Related papers: Photomolecular Effect: Visible Light Absorption at…
We report the discovery of photomolecular effect: cleavage of water clusters off surfaces by photons. This effect is demonstrated through surprising absorption of partially wetted hydrogel in the visible spectrum where both water and…
Although water is almost transparent to visible light, we demonstrate that the air-water interface interacts strongly with visible light via what we hypothesize as the photomolecular effect. In this effect, transverse-magnetic polarized…
It is well-known that water in both liquid and vapor phases exhibits exceptionally weak absorption of light in the visible range. Recent experiments, however, have demonstrated that at the liquid-air interface, absorption in the visible…
Cloud absorption is acknowledged as the biggest source of uncertainty in the climate models. For over 70 years, many experiments have reported clouds absorbing more solar radiation than theory could predict. In the visible spectrum,…
The photomolecular effect has been hypothesized to enhance evaporation of water at visible wavelengths. This study develops a measurement technique to investigate its presence and magnitude at the liquid-vapor interface of water. The…
Electronic excitations near the surface of water ice lead to the desorption of adsorbed molecules, through a so far debated mechanism. A systematic study of photon-induced indirect desorption, revealed by the spectral dependence of the…
Vacuum-UV (VUV) photodesorption from water-rich ice mantles coating interstellar grains is known to play an important role in the gas-to-ice ratio in star- and planet-forming regions. Quantitative photodesorption yields from water ice are…
The photodesorption of icy grain mantles has been claimed to be responsible for the abundance of gas-phase molecules toward cold regions. Being water a ubiquitous molecule, it is crucial to understand its role in photochemistry and its…
A model is described that relates the temperature coefficient of the optical absorption spectrum of pure water to the frequency derivative of that spectrum and two parameters that quantify the dependence of a peak's amplitude and its…
We investigated theoretically water evaporation from concentrated supramolecular mixtures, such as solutions of polymers or amphiphilic molecules, using numerical resolutions of a one dimensional model based on mass transport equations.…
The interfacial resistance to evaporation, in particular for the case of water, is a longstanding issue. The previous data on its main characterizing parameter, the accommodation coefficient, manifest a dispersion over three orders of…
Molecular adsorption on surfaces plays a central role in catalysis, corrosion, desalination, and many other processes of relevance to industry and the natural world. Few adsorption systems are more ubiquitous or of more widespread…
Molecular absorption of infrared radiation is generally due to ro-vibrational electric-dipole transitions. Electric-quadrupole transitions may still occur, but they are typically a million times weaker than electric-dipole transitions,…
Rising water demands and depleting freshwater resources have brought desalination and wastewater treatment technologies to the forefront. For sustainable water management, there is a global push towards Zero Liquid Discharge (ZLD) with the…
A fundamental issue that limits the efficiency of many photoelectrochemical systems is that the photon absorption length is typically much longer than the electron diffusion length. Various photon management schemes have been developed to…
The ExoMol database currently provides comprehensive line lists for modelling the spectroscopic properties of molecules in hot atmospheres. Extending the spectral range of the data provided to ultraviolet (UV) wavelengths brings into play…
Solar-thermal evaporation, a traditional steam generation method for solar desalination, has received numerous attentions in recent years due to the significant increase in efficiency by adopting interfacial evaporation. While most of the…
Photodissociation is the dominant removal process of molecules in any region exposed to intense ultraviolet (UV) radiation. This includes diffuse and translucent interstellar clouds, dense photon-dominated regions, high velocity shocks, the…
Photophoretic force due to the optically-induced thermal effect provides an effective way to manipulate the light-absorbing particles suspended in ambient gases. However, how this force temporally responds to the intensity modulation of the…
Studies of the transport of wet water vapour are relevant for various areas of human activity, including the construction and production of building materials, mining, agriculture, environmental safety of technological processes, scientific…