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A new scheme for constructing approximate effective electron potentials within density-functional theory is proposed. The scheme consists of calculating the effective potential for a series of reference systems, and then using these…

Condensed Matter · Physics 2016-08-14 K. Stokbro , N. Chetty , K. W. Jacobsen , J. K. Nørskov

Recent advances in convex optimization have leveraged computer-assisted proofs to develop optimized first-order methods that improve over classical algorithms. However, each optimized method is specially tailored for a particular problem…

Optimization and Control · Mathematics 2025-07-01 Jinho Bok , Jason M. Altschuler

We analyze the inverse problem of Density Functional Theory using a regularized variational method. First, we show that given $k$ and a target density $\rho$, there exist potentials having $k^{\text{th}}$ bound mixed states which densities…

Mathematical Physics · Physics 2022-07-01 Louis Garrigue

Deriving accurate energy density functional is one of the central problems in condensed matter physics, nuclear physics, and quantum chemistry. We propose a novel method to deduce the energy density functional by combining the idea of the…

Strongly Correlated Electrons · Physics 2018-03-01 Haozhao Liang , Yifei Niu , Tetsuo Hatsuda

The motivation for this paper stems from the desire to develop an adaptive sampling method for solving constrained optimization problems in which the objective function is stochastic and the constraints are deterministic. The method…

Optimization and Control · Mathematics 2021-01-01 Yuchen Xie , Raghu Bollapragada , Richard Byrd , Jorge Nocedal

We consider optimal control problems where the state equation is an elliptic PDE of a Schr\"odinger type, governed by the Laplace operator $-\Delta$ with the addition of a potential V, and the control is the potential V itself, that may…

Optimization and Control · Mathematics 2017-10-24 Giuseppe Buttazzo , Faustino Maestre , Bozhidar Velichkov

The grand potential of a system of interacting electrons is considered as a stationary point of a self-energy functional. It is shown that a rigorous evaluation of the functional is possible for self-energies that are representable within a…

Strongly Correlated Electrons · Physics 2009-11-10 Michael Potthoff

The purpose of this paper is to characterize the weak efficient solutions, the efficient solutions, and the isolated efficient solutions of a given vector optimization problem with finitely many convex objective functions and infinitely…

Optimization and Control · Mathematics 2016-08-11 Miguel A. Goberna , Nader Kanzi

In theories with spontaneous symmetry breaking, the conventional effective potential possesses a defective loop expansion. For such theories, the exact effective potential $V(\phi_c,T)$ is real and convex, but its perturbative series is…

High Energy Physics - Phenomenology · Physics 2009-10-22 Kevin Cahill

In this paper, we propose new proximal Newton-type methods for convex optimization problems in composite form. The applications include model predictive control (MPC) and embedded MPC. Our new methods are computationally attractive since…

Optimization and Control · Mathematics 2020-07-21 Ilan Adler , Zhiyue Tom Hu , Tianyi Lin

Motivated by a long-standing conjecture of Polya and Szeg\"o about the Newtonian capacity of convex bodies, we discuss the role of concavity inequalities in shape optimization, and we provide several counterexamples to the…

Optimization and Control · Mathematics 2011-02-10 Dorin Bucur , Ilaria Fragalà , Jimmy Lamboley

This paper considers an optimization problem for a dynamical system whose evolution depends on a collection of binary decision variables. We develop scalable approximation algorithms with provable suboptimality bounds to provide…

Optimization and Control · Mathematics 2016-10-31 Insoon Yang , Samuel A. Burden , Ram Rajagopal , S. Shankar Sastry , Claire J. Tomlin

The non-convex complementarity constraints present a fundamental computational challenge in energy constrained optimization problems. In this work, we present a new, linear, and robust battery optimization formulation that sidesteps the…

Optimization and Control · Mathematics 2021-09-13 Nawaf Nazir , Mads Almassalkhi

Discrete-time robust optimal control problems generally take a min-max structure over continuous variable spaces, which can be difficult to solve in practice. In this paper, we extend the class of such problems that can be solved through a…

Optimization and Control · Mathematics 2024-04-30 Jad Wehbeh , Eric C. Kerrigan

This paper suggests two novel ideas to develop new proximal variable-metric methods for solving a class of composite convex optimization problems. The first idea is a new parameterization of the optimality condition which allows us to…

Optimization and Control · Mathematics 2018-12-14 Quoc Tran-Dinh , Liang Ling , Kim-Chuan Toh

We consider a deterministic continuous time model of monopolistic firm, which chooses production and pricing strategies of a single good. Firm's goal is to maximize the discounted profit over infinite time horizon. The no-backlogging…

Optimization and Control · Mathematics 2016-01-19 Dmitry B. Rokhlin , Georgii Mironenko

A uniform derivation is presented of the self-consistent field equations in a finite basis set. Both restricted and unrestricted Hartree-Fock (HF) theory as well as various density functional (DF) approximations are considered. The unitary…

Computational Physics · Physics 2020-03-10 Susi Lehtola , Frank Blockhuys , Christian Van Alsenoy

In practical implementations of density-functional theory, the only term where an orbital description is needed is the kinetic one. Even this term in principle depends on the density only, but its explicit form is unknown. We provide a…

Materials Science · Physics 2007-05-23 L. De Santis , R. Resta

The estimation of a density profile from experimental data points is a challenging problem, usually tackled by plotting a histogram. Prior assumptions on the nature of the density, from its smoothness to the specification of its form, allow…

Methodology · Statistics 2015-03-13 Alberto Bernacchia , Simone Pigolotti

Designing high-performance electric machines that maintain their efficiency and reliability under uncertain material and operating conditions is crucial for industrial applications. In this paper, we present a novel framework for robust…

Optimization and Control · Mathematics 2025-04-08 Peter Gangl , Theodor Komann , Nepomuk Krenn , Stefan Ulbrich
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