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Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…

Chemical Physics · Physics 2023-11-02 Shixin Xu , Robert Eisenberg , Zilong Song , Huaxiong Huang

In acceptor doped ferroelectrics and in ferroelectric films and nanocomposites, defect dipoles, strain gradients, and the electric boundary conditions at interfaces and surfaces often impose internal bias fields. In this work we delicately…

Materials Science · Physics 2018-09-05 Yang-Bin Ma , Bai-Xiang Xu , Karsten Albe , Anna Grünebohm

The Electric Dipole Moment of the electron (eEDM) is typically investigated in experiments using paramagnetic molecules. However, the physical observable in these searches consists in a linear combination of CP-violating interactions,…

High Energy Physics - Phenomenology · Physics 2025-03-31 Marco Ardu , Nicola Valori

We present a theory for rigorous quantum scattering calculations of probabilities for chemical reactions of atoms with diatomic molecules in the presence of an external electric field. The approach is based on the fully uncoupled basis set…

Atomic Physics · Physics 2012-02-06 T. V. Tscherbul , R. V. Krems

Effective field theories (EFT) parameterize the long-distance effects of short-distance dynamics whose details may or may not be known. It is known that EFT coefficients must obey certain positivity constraints if causality and unitarity…

High Energy Physics - Theory · Physics 2021-06-16 Simon Caron-Huot , Vincent Van Duong

The conversion of natural gas (methane) to ethane and ethylene (OCM: oxidative coupling of methane) facilitates its transportation and provides a way to synthesize higher value chemicals. The search for high-performance catalysts to achieve…

Materials Science · Physics 2022-11-16 A. Mazheika , M. Geske , M. Muller , S. A. Schunk , F. Rosowski , R. Kraehnert

Some non linear, second order QED processes in the presence of intense plane electromagnetic waves are investigated. Analytic expressions with general kinematics are derived for Compton scattering and $e^+e^-$ pair production in a…

High Energy Physics - Phenomenology · Physics 2017-01-12 A. Hartin

We investigate electron heating by magnetic-field-aligned electric fields ($E_\parallel$) during anti-parallel magnetic reconnection in the Earth's magnetotail. Using a statistical sample of 140 reconnection outflows, we infer the…

A study by infrared spectroscopy of the physisorbed region of catalysis demonstrated that the intermediates of catalysis exist on the surface as a two dimensional gas. Data in the Atomic Energy Level tables show that of the thousands of…

Chemical Physics · Physics 2008-01-10 Ralph A. Gardner-Chavis , John T. Reye , Theodore B. Selover , Huixiong Zhang

We have recently analyzed theoretically the main characteristics of the edge depolarizing electric field (EDEF), in the vicinity of a non-polar face of a pyroelectric. In this work we measured and characterized the EDEF, excited by a…

Other Condensed Matter · Physics 2015-05-14 A. V. Butenko , V. Sandomirsky , G. Chaniel , B. Shapiro , Y. Schlesinger , A. Jarov , V. A. Sablikov

In this Letter we investigate factors that influence the effective critical electric field for runaway-electron generation in plasmas. We present numerical solutions of the kinetic equation and discuss the implications for the threshold…

Plasma Physics · Physics 2015-03-20 Adam Stahl , Eero Hirvijoki , Joan Decker , Ola Embréus , Tünde Fülöp

Electrochemical kinetics at electrode-electrolyte interfaces are crucial to understand high-rate behavior of energy storage devices. Phase transformation of electrodes is typically treated under equilibrium thermodynamic conditions, while…

Materials Science · Physics 2022-12-15 Rachel C. Kurchin , Dhairya Gandhi , Venkatasubramanian Viswanathan

A comprehensive understanding of the electrode-electrolyte interface in energy conversion systems remains challenging due to the complex and multifaceted nature of interfacial processes. This complexity hinders the development of more…

Chemical Physics · Physics 2024-10-23 Ben Wang , Tomohiro Fukushima , Hiro Minamimoto , Andrey Lyalin , Kei Murakoshi , Tetsuya Taketsugu

Optimisation of heat engines at the micro-scale has applications in biological and artificial nano-technology, and stimulates theoretical research in non-equilibrium statistical physics. Here we consider non-interacting overdamped particles…

Soft Condensed Matter · Physics 2021-06-02 Giulia Gronchi , Andrea Puglisi

The quantum diffraction and symmetry effects on the entanglement fidelity (EF) of different elastic electron-electron, ion-ion and electron-ion interactions are investigated in non-ideal dense plasma. The partial wave analysis and an…

Although classical and quantum heat engines work on entirely different fundamental principles, there is an underlying similarity. For instance, the form of efficiency at optimal performance may be similar for both types of engines. In this…

Quantum Physics · Physics 2019-07-31 Varinder Singh , Ramandeep S. Johal

The application of an external, oriented electric field has emerged as an attractive technique for manipulating chemical reactions. Because most applications occur in solution, a theory of electric field catalysis requires treatment of the…

Chemical Physics · Physics 2024-04-03 Sohang Kundu , Timothy C. Berkelbach

The secondary electron emission process is essential for the optimal operation of a wide range of applications, including fusion reactors, high-energy accelerators, or spacecraft. The process can be influenced and controlled by the use of a…

Plasma Physics · Physics 2021-02-03 Claudiu Costin

In a cylindrical container filled with an eutectic GaInSn alloy, an electro-vortex flow (EVF) is generated by the interaction of a non-uniform current with its own magnetic field. In this paper, we investigate the EVF phenomenon numerically…

Fluid Dynamics · Physics 2019-10-24 K. Liu , F. Stefani , N. Weber , T. Weier , B. W. Li

If one-electron observables of a many-electron system are of interest, a many-electron dynamics can be represented exactly by a one-electron dynamics with effective potentials. The formalism for this reduction is provided by the Exact…

Chemical Physics · Physics 2021-01-04 Jakub Kocák , Axel Schild