Related papers: ClF diatomic molecule: rovibrational spectra
Highly accurate variational calculations, based on a few-parameter, physically adequate trial function, are carried out for the hydrogen molecule \hh in inclined configuration, where the molecular axis forms an angle $\theta$ with respect…
The atomic dipole polarizability, $\alpha$, and the van der Waals (vdW) radius, $R_{\rm vdW}$, are two key quantities to describe vdW interactions between atoms in molecules and materials. Until now, they have been determined independently…
This work concerns \emph{ab initio} calculations of the complete potential energy curve and spectroscopic constants for the ground state $X^1\Sigma_g^+$ of the beryllium dimer, Be$_2$. High accuracy and reliability of the results is one of…
We recently reported the formation of ultracold LiCs molecules in the rovibrational ground state X1Sigma+,v''=0,J''=0 [J. Deiglmayr et al., PRL 101, 133004 (2008)]. Here we discuss details of the experimental setup and present a thorough…
We report a new technique to determine the van der Waals coeffcients of lithium (Li) atoms based on the relativistic coupled-cluster theory. These quantities are determined using the imaginary parts of the scalar dipole and quadrupole…
We study optical cycling in the polar free radical calcium monohydroxide (CaOH) and establish an experimental path towards scattering $\sim$$10^4$ photons. We report rovibronic branching ratio measurements with precision at the…
By inferring the dynamic permittivity of different material media from the observations and calculating dynamic electric dipole polarizabilties of the Li through Cs alkali atoms, precise values of $C_3$ coefficients were estimated in Phys.…
This work presents a perturbative calculation methodology for evaluating the energy shifts and broadening of vibrational energy levels, caused by interactions between bound and unbound dissociative electronic states. The method is validated…
The diatomic molecule radium monofluoride (RaF) has recently been proposed as a versatile probe for physics beyond the current standard model. Herein, a route towards production of a RaF molecular beam via radium ions is proposed. It takes…
A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…
We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\rangle$ and $|np\rangle$ states. The…
It is shown that recently observed $\alpha$ cluster states a few MeV above the $\alpha$ threshold energy in $^{52}$Ti correspond to the higher nodal band states with the $\alpha$+$^{48}$Ca cluster structure, i.e. a vibrational mode in which…
The Tietz-Hua (TH) potential is one of the very best analytical model potentials for the vibrational energy of diatomic molecules. By using the Nikiforov-Uvarov (NU) method, we have obtained the exact analytical s-wave solutions of the…
We present an accurate theoretical determination of rovibrational energy levels of the hydrogen molecule and its isotopologues in its electronic ground state. We consider all significant corrections to the Born-Oppenheimer approximation,…
We report ab initio relativistic correlation calculations of potential curves and spectroscopic constants for four lowest-lying electronic states of the lead monofluoride. We also calculated parameters of the spin-rotational Hamiltonian for…
Through the introduction of a class of trial wave functions portraying combined rotations and vibrations of molecules formed through particle localization in concentric polygonal rings, a correlated basis is constructed that spans the…
Through the introduction of a class of appropriate translationally invariant trial wave functions, we show that the strong correlations in the lowest Landau level (LLL) reflect in finite systems the emergence of intrinsic point-group…
We consider a molecule in the Born-Oppenheimer approximation interacting with a plate of infinite thickness, i.e, a half--space, which is perfectly conducting or dielectric. It is well--known in the physics literature that in this case the…
Removal energies and hyperfine constants of the lowest four $ns, np_{1/2}$ and $np_{3/2}$ states in Na, K, Rb and Cs are calculated; removal energies of the n=7--10 states and hyperfine constants of the n=7 and 8 states in Fr are also…
The Chandler wobble (CW) -- the $\sim$433-day free nutation of Earth's rotation pole -- experienced an anomalous near-disappearance between 2015 and 2020, followed by a re-excitation with an approximately $180^{\circ}$ phase reversal. Using…