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The strategic design of ferroelectric materials exhibiting robust and reversible spontaneous polarization remains a pivotal challenge in functional materials research. Here, A-site cation disorder engineering is employed in the n = 2…

While defects are unavoidable in crystals and often detrimental to material performance, they can be a key ingredient for inducing functionalities when tailored. Here, we demonstrate that an A-site-deficient perovskite Y$_{1/3}$TaO$_3$…

Hybrid improper ferroelectricity, where an electrical polarization can be induced via a trilinear coupling to two non-polar structural distortions of different symmetry, has recently been experimentally demonstrated for the first time in…

Materials Science · Physics 2016-10-05 Elizabeth A. Nowadnick , Craig J. Fennie

A triangular lattice with onsite Coulomb interaction $U$ present only on one sub-lattice, is periodically driven by electromagnetic field with a frequency $\Omega \gg (t,~U)$ at half filling. In this high frequency limit, the…

Strongly Correlated Electrons · Physics 2020-04-01 Sayan Jana , Priyanka Mohan , Arijit Saha , Anamitra Mukherjee

By performing accurate ab-initio density functional theory calculations, we study the role of $4f$ electrons in stabilizing the magnetic-field-induced ferroelectric state of DyFeO$_{3}$. We confirm that the ferroelectric polarization is…

Materials Science · Physics 2015-05-14 Alessandro Stroppa , Martijn Marsman , Georg Kresse , Silvia Picozzi

We report first-principles calculations on the coupling between epitaxial strain, polarization, and oxygen octahedra rotations in monodomain (PbTiO$_{3}$)$_{n}$/(SrTiO$_{3}$)$_{n}$ superlattices. We show how the interplay between (i) the…

Materials Science · Physics 2015-05-28 Pablo Aguado-Puente , Pablo García-Fernández , Javier Junquera

In this work, we use density functional theory calculations to demonstrate how spontaneous electric polarizations can be induced \textit{via} a hybrid improper ferroelectric mechanism in iodide perovskites, a family well-known to display…

Materials Science · Physics 2018-06-27 Joshua Young , James M. Rondinelli

Metal-organic frameworks comprehend a wide class of hybrid organic-inorganic materials with general structure A$_m$BX$_n$, with $A$ and $X$ being organic molecules and B a metal cation. This often results in enhanced structural flexibility…

Materials Science · Physics 2022-04-21 Francesco Foggetti , Alessandro Stroppa , Sergey Artyukhin

The coupling of ferroelectricity and magnetic order provides rich tunability for engineering material properties and demonstrates great potential for uncovering novel quantum phenomena and multifunctional devices. Here, we report…

Ferroelectric domain walls are nanoscale objects that can be created, positioned, and erased on demand. They often embody functional properties that are distinct from the surrounding bulk material. Enhanced conductivity, for instance, is…

Materials Science · Physics 2024-10-29 Elzbieta Gradauskaite , Chia-Jung Yang , Shovon Pal , Manfred Fiebig , Morgan Trassin

We study possible superconducting states in transition metal dichalcogenide (TMD) monolayers, assuming an on-site pairing potential that includes both intra- and inter-orbital terms. We find that if the mirror symmetry with respect to the…

Superconductivity · Physics 2021-09-24 Gilad Margalit , Erez Berg , Yuval Oreg

In this work, we carry out first-principles calculations and lattice mode analysis to investigate the polarization switching mechanism in HfO$_2$. Because the stability of the polar orthorhombic $Pca2_1$ phase of HfO$_2$ arises from a…

Materials Science · Physics 2021-08-31 Yubo Qi , Sobhit Singh , Karin M. Rabe

Emergent magnetic states at oxide interfaces arise from the interplay of charge transfer, orbital reconstruction, and dimensional confinement, offering a route to engineered correlated-electron behavior in nanoscale spintronic materials.…

We investigate a double layer system with tight-binding hopping, intra-layer and inter-layer interactions, as well as a Josephson like coupling. We find that an antiferromagnetic spin polarization induces additional spin-triplet pairing…

Condensed Matter · Physics 2009-10-28 Christian Helm , Franz Forsthofer , Joachim Keller

2D Ruddlesden-Popper perovskites are compelling platforms for quantum-confined optoelectronics. However, polar order in iodide composition remains rare under ambient conditions, and the mechanistic origin of anomalous photoluminescence in…

Couplings between ferroelectric and magnetic orders offer promising routes toward low-dissipation electronics. However, such couplings are notably rare, largely due to the poor compatibility between insulating band structures and…

Materials Science · Physics 2026-03-20 Jan Priessnitz , Anna Birk Hellenes , Riccardo Comin , Libor Šmejkal

We examine the electronic properties of newly discovered "ferroelectric" metal LiOsO$_3$ combining density-functional and dynamical mean-field theories. We show that the material is close to a Mott transition and that electronic…

Materials Science · Physics 2015-08-26 Danilo Puggioni , Gianluca Giovannetti , Massimo Capone , James M. Rondinelli

The quasi-one-dimensional spin ladder compounds, BaFe$_2$S$_3$ and BaFe$_2$Se$_3$, are investigated by infrared spectroscopy and density functional theory (DFT) calculations. We observe strong anisotropic electronic properties and an…

We theoretically study the superconducting properties of multi-band two-dimensional transition metal oxide superconductors by analyzing not only the role played by conventional singlet pairings, but also by the triplet order parameters,…

Strongly Correlated Electrons · Physics 2021-10-12 L. Lepori , D. Giuliano , A. Nava , C. A. Perroni

We present a strategy to design structures for which a polar lattice distortion induces weak ferromagnetism. We identify a large class of multiferroic oxides as potential realizations and use density-functional theory to screen several…

Materials Science · Physics 2013-05-29 Craig J. Fennie