional atomic force microscopy…

Materials Science · Physics 2025-09-09 Yitong Li , Qian Ai , Lalith Krishna Samanth Bonagiri , Yingjie Zhang

Interfaces in phase-separated driven liquids are one example of how energy input at the single-particle level changes the long-length-scale material properties of nonequilibrium systems. Here, we measure interfacial fluctuations in…

Statistical Mechanics · Physics 2019-03-27 Clara del Junco , Suriyanarayanan Vaikuntanathan

Direct Numerical Simulations of two superposed fluids in a channel with a textured surface on the lower wall have been carried out. A parametric study varying the viscosity ratio between the two fluids has been performed to mimic both {\bf…

Fluid Dynamics · Physics 2019-05-22 I. Arenas , E. Garcia , M. K. Fu , P. Orlandi , M. Hultmark , S. Leonardi