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We describe a symplectic approach towards thermodynamics in which thermodynamic transformations are described by (symplectic) Hamiltonian dynamics. Upon identifying the spaces of equilibrium states with Lagrangian submanifolds of a…

Mathematical Physics · Physics 2026-05-01 Aritra Ghosh , E. Harikumar

We obtain macroscopic isothermal thermodynamic transformations by space-time scalings of a microscopic Hamiltonian dynamics in contact with a heat bath. The microscopic dynamics is given by a chain of anharmonic oscillators subject to a…

Statistical Mechanics · Physics 2013-10-03 Stefano Olla

We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…

Quantum Physics · Physics 2008-01-23 O. J. E. Maroney

We apply a variant of the Nose-Hoover thermostat to derive the Hamiltonian of a nonextensive system that is compatible with the canonical ensemble of the generalized thermostatistics of Tsallis. This microdynamical approach provides a…

Statistical Mechanics · Physics 2009-11-07 J. S. Andrade , M. P. Almeida , A. A. Moreira , G. A. Farias

Here we investigate how local properties of particles in a thermal bath influence the thermodynamics of the bath. We utilize nanothermodynamics, based on two postulates: that small systems can be treated self-consistently by coupling to an…

Statistical Mechanics · Physics 2022-10-26 Ralph V. Chamberlin , Michael R. Clark , Vladimiro Mujica , George H. Wolf

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

We analyze a steady-state thermoelectric engine, whose working substance consists of two capacitively coupled quantum dots. One dot is tunnel-coupled to a hot reservoir serving as a heat source, the other one to two electrically biased…

Quantum Physics · Physics 2021-02-10 R David Mayrhofer , Cyril Elouard , Janine Splettstoesser , Andrew N Jordan

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

A simple and effective approach to thermodynamics is suggested, which solves the major difficulties in the traditional presentation of the subject. The internal energy is introduced from the behavior of deformable bodies, whereas the…

General Physics · Physics 2012-03-13 Rodrigo de Abreu , Vasco Guerra

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…

Statistical Mechanics · Physics 2009-04-28 D. H. E. Gross

We reconsider the fundamental problem of coarse-graining infinite-dimensional Hamiltonian dynamics to obtain a macroscopic system which includes dissipative mechanisms. In particular, we study the thermodynamical implications concerning…

Mathematical Physics · Physics 2025-06-06 Alexander Mielke , Mark A. Peletier , Johannes Zimmer

Engineering Thermodynamics has been the core course of many science and engineering majors around the world, including energy and power, mechanical engineering, civil engineering, aerospace, cryogenic refrigeration, food engineering,…

Physics Education · Physics 2021-01-19 Di He , Zhipeng Duan , Chaojun Wang , Boshu He

Motivated by the notion that the mathematics of gravity can be reproduced from a statistical requirement of maximal entropy, we study the consequence of introducing an entropic source term in the Einstein-Hilbert action. For a spatially…

General Relativity and Quantum Cosmology · Physics 2024-03-20 Soumya Chakrabarti

We review a series of experimental studies of the thermodynamics of nonequilibrium processes at the microscale. In particular, in these experiments we studied the fluctuations of the thermodynamic properties of a single optically-trapped…

Statistical Mechanics · Physics 2016-06-22 L. Dinis , I. A. Martínez , É. Roldán , J. M. R. Parrondo , R. A. Rica

The basic idea of a microscopic understanding of Thermodynamics is to derive its main features from a microscopic probability distribution. In such a vein, we investigate the thermal statistics of quasi-probabilities's semi-classical…

Statistical Mechanics · Physics 2016-09-20 F. Pennini , A. Plastino , M. C. Rocca

The extension of thermodynamic principles to active matter remains a challenge due to the non-equilibrium nature inherent to active systems. In this study, we introduce a framework to assess entropy in our minimal macroscopic experiment…

Soft Condensed Matter · Physics 2024-09-26 Francesco Romanò , Michael Riedl

The classical thermostatics of equilibrium processes is shown to possess a quantum-mechanical dual theory with a finite-dimensional Hilbert space of quantum states. Specifically, the kernel of a certain Hamiltonian operator becomes the…

Mathematical Physics · Physics 2017-04-05 D. Cabrera , P. Fernandez de Cordoba , J. M. Isidro , J. Vazquez Molina

Based on the property of extensivity (mathematically, homogeneity of first degree), we derive in a mathematically consistent manner the explicit expressions of the chemical potential $\mu$ and the Clausius entropy $S$ for the case of…

Statistical Mechanics · Physics 2013-01-15 Thomas Oikonomou , G. Baris Bagci

We show that classical thermodynamics has a formulation in terms of Hamilton-Jacobi theory, analogous to mechanics. Even though the thermodynamic variables come in conjugate pairs such as pressure/volume or temperature/entropy, the phase…

High Energy Physics - Theory · Physics 2008-11-26 S. G. Rajeev

A generally relativistic theory of thermodynamics is developed, based on four main physical principles: heat is a local form of energy, therefore described by a thermal energy tensor; conservation of mass, equivalent to conservation of…

General Relativity and Quantum Cosmology · Physics 2007-05-23 Sean A. Hayward