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Despite the success of density functional approximations (DFAs) in describing the electronic properties of many-electron systems, the most widely used approximations suffer from self-interaction errors (SIE) that limit their predictive…

Chemical Physics · Physics 2020-01-08 Yoh Yamamoto , Carlos M. Diaz , Luis Basurto , Koblar A. Jackson , Tunna Baruah , Rajendra R. Zope

We analyze in detail the error that arises from the linearization in linearized augmented-plane-wave (LAPW) basis functions around predetermined energies $E_l$ and show that it can lead to undesirable dependences of the calculated results…

Materials Science · Physics 2013-11-19 Gregor Michalicek , Markus Betzinger , Christoph Friedrich , Stefan Blügel

The use of spatially explicit land use and land cover (LULC) change models is widespread in environmental sciences and of interest in public decision-help. However, it appears that these models suffer from significant biases and…

Applications · Statistics 2022-04-01 François-Rémi Mazy , Pierre-Yves Longaretti

Density functional theory with plane-wave basis sets is widely employed in computational materials science, including applications to isolated molecular systems. However, the inadequate description of electron correlation remains a…

Chemical Physics · Physics 2026-04-21 Qian Wang , Calvin Ku , Jyh-Pin Chou , Peng-Jen Chen , Alice Hu , Min-Hsiu Hsieh

The Perdew-Zunger self-interaction correction cures many common problems associated with semilocal density functionals, but suffers from a size-extensivity problem when Kohn-Sham orbitals are used in the correction. Fermi-L\"{o}wdin-orbital…

Computational Physics · Physics 2017-06-30 Zeng-hui Yang , Mark R. Pederson , John P. Perdew

A new method for predicting core level binding energies (CLBEs) is developed by both localizing the core-level states and describing the screening effect. CLBEs contain important information about the electronic structure, elemental…

Chemical Physics · Physics 2024-06-11 Jincheng Yu , Yuncai Mei , Zehua Chen , Weitao Yang

This paper is devoted to numerical approximations for the wave equation with a multiscale character. Our approach is formulated in the framework of the Localized Orthogonal Decomposition (LOD) interpreted as a numerical homogenization with…

Numerical Analysis · Mathematics 2015-09-23 Assyr Abdulle , Patrick Henning

Precision cosmology benefits from extracting maximal information from cosmic structures, motivating the use of higher-order statistics (HOS) at small spatial scales. However, predicting how baryonic processes modify matter statistics at…

Cosmology and Nongalactic Astrophysics · Physics 2025-10-07 Alan Junzhe Zhou , Marco Gatti , Dhayaa Anbajagane , Scott Dodelson , Matthieu Schaller , Joop Schaye

One of the most important open challenges in modern Kohn-Sham (KS) density-functional theory (DFT) is the correct treatment of fractional electron charges and spins. Approximate exchange-correlation (XC) functionals struggle to do this in a…

Chemical Physics · Physics 2015-12-24 Jonathan Nafziger , Adam Wasserman

Within the framework of linear-scaling Kohn-Sham density functional theory, a robust method for maintaining compact localized orbitals close to the ground state is coupled with nuclear dynamics. This allows to obviate the commonly employed…

Computational Physics · Physics 2018-08-01 Hayden Scheiber , Yifei Shi , Rustam Z. Khaliullin

Accurate sound source localization (SSL), such as direction-of-arrival (DoA) estimation, relies on consistent multichannel data. However, batteryless systems often suffer from missing data due to the stochastic nature of energy harvesting,…

Machine Learning · Computer Science 2025-07-21 Subrata Biswas , Mohammad Nur Hossain Khan , Violet Colwell , Jack Adiletta , Bashima Islam

Strongly correlated systems containing d/f-electrons present a challenge to conventional density functional theory (DFT), such as the widely used local density approximation (LDA) or generalized gradient approximation (GGA). In this work,…

Strongly Correlated Electrons · Physics 2024-01-19 Bei-Lei Liu , Yue-Chao Wang , Yu Liu , Hai-Feng Liu , Hai-Feng Song

In this paper, we propose a multiscale method for heterogeneous Stokes problems. The method is based on the Localized Orthogonal Decomposition (LOD) methodology and has approximation properties independent of the regularity of the…

Numerical Analysis · Mathematics 2024-10-21 Moritz Hauck , Alexei Lozinski

Phaseless Auxiliary-Field Quantum Monte Carlo (ph-AFQMC) has recently emerged as a promising method for the production of benchmark-level simulations of medium to large-sized molecules, due to its accuracy and favorable polynomial scaling…

Density functional theory (DFT) and beyond-DFT methods are often used in combination with photoelectron spectroscopy to obtain physical insights into the electronic structure of molecules and solids. The Kohn-Sham eigenvalues are not…

Logarithmic finite-size scaling of the O($n$) universality class at the upper critical dimensionality ($d_c=4$) has a fundamental role in statistical and condensed-matter physics and important applications in various experimental systems.…

Statistical Mechanics · Physics 2021-04-13 Jian-Ping Lv , Wanwan Xu , Yanan Sun , Kun Chen , Youjin Deng

Linear scaling density functional theory approaches to electronic structure are often based on the tendency of electrons to localize even in large atomic and molecular systems. However, in many cases of actual interest, for example in…

Chemical Physics · Physics 2022-03-25 Marcel David Fabian , Ben Shpiro , Roi Baer

We introduce an energy functional for ground-state electronic structure calculations. Its variables are the natural spin-orbitals of singlet many-body wave functions and their joint occupation probabilities deriving from controlled…

Chemical Physics · Physics 2016-12-04 Ralph Gebauer , Morrel H. Cohen , Roberto Car

We improved a previously proposed method of using closed-orbit modulation for linear optics correction. Instead of fitting individual closed orbits, the improved method decomposes the orbit oscillation data into two orthogonal modes and…

Accelerator Physics · Physics 2023-06-14 Xiaobiao Huang , Xi Yang

We introduce a method for solving a self consistent electronic calculation within localized atomic orbitals, that allows us to converge to the complete basis set (CBS) limit in a stable, controlled, and systematic way. We compare our…

Strongly Correlated Electrons · Physics 2015-05-19 S. Azadi , C. Cavazzoni , S. Sorella