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Calculations combining density functional theory (DFT) and dynamical mean-field theory (DMFT) for transition metal (TM) oxides and similar compounds usually focus on improving the description of the TM $d$ states. Here, we emphasize the…

Strongly Correlated Electrons · Physics 2025-03-26 Alberto Carta , Anwesha Panda , Claude Ederer

Electron correlation and long-range magnetic ordering have a significant impact on the electronic structure and physical properties of solids. Here, we investigate the electronic structure of ilmenite MnTiO$_{3}$ using room temperature…

Strongly Correlated Electrons · Physics 2025-06-13 Asif Ali , R. K. Maurya , Sakshi Bansal , B. H. Reddy , Ravi Shankar Singh

We present a comparative electronic structure study using DFT and various beyond-DFT (DFT+$U$, $G_0W_0$, DFT+DMFT) methods for ferromagnetic Iron (Fe) to find better approach for describing the spectral properties of correlated magnetic…

Strongly Correlated Electrons · Physics 2021-01-01 Antik Sihi , Sudhir K. Pandey

First principles density functional theory DFT+U calculations and experimental neutron diffraction structure analyses were used to determine the low-temperature crystallographic and magnetic structure of bixbyite Mn2O3. The energies of…

Materials Science · Physics 2013-05-20 Eric Cockayne , Igor Levin , Hui Wu , Anna Llobet

Examining phase stabilities and phase equilibria in strongly correlated materials asks for a next level in the many-body extensions to the local-density approximation (LDA) beyond mainly spectroscopic assessments. Here we put the…

Materials Science · Physics 2013-04-26 Daniel Grieger , Christoph Piefke , Oleg E. Peil , Frank Lechermann

Density-functional Theory (DFT) approaches have recently been used to judge the topological order of various materials despite its well-known band gap underestimation. Use of the more accurate quasi-particle GW approach reveals here few…

Materials Science · Physics 2015-05-27 Julien Vidal , Xiuwen Zhang , Liping Yu , Jun-Wei Luo , Alex Zunger

In positive muon spin rotation and relaxation spectroscopy it is becoming nowadays customary to take advantage of Density Functional Theory (DFT) based computational methods to aid the experimental data analysis. DFT aided muon site…

Strongly Correlated Electrons · Physics 2018-05-23 Ifeanyi John Onuorah , Pietro Bonfà , Roberto De Renzi

Static correlation is a difficult problem for density-functional theory (DFT) as it arises in cases of degenerate or quasi-degenerate states where a multideterminantal wave function provides the simplest reasonable first approximation to…

Chemical Physics · Physics 2024-01-01 Abraham Ponra , Carolyne Bakasa , Anne Justine Etindele , Mark E. Casida

Quantum mechanical methods based on the density functional theory (DFT) offer a realistic possibility of first-principles design of organic donor-acceptor systems and engineered band-gap materials. This promise is contingent upon the…

Chemical Physics · Physics 2013-12-03 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

The electronic structure of lanthanide and actinide compounds is often characterized by orbital ordering of localized $f$-electrons. Density-functional theory (DFT) studies of such systems using the currently available LDA+$U$ method are…

Strongly Correlated Electrons · Physics 2015-11-17 Fei Zhou , Vidvuds Ozolins

In this report we have analyzed a simple effective model for a description of magnetically ordered insulators. The Hamiltonian considered consists of the effective on-site interaction (U) and the intersite Ising-like magnetic exchange…

Strongly Correlated Electrons · Physics 2023-07-19 Szymon Murawski , Konrad Kapcia , Grzegorz Pawłowski , Stanisław Robaszkiewicz

Magnetic phase transitions have been explored in a superlattice formed by stacking monolayers of $\rm LaTiO_{3}$ and $\rm LaVO_{3}$ alternately, using ab-initio density functional theory (DFT) and Monte-Carlo (MC) simulations. DFT derived…

Computational Physics · Physics 2022-05-10 Mukesh Sharma , Tulika Maitra

VO2 is renowned for its electric transition from an insulating monoclinic (M1) phase characterized by V-V dimerized structures, to a metallic rutile (R) phase above 340 Kelvin. This transition is accompanied by a magnetic change: the M1…

Materials Science · Physics 2023-10-10 Yubo Zhang , Da Ke , Junxiong Wu , Chutong Zhang , Baichen Lin , Zuhuang Chen , John P. Perdew , Jianwei Sun

We study ordered phases with broken translational symmetry in the half-filled three-orbital Hubbard model with antiferromagnetic Hund coupling by means of dynamical mean-field theory (DMFT) and continuous-time quantum Monte Carlo…

Strongly Correlated Electrons · Physics 2019-02-27 Kosuke Ishigaki , Joji Nasu , Akihisa Koga , Shintaro Hoshino , Philipp Werner

Static electric response properties of atoms and molecules are reported within the real-space Cartesian grid implementation of pseudopotential Kohn-Sham (KS) density functional theory (DFT). A detailed systematic investigation is made for a…

Chemical Physics · Physics 2019-04-26 Tanmay Mandal , Abhisek Ghosal , Amlan K. Roy

The applicability of DFT+$U$ to the star-of-David phase of $1T$-TaS$_2$ is examined. The viability of a Mott phase as a ground state for the bulk of this material is briefly discussed in light of the available experimental evidence.

Strongly Correlated Electrons · Physics 2023-08-14 Diego Pasquier

We study the effects of an orbital magnetic field on the Mott metal-insulator transition in the Hubbard-Hofstadter model. We demonstrate that sufficiently large magnetic fields induce a Mott insulator-to-metal phase transition supporting…

Strongly Correlated Electrons · Physics 2025-10-28 Georg Rohringer , Anton A. Markov

We present a first-principles investigation of the structural, electronic, and magnetic properties of pyrolusite ($\beta$-MnO$_2$) using conventional and extended Hubbard-corrected density-functional theory (DFT+$U$ and DFT+$U$+$V$). The…

Materials Science · Physics 2021-10-06 Ruchika Mahajan , Iurii Timrov , Nicola Marzari , Arti Kashyap

Accurate computational predictions of band gaps are of practical importance to the modeling and development of semiconductor technologies, such as (opto)electronic devices and photoelectrochemical cells. Among available electronic-structure…

Materials Science · Physics 2021-03-16 Nicole E. Kirchner-Hall , Wayne Zhao , Yihuang Xiong , Iurii Timrov , Ismaila Dabo

We study magnetic properties of CrO$_2$ within the density functional theory plus dynamical mean-field theory (DFT+DMFT) approach in the paramagnetic phase. We consider the 3-orbital (per Cr site) model, containing only $t_{2g}$ states, the…

Strongly Correlated Electrons · Physics 2024-10-15 A. A. Katanin