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We present a method for calculation of Raman modes of the quantum solid phase I solid hydrogen and deuterium. We use the mean-field assumption that the quantised excitations are localized on one molecule. This is done by explicit solution…

The small cross section of Raman scattering poses a great challenge for its direct study at the single-molecule level. By exploiting the high Franck-Condon factor of a common-mode resonance, choosing a large vibrational frequency difference…

A consistent calculation of resonant inelastic (Raman) scattering amplitudes for relatively large quantum dots, which takes account of valence-band mixing, discrete character of the spectrum in intermediate and final states, and…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Alain Delgado , Augusto Gonzalez

We treat resonant Raman scattering via the multiphonon exciton transitions in cylindrical quantum dots with a parabolic confinement in the lateral direction and with a finite rectangular interface-barrier confinement in the axial direction.…

Mesoscale and Nanoscale Physics · Physics 2012-05-09 S. N. Klimin , V. M. Fomin , J. T. Devreese , J. -P. Leburton

In a molecule subjected to no external fields, motion of nuclei is governed by a function V of nuclear coordinates. This function (potential energy) is a sum of two terms: Coulomb repulsion between nuclei and the electronic effective…

Mathematical Physics · Physics 2015-09-01 Vladimir Damljanovic

The dynamics of non-polar diatomic molecules interacting with a far-detuned narrow-band laser field, that only may drive rotational transitions, is studied. The rotation of the molecule is considered both classically and quantum…

Quantum Physics · Physics 2009-11-10 A. Adelswaerd , S. Wallentowitz

Preparing molecules at rest and in a highly pure quantum state is a long standing dream in chemistry and physics, so far achieved only for a select set of molecules in dedicated experimental setups. Here, a quantum-limited combination of…

Quantum Physics · Physics 2015-05-30 D. Leibfried

We present a systematic understanding of the rotational structure of a long-range (vibrationally highly-excited) diatomic molecule. For example, we show that depending on a quantum defect, the least-bound vibrational state of a diatomic…

Atomic Physics · Physics 2009-11-10 Bo Gao

We present a combined experimental and theoretical study of resonant Raman spectroscopy in single- and triple-layer MoTe$_2$. Raman intensities are computed entirely from first principles by calculating finite differences of the dielectric…

We present theoretical results concerning inelastic light (Raman) scattering from semiconductor quantum dots. The characteristics of each dot state (whether it is a collective or single-particle excitation, its multipolarity, and its spin)…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Alain Delgado , Augusto Gonzalez , David J. Lockwood

We present a self-consistent quantum optics approach to calculating the surface enhanced Raman spectrum of molecules coupled to arbitrarily shaped plasmonic systems. Our treatment is intuitive to use and provides fresh analytical insight…

Optics · Physics 2017-06-26 Mohsen Kamandar Dezfouli , Stephen Hughes

The application of molecular dynamics (MD) simulations to the interpretation of Raman scattering spectra is hindered by inability of atomistic simulations to account for the dynamic evolution of electronic polarizability, requiring the use…

Materials Science · Physics 2023-04-18 Atanu Paul , Anthony Ruffino , Stefan Masiuk , Jonathan Spanier , Ilya Grinberg

Raman spectroscopy stands as a cornerstone technique for probing collective excitations and emergent quantum phases in solids. While polarization-resolved Raman scattering has been widely used to extract symmetry information of eigenmodes,…

Materials Science · Physics 2026-02-24 Di Cheng , Junxiang Li , Shizhuo Luo , Zehao Chen , Xinwei Li

Precision spectroscopy of atoms and molecules allows one to search for and to put stringent limits on the variation of fundamental constants. These experiments are typically interpreted in terms of variations of the fine structure constant…

Accurate ro-vibrational energies, eigenfunctions, radial densities, expectation values are presented for the exponential-type Manning-Rosen (MR) potential. Bound states accurate up to ten significant figure are obtained by employing a…

Atomic Physics · Physics 2015-06-22 Amlan K. Roy

We present and evaluate an efficient method for simulating Raman spectra from molecular dynamics (MD) calculations {\it without} defining normal modes. We apply the method to high pressure hydrogen in the high-temperature "Phase IV": a…

Materials Science · Physics 2014-08-19 G. J. Ackland , I. B. Magdau

Excited-state vibrational dynamics in molecules can be studied by an electronically off-resonant Raman process induced by a probe pulse with variable delay with respect to an actinic pulse. We establish the connection between several…

Chemical Physics · Physics 2013-09-27 Konstantin E. Dorfman , Benjamin P. Fingerhut , Shaul Mukamel

A photonic molecule (PM) is a miniature diffractive optical structure composed of resonance microcavities called atoms (e.g., cylinders or spheres) supporting a set of high-quality eigenmodes. All atoms in a PM are coupled by the…

Optics · Physics 2022-11-29 Yury E. Geints

Probing the real time dynamics of a reacting molecule remains one of the central challenges in chemistry. In this letter we show how the time-dependent wavefunction of an excited-state reacting molecule can be completely reconstructed from…

Quantum Physics · Physics 2015-05-27 David Avisar , David J. Tannor

Bound-state spectra of shifted Deng-Fan oscillator potential are studied by means of a generalized pseudospectral method. Very accurate results are obtained for \emph{both low as well as high} states by a non-uniform optimal discretization…

Chemical Physics · Physics 2014-09-09 Amlan K. Roy
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