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Within the framework of nonequilibrium Green's functions, we investigate the thermoelectric transport in a single molecular junction with electron-phonon and electron-electron interactions. By transforming into a displaced phonon basis, we…

Mesoscale and Nanoscale Physics · Physics 2012-04-26 Jie Ren , Jian-Xin Zhu , James E. Gubernatis , Chen Wang , Baowen Li

Electronic current flowing in a molecular electronic junction dissipates significant amounts of energy to vibrational degrees of freedom, straining and rupturing chemical bonds and often quickly destroying the integrity of the molecular…

Mesoscale and Nanoscale Physics · Physics 2020-09-25 Riley J. Preston , Thomas D. Honeychurch , Daniel S. Kosov

Phonon-phonon interaction is systematically studied by nonequilibrium Green's function (NEGF) formulism in momentum space at finite temperatures. Within the quasi-particle approximation, phonon frequency shift and lifetime are obtained from…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Yong Xu , Jian-Sheng Wang , Wenhui Duan , Bing-Lin Gu , Baowen Li

We present a formulation of a nonequilibrium Green's function method for thermal current in nanojunction atomic systems with nonlinear interactions. This first-principle approach is applied to the calculation of the thermal conductance in…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jian-Sheng Wang , Jian Wang , Nan Zeng

A nonperturbative dynamical coupling approach based on tight-binding molecular dynamics is used to evaluate the electron-ion (electron-phonon) coupling parameter in irradiated semiconductors as a function of the electronic temperature up to…

Materials Science · Physics 2023-10-25 Nikita Medvedev

We present an \emph{ab initio} study of the role of interference effects in the thermal conductance of single-molecule junctions. To be precise, using a first-principles transport method based on density functional theory, we analyze the…

Mesoscale and Nanoscale Physics · Physics 2017-12-27 J. C. Klöckner , J. C. Cuevas , F. Pauly

The energy dissipation and heat flows associated with the particle current in a system with a molecular junction are considered. In this connection, we determine the effective temperature of the molecular oscillator that is compatible with…

Mesoscale and Nanoscale Physics · Physics 2018-03-20 Jan Loos , Thomas Koch , Holger Fehske

Understanding phonon transport at a molecular scale is fundamental to the development of high-performance thermoelectric materials for the conversion of waste heat into electricity. We have studied phonon and electron transport in alkane…

Mesoscale and Nanoscale Physics · Physics 2015-11-13 Hatef Sadeghi , Sara Sangtarash , Colin J. Lambert

An efficient implementation of the nonequilibrium Green function (NEGF) method combined with the density functional theory (DFT) using localized pseudo-atomic orbitals (PAOs) is presented for electronic transport calculations of a system…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Taisuke Ozaki , Kengo Nishio , Hiori Kino

Employing the nonequilibrium Green's function method, we develop a fully quantum mechanical model to study the coupled electron-phonon transport in one-dimensional atomic junctions in the presence of a weak electron-phonon interaction. This…

Mesoscale and Nanoscale Physics · Physics 2008-03-04 J. T. Lü , Jian-Sheng Wang

A three terminal nanoscale refrigeration concept based on a vibron-coupled quantum dot hybrid system coupled to two electronic reservoirs and a phonon bath is proposed and analyzed in detail. While investigating the non-trivial role of…

Mesoscale and Nanoscale Physics · Physics 2021-02-03 Swarnadip Mukherjee , Bitan De , Bhaskaran Muralidharan

Due to their small size and unique properties, single-molecule electronics have long seen research interest from experimentalists and theoreticians alike. From a theoretical standpoint, modeling these systems using electronic structure…

Chemical Physics · Physics 2021-10-04 Andrew M. Sand , Justin T. Malme , Erik P. Hoy

Heating and heat conduction in molecular junctions are considered within a general NEGF formalism. We obtain a unified description of heating in current carrying molecular junctions as well as the electron and phonon contributions to the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Mark A. Ratner , Abraham Nitzan

We study inelastic electron tunneling through a molecular junction using the non-equilibrium Green function (NEGF) formalism. The effect of the mutual influence between the phonon and the electron subsystems on the electron tunneling…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Michael Galperin , Mark A. Ratner , Abraham Nitzan

Thermal engineering of quantum devices has attracted much attention since the discovery of quantized thermal conductance of phonons. Although easily submerged in numerous excitations in macro-systems, quantum behaviors of phonons manifest…

Materials Science · Physics 2020-10-02 Xiaobin Chen , Yizhou Liu , Wenhui Duan

The thermoelectric properties of a molecular junction model, appropriate for large molecules such as fullerenes, are studied within a non-equilibrium adiabatic approach in the linear regime at room temperature. A self-consistent calculation…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. A. Perroni , D. Ninno , V. Cataudella

Despite the uniquely high thermal conductivity of graphene is well known, the exploitation of graphene into thermally conductive nanomaterials and devices is limited by the inefficiency of thermal contacts between the individual nanosheets.…

The linear thermoelectric properties of molecular junctions are theoretically studied close to room temperature within a model including electron-electron and electron-vibration interactions on the molecule. A nonequilibrium adiabatic…

Mesoscale and Nanoscale Physics · Physics 2015-11-26 C. A. Perroni , D. Ninno , V. Cataudella

While heating of a current carrying Ohmic conductors is an obvious consequence of the diffusive nature of the conduction in such systems, current induced cooling has been recently reported in some molecular conduction junctions. In this…

Mesoscale and Nanoscale Physics · Physics 2009-09-25 Michael Galperin , Keiji Saito , Alexander V. Balatsky , Abraham Nitzan

We consider an open molecular junction in which electrons are coupled to multi-mode phonons. Using a master equation approach for equilibrated phonons, we show that nearly-degenerate phonon modes can be mapped into an effective single mode,…

Mesoscale and Nanoscale Physics · Physics 2021-09-07 Amir Eskandari-asl
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