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$\mathrm{HfO_2}$-based dielectrics are promising for nanoscale ferroelectric applications, and the most favorable material within the family is Zr-substituted hafnia, i.e., $\mathrm{Hf_{1-x}Zr_xO_2}$ (HZO). The extent of Zr substitution can…

Materials Science · Physics 2024-09-17 Jinhai Huang , Ge-Qi Mao , Kan-Hao Xue , Shengxin Yang , Fan Ye , Huajun Sun , Xiangshui Miao

New approaches for the design of alloy systems with multiprincipal elements is recently researched in refractory materials field. However, most research aimed at arc melting process with weakness of coarsening of grains and inhomogeneous…

Materials Science · Physics 2018-01-03 Yuqiao Li , Junho Lee , Byungchul Kang , Soon Hyung Hong

Doped strontium titanate SrTiO$_3$ (STO) is one of the most dilute superconductors known today. The fact that superconductivity occurs at very low carrier concentrations is one of the two reasons that the pairing mechanism is not yet…

Superconductivity · Physics 2022-01-11 C. W. Rischau , D. Pulmannova , G. W. Scheerer , A. Stucky , E. Giannini , D. van der Marel

CeO2 and Ce0.9Zr0.1O2 are prepared from the sol-gel method to investigate and compare their electrochemical properties for supercapacitor applications. Structural, morphological, and elemental studies have been done for CeO2 and…

Materials Science · Physics 2021-01-11 Sourav Ghosh , G. Ranga Rao , Tiju Thomas

Ternary intermetallic half-Heusler (HH) compounds (XYZ) with 18 valence electron count viz. ZrCoSb, ZrNiSn, and ZrPdSn, have revealed promising thermoelectric properties. Exemplarily, it has been experimentally observed that a slight change…

Materials Science · Physics 2021-11-02 Parul R. Raghuvanshi , Dipanwita Bhattacharjee , Amrita Bhattacharya

We describe, within an ab-initio approach, the stabilization of the tetragonal phase vs. the monoclinic one in Yttrium-doped Zirconia. The process is believed to be influenced from different mechanisms. Indeed we show that there is a…

Materials Science · Physics 2012-01-25 Davide Sangalli , Alberto Debernardi

The variation in local atomic structure and chemical bonding of ZrHx (x=0.15, 0.30, 1.16) magnetron sputtered thin films are investigated by Zr K-edge (1s) X-ray absorption near-edge structure and extended X-ray absorption fine structure…

Materials Science · Physics 2017-11-28 Martin Magnuson , Fredrik Eriksson , Lars Hultman , Hans Högberg

The electronic structures of TixZrx/2CoPbxTex, TixZrx/2Hfx/2CoPbxTex (x = 0.5), and the parent compound TiCoSb were investigated using the full potential linearized augmented plane wave method. The thermoelectric transport properties of…

Materials Science · Physics 2018-05-23 Mukesh K. Choudhary , P. Ravindran

We have investigated the effect of transition metal dopants on the local structure of the prototypical 0.75 Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$-0.25 PbTiO$_3$ relaxor ferroelectric. We find that these dopants give rise to very different local…

Materials Science · Physics 2018-05-09 Hengxin Tan , Hiroyuki Takenaka , Changsong Xu , Wenhui Duan , Ilya Grinberg , Andrew M. Rappe

Wurtzite-ZnO is a wide-bandgap polar material with a ferroelectric-switching barrier that is too high to utilize, but the barrier can be reduced and switching observed in substituted materials such as Zn0.5Mg0.5O. Here, we seek to…

Materials Science · Physics 2026-01-22 Lingyao Zhang , Musen Li , Nisha Metha , Carla Verdi , Wei Ren , Jeffrey R. Reimers

We carry out temperature-dependent scanning tunneling microscopy (STM) studies of the charge density wave (CDW) compound ZrTe$_3$ which is intentionally doped with Hf. Previous bulk studies tie Hf doping to an enhancement of the CDW…

We observed a large decrease of Tc by no more than 3 at.% of Zn doped to the optimized superconductor LaFeAsO0.85 (Tc = 26 K), confirmed by measurements of electrical resistivity, magnetic susceptibility, specific heat, M\"ossbauer…

Conventional Oxide dispersion strengthened steels are characterized by thermally stable, high density of Y-Ti-O nanoclusters, which are responsible for their high creep strength. Ti plays a major role in obtaining a high density of…

Materials Science · Physics 2021-06-01 Sruthi Mohan , Gurpreet Kaur , B. K. Panigrahi , C. David , G. Amarendra

We have developed a simple, surfactant assisted synthesis route for the preparation, in gram quantities, of Co and Li doped ZnO nanocrystalline samples showing robust room temperature ferromagnetism. Our studies show that RTF is intrinsic…

Materials Science · Physics 2007-05-23 onattu D. Jayakumar , Iyyani K. Gopalakrishnan , Shailendra K. Kulshreshtha

Two-dimensional transition metal trichalcogenides (TMTC's) feature covalently bonded metal-chalcogen layers separated by the van der Waals (vdW) gap. Similar to transition metal dichalcogenides (TMDCs), TMTCs often host charge density waves…

Strongly Correlated Electrons · Physics 2022-03-01 Yu Liu , Zhixiang Hu , Xiao Tong , Denis Leshchev , Xiangde Zhu , Hechang Lei , Eli Stavitski , Klaus Attenkofer , C. Petrovic

We develop a sub-lattice phase-field model of Hf1-xZrxO2 incorporating zirconium (Zr) concentration (x)-dependence. Our framework expands the time-dependent Ginzburg-Landau (TDGL) equation to the sub-lattice level and incorporates…

Materials Science · Physics 2026-04-08 Tae Ryong Kim , Sumeet K. Gupta

A large body of literature within the additive manufacturing (AM) community has focused on successfully creating stable tungsten (W) microstructures due to significant interest in its application for extreme environments. However,…

Zincblende copper iodide has been attracting growing interest as p-type semiconductor for applications in transparent electronics and transparent thermoelectrics. A key step towards technological applications is the possibility to enhance…

Materials Science · Physics 2022-12-22 Michael Seifert , Miguel A. L. Marques , Silvana Botti

A tetragonal phase is predicted for Hf2O3 and Zr2O3 using density functional theory. Starting from atomic and unit cell relaxations of substoichiometric monoclinic HfO2 and ZrO2, such tetragonal structures are only reached at zero…

Materials Science · Physics 2024-09-17 Kan-Hao Xue , Philippe Blaise , Leonardo R. C. Fonseca , Yoshio Nishi

Tailoring and improving material properties by alloying is a long-known and used concept. Recent research has demonstrated the potential of ab initio calculations in understanding the material properties at the nanoscale. Here we present a…

Materials Science · Physics 2013-10-16 David Holec , Liangcai Zhou , Richard Rachbauer , Paul H. Mayrhofer