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Properly spin-adapted coupled-cluster theory for general open-shell configurations remains an active area of research in electronic structure theory. In this contribution we examine Lindgren's normal-ordered exponential ansatz to correlate…

Chemical Physics · Physics 2024-10-02 Alexander Gunasekera , Nicholas Lee , David P. Tew

In the present article, we review a continual effort on generalization of the Trotter formula to higher-order exponential product formulas. The exponential product formula is a good and useful approximant, particularly because it conserves…

Mathematical Physics · Physics 2011-11-10 Naomichi Hatano , Masuo Suzuki

Methods which aim at universal applicability must be able to describe both weak and strong electronic correlation with equal facility. Such methods are in short supply. The combination of symmetry projection for strong correlation and…

Chemical Physics · Physics 2020-05-14 Yiheng Qiu , Thomas M. Henderson , Jinmo Zhao , Gustavo E. Scuseria

The unitary coupled cluster (UCC) algorithm is one of the most promising implementations of the variational quantum eigensolver for quantum computers. However, for large systems, the number of UCC factors leads to deep quantum circuits,…

Quantum Physics · Physics 2026-02-17 Jeremy Canfield , Dominika Zgid , J K Freericks

Operator entanglement of two-qubit joint unitary operations is revisited. Schmidt number is an important attribute of a two-qubit unitary operation, and may have connection with the entanglement measure of the unitary operator. We found the…

Quantum Physics · Physics 2015-06-04 Hui-Zhi Xia , Chao Li , Qing Yang , Ming Yang , Zhuo-Liang Cao

We study the entanglement of unitary operators on $d_1\times d_2$ quantum systems. This quantity is closely related to the entangling power of the associated quantum evolutions. The entanglement of a class of unitary operators is quantified…

Quantum Physics · Physics 2009-11-07 X. Wang , P. Zanardi

Quantum cluster theories are a set of approaches for the theory of correlated and disordered lattice systems, which treat correlations within the cluster explicitly, and correlations at longer length scales either perturbatively or within a…

Superconductivity · Physics 2009-11-11 T. A. Maier , M. S. Jarrell , D. J. Scalapino

Coupled cluster theory produced arguably the most widely used high-accuracy computational quantum chemistry methods. Despite the approach's overall great computational success, its mathematical understanding is so far limited to results…

Algebraic Geometry · Mathematics 2024-03-29 Fabian M. Faulstich , Mathias Oster

The Trotter product formula is a key instrument in numerical simulations of quantum systems. However, computers cannot deal with continuous degrees of freedom, such as the position of particles in molecules, or the amplitude of…

Quantum Physics · Physics 2024-02-29 Daniel Burgarth , Niklas Galke , Alexander Hahn , Lauritz van Luijk

Product formulas can be used to simulate Hamiltonian dynamics on a quantum computer by approximating the exponential of a sum of operators by a product of exponentials of the individual summands. This approach is both straightforward and…

Quantum Physics · Physics 2019-09-04 Andrew M. Childs , Aaron Ostrander , Yuan Su

Using some modification of the standard fermion technique we derive factorized formula for spin operator matrix elements (form-factors) between general eigenstates of the Hamiltonian of quantum Ising chain in a transverse field of finite…

Statistical Mechanics · Physics 2011-12-05 N. Iorgov , V. Shadura , Yu. Tykhyy

Shape dependence of higher order correlations introduces complication in direct determination of these quantities. For this reason theoretical and observational progress has been restricted in calculating one point distribution functions…

Astrophysics · Physics 2007-05-23 Dipak Munshi , Adrian L. Melott

Efficiently calculating the low-lying eigenvalues of Hamiltonians, written as sums of Pauli operators, is a fundamental challenge in quantum computing. While various methods have been proposed to reduce the complexity of quantum circuits…

Quantum Physics · Physics 2025-08-08 Abhinav Anand , Kenneth R. Brown

Conventional clustering methods based on pairwise affinity usually suffer from the concentration effect while processing huge dimensional features yet low sample sizes data, resulting in inaccuracy to encode the sample proximity and…

Machine Learning · Computer Science 2023-02-06 Hongmin Cai , Fei Qi , Junyu Li , Yu Hu , Yue Zhang , Yiu-ming Cheung , Bin Hu

Some mathematical models of applied problems lead to the need of solving boundary value problems with a fractional power of an elliptic operator. In a number of works, approximations of such a nonlocal operator are constructed on the basis…

Numerical Analysis · Computer Science 2019-05-28 Petr N. Vabishchevich

This paper introduces a novel ansatz-based technique for solution of the Hubbard model over two length scales. Short range correlations are treated exactly using a dynamical cluster approximation QMC simulation, while longer-length-scale…

Strongly Correlated Electrons · Physics 2009-11-10 J. P. Hague , Mark Jarrell , T. C. Schulthess

The Macdonald operator is known to coincide with a certain element of the quantum toroidal $\mathfrak{gl}(1)$ algebra in the Fock representation of levels $(1,0)$. A generalization of this operator to higher levels $(r,0)$ can be built…

Mathematical Physics · Physics 2025-10-03 Jean-Emile Bourgine , Luca Cassia , Artem Stoyan

An exact invariant operator of time-dependent coupled oscillators is derived using the Liouville-von Neumann equation. The unitary relation between this invariant and the invariant of two uncoupled simple harmonic oscillators is…

Quantum Physics · Physics 2022-10-17 Jeong Ryeol Choi

The operator-Schmidt decomposition is useful in quantum information theory for quantifying the nonlocality of bipartite unitary operations. We construct a family of unitary operators on C^n tensor C^n whose operator-Schmidt decompositions…

Quantum Physics · Physics 2009-11-10 Jon E Tyson

Unitary Coupled Cluster (UCC) theory is a promising variational method for electronic structure calculations, especially for strongly correlated systems and quantum computers. However, its practical application is limited by the steep…

Chemical Physics · Physics 2026-02-05 Prateek Vaish , Brenda Rubenstein