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With octahedrally coordinated $t_{\rm 2g}$ orbitals which are active at filling $n=2$, the $\rm Sr_2CrO_4$ compound exhibits rich interplay of spin-orbital physics with tetragonal distortion induced crystal field tuning by external agent…

Strongly Correlated Electrons · Physics 2022-10-20 Shubhajyoti Mohapatra , Dheeraj Kumar Singh , Avinash Singh

Evolution of composite spin-orbital order and coupled spin-orbital excitations is studied in a variety of $d^4$ systems with $n$=$4$ electrons in the $t_{2g}$ orbital sector using the generalised self-consistent + fluctuations approach for…

Strongly Correlated Electrons · Physics 2025-04-30 Shahid Ahmad , Harshvardhan Parmar , Shubhajyoti Mohapatra , Avinash Singh

MgV$_{2}$O$_{4}$ is a spinel based on magnetic V$^{3+}$ ions which host both spin ($S=1$) and orbital ($l_{eff}=1$) moments. Owing to the underlying pyrochlore coordination of the magnetic sites, the spins in MgV$_{2}$O$_{4}$ only…

We investigate the collective behavior of orbital angular momentum in the spin ferromagnetic state of a Mott insulator with $t_{2g}$ orbital degeneracy. The frustrated nature of the interactions leads to an infinite degeneracy of classical…

Strongly Correlated Electrons · Physics 2009-11-07 Giniyat Khaliullin , Satoshi Okamoto

A spin-orbital superexchange Hamiltonian in a Mott insulator with $t_{2g}$ orbital degeneracy is investigated. More specifically, we focus on a spin ferromagnetic state of the model and study a collective behavior of orbital angular…

Strongly Correlated Electrons · Physics 2009-11-11 G. Khaliullin , S. Okamoto

At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$…

Materials Science · Physics 2012-09-11 Matthew R. Suchomel , Daniel P. Shoemaker , Lynn Ribaud , Moureen C. Kemei , Ram Seshadri

Considering spin-orbit coupling, the tetragonal crystal-field, and all relevant superexchange processes including quantum interference, we derive expressions for the energy levels of the vanadium ions in tetragonal Sr2VO4. The used…

Strongly Correlated Electrons · Physics 2015-06-03 M. V. Eremin , J. Deisenhofer , R. M. Eremina , J. Teyssier , D. van der Marel , A. Loidl

We consider a model of strongly correlated $e_g$ electrons interacting by superexchange orbital interactions in the ferromagnetic phase of LaMnO$_3$. It is found that the classical orbital order with alternating occupied $e_g$ orbitals has…

Strongly Correlated Electrons · Physics 2009-10-31 Jeroen van den Brink , Peter Horsch , Frank Mack , Andrzej M. Oles

Alkali superoxides differ from conventional transition metal magnets, exhibit magnetism from partially occupied oxygen molecular $\pi^*$-orbitals. Among them, CsO$_2$ stands out for its potential to exhibit novel quantum collective…

Strongly Correlated Electrons · Physics 2024-11-12 Ryota Ono , Ravi Kaushik , Sergey Artyukhin , Martin Jansen , Igor Solovyev , Russell A. Ewings

Recent measurements on MgV$_2$O$_4$ single crystal have reignited the debate on the role of spin-orbit (SO) coupling in dictating the orbital order in Vanadium spinel systems. Density functional theory calculations were performed using the…

Strongly Correlated Electrons · Physics 2015-06-05 Ramandeep Kaur , T. Maitra , T. Nautiyal

The correlated motion of electrons in the presence of strong orbital fluctuations and correlations is investigated with respect to magnetic couplings and excitations in an orbitally degenerate ferromagnet. Introduction of the orbital degree…

Strongly Correlated Electrons · Physics 2015-05-14 Dheeraj Kumar Singh , Bhaskar Kamble , Avinash Singh

We develop an understanding of the anomalous metal state of the parent compounds of recently discovered iron based superconductors starting from a strong coupling viewpoint, including orbital degrees of freedom. On the basis of an…

Superconductivity · Physics 2009-11-13 F. Krüger , S. Kumar , J. Zaanen , J. van den Brink

Spectra of one-electron and collective excitations in narrow-band ferromagnets with unquenched orbital moments are calculated in various theoretical models. The interaction of spin and orbital excitations with conduction electrons results…

Strongly Correlated Electrons · Physics 2009-11-11 V. Yu. Irkhin , M. I. Katsnelson

We present a unique study of the frustrated spinel MgV2O4 which possesses highly coupled spin, lattice and orbital degrees of freedom. Using large single-crystal and powder samples, we find a distortion from spinel at room temperature…

Strongly Correlated Electrons · Physics 2010-10-14 Elisa M. Wheeler , Bella Lake , A. T. M. Nazmul Islam , Manfred Reehuis , Paul Steffens , Tatiana Guidi , Adrian H. Hill

In FeSc2S4 spin-orbital exchange competes with strong spin-orbit coupling, suppressing long-range spin and orbital order and, hence, this material represents one of the rare examples of a spin-orbital liquid ground state. Moreover, it is…

Strongly Correlated Electrons · Physics 2015-06-22 L. Mittelstädt , M. Schmidt , Zhe Wang , F. Mayr , V. Tsurkan , P. Lunkenheimer , D. Ish , L. Balents , J. Deisenhofer , A. Loidl

Strongly anisotropic spin-orbit coupling (SOC) renormalization and strongly enhanced orbital magnetic moments are obtained in the fully self consistent approach including the orbital off-diagonal spin and charge condensates. For moderate…

Strongly Correlated Electrons · Physics 2021-07-05 Shubhajyoti Mohapatra , Ritajit Kundu , Ashutosh Dubey , Debasis Dutta , Avinash Singh

In the light of recent interesting experimental work on MgV$_2$O$_4$ we employ the density functional theory to investigate the crucial role played by different interaction parameters in deciding its electronic and magnetic properties. The…

Strongly Correlated Electrons · Physics 2011-09-15 Sudhir K. Pandey

The collective behavior of correlated electrons in the VO$_2-$interface layer of LaVO$_3$/SrTiO$_3$ heterostructure is studied within a quarter-filled $t_{2g}$-orbital Hubbard model on a square lattice. We argue that the ground state is…

Strongly Correlated Electrons · Physics 2008-11-21 G. Jackeli , G. Khaliullin

A unified approach is presented for investigating coupled spin-orbital fluctuations within a realistic three-orbital model for strongly spin-orbit coupled systems with electron fillings $n=3,4,5$ in the $t_{2g}$ sector of…

Strongly Correlated Electrons · Physics 2021-07-05 Shubhajyoti Mohapatra , Avinash Singh

The entanglement of the spin and orbital degrees of freedom through the spin-orbit coupling has been actively studied in condensed matter physics. In several iridium-oxide systems, the spin-orbital entangled state, identified by the…

Strongly Correlated Electrons · Physics 2014-06-10 Heung-Sik Kim , Jino Im , Myung Joon Han , Hosub Jin
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