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The two-dimensional organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ undergoes a metal-insulator transition at $T_{\rm CO}=135$ K due to electronic charge ordering. We have conducted time-resolved investigations of its electronic properties…

Strongly Correlated Electrons · Physics 2016-06-15 Tobias Peterseim , Tomislav Ivek , Dieter Schweitzer , Martin Dressel

The conducting state of the quasi-two-dimensional organic conductor, $\alpha$-(BEDT-TTF)$_2$I$_3$, at ambient pressure is investigated with $^{13}$C NMR measurements, which separate the local electronic states at three nonequivalent…

Materials Science · Physics 2011-10-04 Michihiro Hirata , Kyohei Ishikawa , Kazuya Miyagawa , Kazushi Kanoda

A detailed investigation of the out-of-plane electrical properties of charge-ordered alpha-(BEDT-TTF)2I3 provides clear evidence for ferroelectricity. Similar to multiferroic alpha-(BEDT-TTF)2Cu[N(CN)2]Cl, the polar order in this material…

Strongly Correlated Electrons · Physics 2015-06-22 P. Lunkenheimer , B. Hartmann , M. Lang , J. Müller , D. Schweitzer , S. Krohns , A. Loidl

We investigate low-temperature electronic states of the series of organic conductors $\beta^{\prime\prime}$-(BEDT-TTF)$_4$[(H$_3$O)M(C$_2$O$_4$)$_3$]G, where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene, and M and G represent trivalent…

Strongly Correlated Electrons · Physics 2019-12-25 S. Imajo , H. Akutsu , A. Akutsu-Sato , A. L. Morritt , L. Martin , Y. Nakazawa

The organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ provides the prime example of a charge-order-driven metal-insulator transition. Restricted chemical substitution of S atoms by Se in the constituent molecules allows us to modify the…

The quasi-one-dimensional organic conductors (TMTTF)$_2X$ with non-centrosymmetric anions commonly undergo charge- and anion-order transitions upon cooling. While for compounds with tetrahedral anions ($X$ = BF$_4^-$, ReO$_4^-$, and…

Strongly Correlated Electrons · Physics 2021-04-23 Olga Iakutkina , Lena Nadine Majer , Guilherme Gorgen Lesseux , Gabriele Untereiner , Martin Dressel

We theoretically investigate charge order and nonlinear conduction in a quasi-two-dimensional organic conductor \beta-(meso-DMBEDT-TTF)2PF6 [DMBEDT-TTF=dimethylbis(ethylenedithio)tetrathiafulvalene]. Within the Hartree-Fock approximation,…

Strongly Correlated Electrons · Physics 2013-10-28 Yasuhiro Tanaka , Kenji Yonemitsu

We present $^{127}$I nuclear quadrupole resonance spectra and nuclear relaxation of $\alpha$-(BEDT-TTF)$_2$I$_3$ that undergoes a charge-ordering transition. Only one of the two I$_3$ anion sites shows a significant differentiation in the…

Strongly Correlated Electrons · Physics 2025-09-29 T. Kobayashi , Y. Kato , H. Taniguchi , T. Tsumuraya , K. Hiraki , S. Fujiyama

Motivated by recent experimental suggestions of charge-order-driven ferroelectricity in organic charge-transfer salts, such as $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Cl, we investigate magnetic and charge-ordered phases that emerge in an…

Strongly Correlated Electrons · Physics 2017-10-30 Ryui Kaneko , Luca F. Tocchio , Roser Valentí , Federico Becca

We theoretically discuss the mechanism for the peculiar nonlinear conduction in quasi-two-dimensional organic conductors \theta-(BEDT-TTF)2X [BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene] through the melting of stripe-type charge order.…

Strongly Correlated Electrons · Physics 2011-10-17 Yasuhiro Tanaka , Kenji Yonemitsu

$\alpha$-(BEDT-TTF)$_2$I$_3$ is a prominent example of charge ordering among organic conductors. In this work we explore the details of transport within the charge-ordered as well as semimetallic phase at ambient pressure. In the…

The spatial charge arrangement of a typical quasi-two-dimensional organic conductor alpha-(BEDT-TTF)2I3 is revealed by single crystal structure analysis using synchrotron radiation. The results show that the horizontal stripe type…

Strongly Correlated Electrons · Physics 2009-11-13 Toru Kakiuchi , Yusuke Wakabayashi , Hiroshi Sawa , Toshihiro Takahashi , Toshikazu Nakamura

The effects of electron correlation in the quasi-two-dimensional organic conductor \alpha-(BEDT-TTF)2I3 are investigated theoretically by using an extended Hubbard model with on-site and nearest-neighbor Coulomb interactions. A variational…

Strongly Correlated Electrons · Physics 2016-09-13 Yasuhiro Tanaka , Masao Ogata

We derive the nonlinear optical conductivity of an isotropic electron fluid at frequencies below the interparticle collision rate. In this regime, governed by hydrodynamics, the conductivity acquires a universal form at any temperature,…

Mesoscale and Nanoscale Physics · Physics 2018-02-22 Zhiyuan Sun , D. N. Basov , M. M. Fogler

The organic salt $\alpha$-(BEDT-TTF)$_2$I$_3$ is considered a model system for metal-insulator transition due to electronic charge ordering at $T_{\rm CO}=135$~K. The optical properties obtained from polarized reflection measurements above…

Strongly Correlated Electrons · Physics 2016-03-25 T. Peterseim , M. Dressel

Low-dimensional organic conductors show a rich phase diagram, which has, despite all efforts, still some unexploed regions. Charge ordered phases present in many compounds of the (TMTTF)$_2 X$ family are typically studied with their unique…

Transport properties of the charge ordering compound $\beta-$Na$_{0.33}$V$_2$O$_5$ are studied in the temperature range from 30 K to 300 K using current driven DC conductivity experiments. It is found that below the metal-insulator…

Strongly Correlated Electrons · Physics 2009-11-11 S. Sirbu , P. H. M. van Loosdrecht , T. Yamauchi , Y. Ueda , .

While the optical properties of the superconducting salt $\alpha$-(BEDT-TTF)$_2$NH$_4$Hg(SCN)$_4$ remain metallic down to 2 K, in the non-superconducting K-analog a pseudogap develops at frequencies of about 200 cm$^{-1}$ for temperatures T…

Strongly Correlated Electrons · Physics 2013-05-29 M. Dressel , N. Drichko , J. Schlueter , J. Merino

We report comprehensive Raman and infrared investigations of charge-order (CO) fluctuations in the organic metal $\beta^{\prime\prime}$-(BEDT-TTF)$_2$SF$_5$CHFSO$_3$ and superconductor…

The charge response of charge-ordered state in the organic conductor alpha-(BEDT-TTF)2I3 is characterized by dc resistivity, dielectric and optical spectroscopy in different crystallographic directions within the two-dimensional conduction…

Strongly Correlated Electrons · Physics 2010-05-27 T. Ivek , B. Korin-Hamzic , O. Milat , S. Tomic , C. Clauss , N. Drichko , D. Schweitzer , M. Dressel
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