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A new methodology of simulating nonadiabatic dynamics using frozen-width Gaussian wavepackets within the moving crude adiabatic representation with the on-the-fly evaluation of electronic structure is presented. The main feature of the new…

Chemical Physics · Physics 2018-04-04 Loïc Joubert-Doriol , Artur F. Izmaylov

A simple variational Lagrangian is proposed for the time development of an arbitrary density matrix, employing the "factorization" of the density. Only the "kinetic energy" appears in the Lagrangian. The formalism applies to pure and mixed…

Fluid Dynamics · Physics 2009-11-10 R. Englman , A. Yahalom

We present a time-dependent extension of logarithmic perturbation theory for nonrelativistic quantum dynamics governed by the Schr\"odinger equation, in which the logarithm of the wave function is expanded in powers of a coupling constant.…

Quantum Physics · Physics 2026-04-17 Juan Carlos del Valle , Paul Bergold , Karolina Kropielnicka

We introduce a simple ansatz for the wavefunction of a many-body system based on coupled forward and backward-propagating semiclassical trajectories. This method is primarily aimed at, but not limited to, treating nonequilibrium dynamics in…

Chemical Physics · Physics 2018-05-01 Shunsuke A. Sato , Aaron Kelly , Angel Rubio

This work considers a short-term, continuous time setting characterized by a coupled power supply system controlled exclusively by a single provider and comprising a cascade of hydropower systems (dams), fossil fuel power stations, and a…

Optimization and Control · Mathematics 2024-04-12 Chiheb Ben Hammouda , Eliza Rezvanova , Erik von Schwerin , Raúl Tempone

Due to the exponential growth of the state space of coupled quantum systems it is not possible, in general, to numerically store the state of a very large number of quantum systems within a classical computer. We demonstrate a method for…

Quantum Physics · Physics 2017-02-07 J. J. Bowen , V. M. Dwyer , I. W. Phillips , M. J. Everitt

In this paper, we present a variational treatment of the linear dependence for a non-orthogonal time-dependent basis set in solving the Schr\"odinger equation. The method is based on: i) the definition of a linearly independent working…

Quantum Physics · Physics 2022-10-12 Loïc Joubert-Doriol

We formulate equations of motion and conservation laws for a quantum many-body system in a co-moving Lagrangian reference frame. It is shown that generalized inertia forces in the co-moving frame are described by Green's deformation tensor…

Statistical Mechanics · Physics 2009-11-10 I. V. Tokatly

Critical points of energy functionals, which are of broad interest, for instance, in physics and chemistry, in solid and quantum mechanics, in material science, or in general diffusion-reaction models arise as solutions to the associated…

Numerical Analysis · Mathematics 2025-10-20 Pascal Heid , Thomas P. Wihler

We introduce a scalable variational method for simulating the dynamics of interacting open quantum bosonic systems deep in the quantum regime. The method is based on a multi-dimensional Wigner phase-space representation and employs a…

Quantum Physics · Physics 2025-07-21 Jacopo Tosca , Francesco Carnazza , Luca Giacomelli , Cristiano Ciuti

In this work, a methodology is proposed for formulating general dynamical equations in mechanics under the umbrella of the principle of energy conservation. It is shown that Lagrange's equation, Hamilton's canonical equations, and…

Classical Physics · Physics 2025-01-08 Yinqiu Zhou , Xiuming Wang

Quantum coherence inherently affects the dynamics and the performances of a quantum machine. Coherent control can, at least in principle, enhance the work extraction and boost the velocity of evolution in an open quantum system. Using…

Quantum Physics · Physics 2018-12-10 Vasco Cavina , Andrea Mari , Alberto Carlini , Vittorio Giovannetti

We show that standard Ehrenfest dynamics does not conserve linear and angular momentum when using a basis of truncated adiabatic states. However, we also show that previously proposed effective Ehrenfest equations of…

Chemical Physics · Physics 2023-12-15 Zhen Tao , Xuezhi Bian , Yanze Wu , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

On-the-fly quantum nonadiabatic dynamics for large systems greatly benefits from the adiabatic representation readily available from the electronic structure programs. However, frequently occurring in this representation conical…

Stochastic mechanics is regarded as a physical theory to explain quantum mechanics with classical terms such that some of the quantum mechanics paradoxes can be avoided. Here we propose a new variational principle to uncover more insights…

Quantum Physics · Physics 2025-12-02 Jianhao M. Yang

We introduce a classical computational method for quantum dynamics that relies on a global-in-time variational principle. Unlike conventional time-stepping approaches, our scheme computes the entire state trajectory over a finite time…

Quantum Physics · Physics 2026-04-27 Alessandro Sinibaldi , Douglas Hendry , Filippo Vicentini , Giuseppe Carleo

Taking advantage of the flexibility of the variational method with coordinate transformations, we derive a self-consistent set of equations of motion from a discretized Lagrangian to study kinetic plasmas using a Fourier decomposed…

Computational Physics · Physics 2014-11-04 A. B. Stamm , B. A. Shadwick

There exists in nature many examples of systems presenting self-limiting behaviour: population dynamics, structure engineering, Townsend's electron breakdown, nuclear decay in radioactive equilibrium, histeresis process, meteorological…

Biological Physics · Physics 2007-05-23 A. G. Munoz S. , D. Sierra Porta , T. Soldovieri

This paper presents a Lagrangian approach to simulating multibody dynamics in a tensegrity framework with an ability to tackle holonomic constraint violations in an energy-preserving scheme. Governing equations are described using…

Systems and Control · Electrical Eng. & Systems 2020-09-01 Shao-Chen Hsu , Vaishnav Tadiparthi , Raktim Bhattacharya

A Feynman-Jensen version of the thermal variational principle is applied to hot gauge fields, Abelian as well as non-Abelian: scalar electrodynamics (without scalar self-coupling) and the gluon plasma. The perturbatively known self-energies…

High Energy Physics - Phenomenology · Physics 2009-10-28 Y. Schröder , H. Schulz