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The static configuration of ferroelectric domain walls was investigated using atomic force microscopy on epitaxial PbZr0.2Ti0.8O3 thin films. Measurements of domain wall roughness reveal a power law growth of the correlation function of…

Disordered Systems and Neural Networks · Physics 2013-11-07 P. Paruch , T. Giamarchi , J. -M. Triscone

Ferroelectric domain walls are attracting broad attention as atomic-scale switches, diodes and mobile wires for next-generation nanoelectronics. Charged domain walls in improper ferroelectrics are particularly interesting as they offer…

Despite multiple efforts, there exist many unsolved fundamental problems related with detection and analysis of internal polarization structure and related phase transitions in ferroelectric domain walls. Their solution can be very…

We present a spatial and wave-vector resolved study of the electronic structure of micron sized ferroelectric domains at the surface of a BaTiO3(001) single crystal. The n-type doping of the BaTiO3 is controlled by in-situ vacuum and oxygen…

Materials Science · Physics 2018-06-12 J. E. Rault , J. Dionot , C. Mathieu , V. Feyer , C. M. Schneider , G. Geneste , N. Barrett

We show that nano-scale variations of the order parameter in strongly-correlated systems can induce local spatial regions such as domain walls that exhibit electronic properties representative of a different, but nearby, part of the phase…

Strongly Correlated Electrons · Physics 2009-11-10 M. S. Rzchowski , Robert Joynt

HfO$_2$- and ZrO$_2$-based ferroelectric thin films have emerged as promising candidates for the gate oxides of next generation electronic devices. Recent work has experimentally demonstrated that a tetragonal/orthorhombic (t/o-) phase…

Mesoscale and Nanoscale Physics · Physics 2024-03-11 Prabhat Kumar , Michael Hoffmann , Andrew Nonaka , Sayeef Salahuddin , Zhi Yao

Surprisingly little is known about the microscopic processes that govern ferroelectric switching in orthorhombic ferroelectrics. To study microscopic switching processes we combine ab initio-based molecular dynamics simulations and data…

Ferroelectric domain structures, separated by domain walls, often display unconventional physics and hold significant potential for applications in nano-devices. Most naturally growth domain walls are charge-neutral to avoid increased…

Materials Science · Physics 2024-12-17 Yunfei Hong , Junkai Deng , Yang Yang , Ri He , Zhicheng Zhong , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu

We resolve the microscopic mechanism of polarization switching in wurtzite ferroelectric AlScN by integrating advanced thin-film fabrication, ferroelectric switching dynamics characterizations, high-resolution scanning transmission electron…

Materials Science · Physics 2025-08-26 Jiawei Huang , Jinyang Li , Xinyue Guo , Tongqi Wen , David J. Srolovitz , Zhen Chen , Zuhuang Chen , Shi Liu

We investigate the emergence of Bloch-type polarization components in 180$^\circ$ ferroelectric domain walls in bulk PbTiO$_{3}$ under varying mechanical boundary conditions, using first-principles simulations based on density functional…

Despite remarkable progress in developing multifunctional materials, spin-driven ferroelectrics featuring both spontaneous magnetization and electric polarization are still rare. Among such ferromagnetic ferroelectrics are conical spin…

Strongly Correlated Electrons · Physics 2017-06-09 T. Honda , J. S. White , A. B. Harris , L. C. Chapon , A. Fennell , B. Roessli , O. Zaharko , Y. Murakami , M. Kenzelmann , T. Kimura

Ferroelectric nanostructures can be formed by local switching of domains using techniques such as piezo-force microscopy (PFM). Understanding lateral size effects is important to determine the minimum feature size for writing ferroelectric…

Materials Science · Physics 2013-10-31 Nathaniel Ng , Rajeev Ahluwalia , Haibin Su , Freddy Boey

We use shear-mode Raman imaging to track ferroelectric switching in multilayer 3$R$-MoS$_2$. Within a single flake, mechanically segmented regions respond independently and follow distinct pathways. Partially polarized end states indicate…

Materials Science · Physics 2026-05-21 Yulu Liu , Kenji Watanabe , Takashi Taniguchi , Xiaoxiang Xi

Twisted heterostructures of two-dimensional crystals offer almost unlimited scope for the design of novel metamaterials. Here we demonstrate a room-temperature ferroelectric semiconductor that is assembled using mono- or few- layer MoS2.…

Wurtzite ferroelectrics possess transformative potential for next-generation microelectronics. A comprehensive understanding of their ferroelectric properties and domain energetics is crucial for tailoring their ferroelectric…

Domain switching pathways in ferroelectric materials visualized by dynamic Piezoresponse Force Microscopy (PFM) are explored via variational autoencoder (VAE), which simplifies the elements of the observed domain structure, crucially…

Disordered Systems and Neural Networks · Physics 2021-04-14 Sergei V. Kalinin , James J. Steffes , Yongtao Liu , Bryan D. Huey , Maxim Ziatdinov

BaTiO$_3$ (BTO) is a prototypical perovskite ferroelectric, whose dielectric permittivity and loss spectra -- which are strongly temperature and frequency dependent -- include contributions from inhomogeneous polarization patterns, with…

Materials Science · Physics 2024-07-31 Ashok Gurung , Mohammad Fatin Ishtiyaq , S. Pamir Alpay , John Mangeri , Serge Nakhmanson

Understanding and controlling the motion, stability, and equilibrium configuration of ferroelectric domain walls is key for their integration into potential nanoelectronics applications, such as ferroelectric racetrack memories. Using…

Disordered Systems and Neural Networks · Physics 2022-01-05 Guillaume Rapin , Sophia Ehrensperger , Cédric Blaser , Nirvana Caballero , Patrycja Paruch

Semiconducting ferroelectric materials with low energy polarisation switching offer a platform for next-generation electronics such as ferroelectric field-effect transistors. Ferroelectric domains at symmetry-broken interfaces of transition…

Mesoscale and Nanoscale Physics · Physics 2022-10-07 Laurent Molino , Leena Aggarwal , Vladimir Enaldiev , Ryan Plumadore , Vladimir Falko , Adina Luican-Mayer

Ferroelectrics usually adopt a multi-domain state with domain walls separating domains with polarization axes oriented differently. It has long been recognized that domain walls can dramatically impact the properties of ferroelectric…

Materials Science · Physics 2017-03-15 Shi Liu , R. E. Cohen