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The theory for the generation of Wannier functions within the generalized Pipek--Mezey approach [Lehtola, S.; J\'onsson, H. J. Chem. Theory Comput. 2014, 10, 642] is presented and an implementation thereof is described. Results are…

Materials Science · Physics 2017-02-15 Elvar Ö. Jónsson , Susi Lehtola , Martti Puska , Hannes Jónsson

The strong boundary normalized condition of wavefunction for fully occupied semicore 3d orbitals leads the linear response DFT+U on such metal oxide to have an insurmountable obstacle in Hubbard U determination. We treated the orbital…

Strongly Correlated Electrons · Physics 2015-11-17 Bolong Huang

Maximally-localized Wannier functions (MLWFs) are a powerful and broadly used tool to characterize the electronic structure of materials, from chemical bonding to dielectric response to topological properties. Most generally, one can…

Computational Physics · Physics 2023-11-07 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari

We report a theoretical scheme that enables the calculation of maximally localized Wannier functions in the formalism of projector-augmented-waves (PAW) which also includes the ultrasoft-pseudopotential (USPP) approach. We give a…

Soft Condensed Matter · Physics 2007-05-23 Andrea Ferretti , Arrigo Calzolari , Benedetta Bonferroni , Rosa Di Felice

Let $ E $ be a space of holomorphic functions on the unit ball $ B_X $ of a Banach space $ X.$ In this work, we introduce a Banach structure associated to $ E $ on the linear space $ WE(Y) $ containing $ Y$-valued holomorphic functions on $…

Functional Analysis · Mathematics 2022-03-08 Thai Thuan Quang

We present a rapidly convergent scheme for computing globally optimal Wannier functions of isolated single bands for matrix models in two dimensions. The scheme proceeds first by constructing provably exponentially localized Wannier…

Mathematical Physics · Physics 2025-04-24 Hanwen Zhang

Gapped periodic quantum systems exhibit an interesting Localization Dichotomy, which emerges when one looks at the localization of the optimally localized Wannier functions associated to the Bloch bands below the gap. As recently proved,…

Mathematical Physics · Physics 2019-09-10 Giovanna Marcelli , Domenico Monaco , Massimo Moscolari , Gianluca Panati

An ab initio Hartree-Fock approach aimed at directly obtaining the localized orthogonal orbitals (Wannier functions) of a crystalline insulator is described in detail. The method is used to perform all-electron calculations on the ground…

Condensed Matter · Physics 2009-10-30 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

We derive a multi-band formulation of the orbital magnetization in a normal periodic insulator (i.e., one in which the Chern invariant, or in 2d the Chern number, vanishes). Following the approach used recently to develop the single-band…

Materials Science · Physics 2009-11-11 Davide Ceresoli , T. Thonhauser , David Vanderbilt , R. Resta

A new method for calculation of band structure has been proposed based on the Green's function theory and local sampling. Potential energy in the Hamiltonian of Schrodinger's equation is approximated with a series of sampled Dirac delta…

Mesoscale and Nanoscale Physics · Physics 2010-02-24 Milad Khoshnegar , Sina Khorasani , Amirhossein Hosseinnia

The electronic structure of solids can routinely be calculated by standard methods like density functional theory. However, in complicated situations like interfaces, grain boundaries or contact geometries one needs to resort to more…

Materials Science · Physics 2025-11-18 Henrik Dick , Thomas Dahm

It is believed that the density functional theory (DFT) describes most elements with s, p and d orbitals very well, except some materials that having strongly localized and correlated valence electrons. In this work, we find that the widely…

Materials Science · Physics 2020-03-17 Y. X. Wang , Hua Y. Geng , Q. Wu , Xiang R. Chen

Molecular dipole moment in liquid water is an intriguing property, partly due to the fact that there is no unique way to partition the total electron density into individual molecular contributions. The prevailing method to circumvent this…

Chemical Physics · Physics 2021-05-17 Lisanne Knijff , Chao Zhang

We present an automatized approach towards maximally localized Wannier functions (MLWFs) applicable to both occupied and unoccupied states. We overcome limitations of the standard optimized projection function (OPF) method and its…

Materials Science · Physics 2025-02-17 Sebastian Tillack , Claudia Draxl

Second-order topological insulators can be characterized by their bulk polarization, which is believed to be intrinsically connected to the center of the Wannier function. In this study, we demonstrate the existence of second-order…

Mesoscale and Nanoscale Physics · Physics 2024-05-06 Zhenzhen Liu , Xiaoxi Zhou , Guochao Wei , Lei Gao , Bo hou , Jun-Jun Xiao

In this work, we use Wannier functions to analyze topological phase transitions in one dimensional photonic crystals. We first review the construction of exponentially localized Wannier functions in one dimension, and show how to…

Optics · Physics 2022-06-07 Vaibhav Gupta , Barry Bradlyn

By means of first-principles density functional calculations, we study the maximally localized Wannier functions for the 2D transition metal dichalcogenides MX2 (M=Mo,W X=S,Se,Te). We found a M^+4-like ionic charge and a single occupied…

Materials Science · Physics 2026-01-13 Carmine Autieri , Adrien Bouhon , Biplab Sanyal

We present a general method of constructing maximally localized Wannier functions. It consists of three steps: (1) picking a localized trial wave function, (2) performing a full band projection, and (3) orthonormalizing with the Lowdin…

Other Condensed Matter · Physics 2017-01-11 Junbo Zhu , Zhu Chen , Biao Wu

This paper extends earlier work on the definition of Wannier functions for Bloch electrons in a magnetic field. Extensions to irrational as well as rational magnetic fields are defined, and their properties investigated. The results are…

Condensed Matter · Physics 2009-10-31 Michael Wilkinson

We describe a robust method for determining Pipek-Mezey (PM) Wannier functions (WF), recently introduced by J\'onsson et al. (J. Chem. Theor. Chem. 2017, 13, 460), which provide some formal advantages over the more common Boys (also known…

Chemical Physics · Physics 2024-07-30 Marjory C. Clement , Xiao Wang , Edward F. Valeev