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In a previous contribution (Mol. Phys. {\bf 103}, xxxx, 2005), we established the suitability of density functional theory (DFT) for the calculation of molecular anharmonic force fields. In the present work, we have assessed a wide variety…

Chemical Physics · Physics 2007-05-23 A. Daniel Boese , Wim Klopper , Jan M. L. Martin

A detailed exploration of the $f$-atomic orbital occupancy space for UO$_2$ is performed using a first principles approach based on density functional theory (DFT), employing a full hybrid functional within a systematic basis set.…

Strongly Correlated Electrons · Physics 2022-01-05 Laura E. Ratcliff , Luigi Genovese , Hyowon Park , Peter B. Littlewood , Alejandro Lopez-Bezanilla

The ground-state phase diagrams of the three-orbital t2g Hubbard model are studied using a Hartree-Fock approximation. First, a complete set of multipolar order parameters for t2g models defined in terms of the effective total angular…

Strongly Correlated Electrons · Physics 2022-01-05 Naoya Chikano , Shintaro Hoshino , Hiroshi Shinaoka

Magnetic phases are commonly identified through macroscopic magnetization, yet many ordered states, including antiferromagnets and altermagnets, possess a vanishing net moment despite distinct local spin structure. We show that such an…

Mesoscale and Nanoscale Physics · Physics 2026-01-14 Rishith Reddy , Parveen Kumar , Ankur Das

We employ density functional theory to study in detail the crystallization of super-paramagnetic particles in two dimensions under the influence of an external magnetic field that lies perpendicular to the confining plane. The field induces…

Soft Condensed Matter · Physics 2009-11-13 Sven van Teeffelen , Hartmut Löwen , Christos N. Likos

The magnetic ground state is crucial for the applications of the two-dimension magnets as it decides fundamental magnetic properties of the material, such as magnetic order, magnetic transition temperature, and low-energy excitation of the…

Materials Science · Physics 2024-12-06 Yue-Fei Hou , Shujing Li , Xinlong Yang , Wei Jiang , Qiuhao Wang , Fawei Zheng , Zhen-Guo Fu , Ping Zhang

The practical utility of M{\o}ller-Plesset (MP) perturbation theory is severely constrained by the use of Hartree-Fock (HF) orbitals. It has recently been shown that use of regularized orbital-optimized MP2 orbitals and scaling of MP3…

Chemical Physics · Physics 2021-01-06 Adam Rettig , Diptarka Hait , Luke W. Bertels , Martin Head-Gordon

Accurate predictions of the properties of transition metal oxides using density functional theory (DFT) calculations are essential for the computational design of energy materials. In this work, we investigate the anomalous reversal of the…

We study field-induced phase transitions in the two-dimensional dipolar Ising ferromagnet with a specific ratio between the exchange and dipolar constants, $\delta=1$, which exhibits a stripe-ordered phase with the width of one lattice unit…

Statistical Mechanics · Physics 2018-12-26 Hisato Komatsu , Yoshihiko Nonomura , Masamichi Nishino

We study the magnetic phases of two coupled two-dimensional electron gases in order to determine under what circumstances these phases may occur in real semiconductor quantum wells and what the experimental properties of the broken-symmetry…

Condensed Matter · Physics 2007-05-23 P. I. Tamborenea , R. J. Radtke , S. Das Sarma

Approximate density functional theory (DFT) suffers from many-electron self- interaction error, otherwise known as delocalization error, that may be diagnosed and then corrected through elimination of the deviation from exact piecewise…

Materials Science · Physics 2016-11-08 Terry Z. H. Gani , Heather J. Kulik

In contrast to the original Kohn-Sham (KS) formalism, we propose a density functional theory (DFT) with fractional orbital occupations for the study of ground states of many-electron systems, wherein strong static correlation is shown to be…

Chemical Physics · Physics 2015-06-03 Jeng-Da Chai

A broken symmetry ground state without any magnetic moments has been calculated by means of local-density-approximation to density functional theory plus a local exchange term, the so-called LDA+$U$ approach, for URu$_{2}$Si$_{2}$. The…

Strongly Correlated Electrons · Physics 2013-05-29 Francesco Crichhio , fredrik Bultmark , Oscar Granas , Lars Nordstrom

We discuss an efficient scheme for obtaining spin-polarized quasi-particle excitation energies within the general framework of the density functional theory (DFT). Our approach is to correct the DFT eigenvalues via the electrostatic energy…

Strongly Correlated Electrons · Physics 2007-10-11 B. Barbiellini , A. Bansil

We study finite-temperature magnetic phases of three-component mixtures of ultracold fermions with repulsive interactions in optical lattices with simple cubic or square geometry by means of dynamical mean-field theory (DMFT). We focus on…

Quantum Gases · Physics 2014-06-04 Andrii Sotnikov , Walter Hofstetter

Density Functional Theory (DFT) calculations were used to evaluate polarity of group III nitrides, such as aluminum nitride (AlN), gallium nitride (GaN) and indium nitride (InN) providing physically sound quantitative measure of polarity of…

Mesoscale and Nanoscale Physics · Physics 2011-11-17 Pawel Strak , Pawel Kempisty , Konrad Sakowski , Stanislaw Krukowski

The density driven Mott transition is studied by means of Dynamical Mean-Field Theory in the Hubbard-Holstein model, where the Hubbard term leading to the Mott transition is supplemented by an electron-phonon (e-ph) term. We show that an…

Strongly Correlated Electrons · Physics 2007-08-07 M. Capone , G. Sangiovanni , C. Castellani , C. Di Castro , M. Grilli

An impurity solver for the dynamical mean field (DMFT) study of the Mott insulators is proposed, which is based on the second order perturbation of the hybridization function. After carefully benchmarking it with Quantum Monte Carlo results…

Strongly Correlated Electrons · Physics 2009-11-10 Jia Ning Zhuang , Qing Mei Liu , Zhong Fang , Xi Dai

Distortions of the oxygen octahedra influence the fundamental electronic structure of perovskite oxides, such as their bandwidth and exchange interactions. Utilizing a fully ab-initio methodology based on density functional theory plus…

Strongly Correlated Electrons · Physics 2021-07-02 Alexander Hampel , Jeremy Lee-Hand , Antoine Georges , Cyrus E. Dreyer

We present a model to describe complex phases observed at mesoscopic scales in ultrathin magnetic films. The model is based on the interaction between dipolar as well as quadrupolar magnetic moments. In the special case of strong…

Statistical Mechanics · Physics 2010-05-21 Daniel G. Barci , Daniel A. Stariolo