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In polarizable materials, electronic charge carriers interact with the surrounding ions, leading to quasiparticle behaviour. The resulting polarons play a central role in many materials properties including electrical transport, optical…

Two-dimensional mixtures of dipolar colloidal particles with different dipole moments exhibit extremely rich self-assembly behaviour and are relevant to a wide range of experimental systems, including charged and super-paramagnetic colloids…

Soft Condensed Matter · Physics 2019-04-16 W. R. C. Somerville , J. L. Stokes , A. M. Adawi , T. S. Horozov , A. J. Archer , D. M. A. Buzza

We investigate spontaneous emission of a two-level atom with an arbitrarily polarized electric dipole in front of a flat dielectric surface. We treat the general case where the atomic dipole matrix element is a complex vector, that is, the…

Quantum Physics · Physics 2016-04-20 Fam Le Kien , A. Rauschenbeutel

The local environment of metal-oxide supported single-atom catalysts plays a decisive role in the surface reactivity and related catalytic properties. The study of such systems is complicated by the presence of point defects on the surface,…

Ferroelectric materials can switch their polarization in response to an applied electric field. In this work, ferroelectricity at the single molecule level is proposed and investigated using density functional theory (DFT) calculations.…

Applied Physics · Physics 2017-05-30 Xinfeng Quan , Geoffrey R. Hutchison

Invariance under time translation (or stationarity) is probably one of the most important assumptions made when investigating electromagnetic phenomena. Breaking this assumption is expected to open up novel possibilities and result in…

Applied Physics · Physics 2021-10-06 M. S. Mirmoosa , T. T. Koutserimpas , G. A. Ptitcyn , S. A. Tretyakov , R. Fleury

We have calculated dynamical Casimir-Polder interaction force between a moving ground state atom and a flat polarizable surface. The velocity of an atom can be close to the velocity of light. The material properties are taken into account…

Other Condensed Matter · Physics 2015-05-28 G. V. Dedkov , A. A. Kyasov

The polarization state of the optical electromagnetic field lying several nanometers above complex dielectric structures reveals the intricate light-matter interaction that occurs in this near-field zone. This information can only be…

Ferroelectricity in atomically thin bilayer structures has been recently predicted1 and measured[2-4] in two-dimensional (2D) materials with hexagonal non-centrosymmetric unit-cells. Interestingly, the crystal symmetry translates lateral…

The polarization properties of a magnetophotonic crystal at the frequencies located in the vicinity of ferromagnetic resonance are studied. The investigations are curried out taking into consideration the fact that the magnitude of material…

Optics · Physics 2010-11-17 Vladimir R. Tuz , Mikhail Yu. Vidil , Sergey L. Prosvirnin

A new scenario of thermalization process of the adsorbate attached at solid surfaces is proposed. The scenario is based on existence of electric dipole layer in which the electron wavefunctions extend over the positive ions. Thus the strong…

Chemical Physics · Physics 2017-04-26 Paweł Strak , Konrad Sakowski , Stanisław Krukowski

Orbital-free density functional theory (OF-DFT) provides an alternative approach for calculating the molecular electronic energy, relying solely on the electron density. In OF-DFT, both the ground-state density is optimized variationally to…

Chemical Physics · Physics 2023-11-23 Alexandre de Camargo , Ricky T. Q. Chen , Rodrigo A. Vargas-Hernández

A framework is introduced for expressing electromagnetic (EM) potentials and fields of single atomic or molecular emitters modeled as oscillating dipoles, which follows a recently proposed method for solving inhomogeneous wave equations for…

Quantum Physics · Physics 2026-03-03 Valerica Raicu

We use density functional theory (DFT) with the generalized gradient approximation (GGA) and our first-principles extrapolation method for accurate chemisorption energies {[Mason {\em et al.}, Phys. Rev. B {\bf 69}, 161401R (2004)]} to…

Materials Science · Physics 2007-05-23 Sara E. Mason , Ilya Grinberg , Andrew M. Rappe

Structural disorder causes materials surface electronic properties, e.g. work function ($\phi$) to vary spatially, yet it is challenging to prove exact causal relationships to underlying ensemble disorder, e.g. roughness or granularity. For…

Density functional theory (DFT) is used to study vibrations, electrical dipole moments, and polarizabilities of NaF clusters. Because of prior experimental and theoretical studies, this is a good model system for tracking the evolution of…

Other Condensed Matter · Physics 2007-05-23 Christian Schmidt , Philip B. Allen , Tunna Baruah , Mark Pederson

Density Functional Theory (DFT) calculations were used to evaluate polarity of group III nitrides, such as aluminum nitride (AlN), gallium nitride (GaN) and indium nitride (InN) providing physically sound quantitative measure of polarity of…

Mesoscale and Nanoscale Physics · Physics 2011-11-17 Pawel Strak , Pawel Kempisty , Konrad Sakowski , Stanislaw Krukowski

We have performed a thorough computational study to assess the accuracy of density functional theory (DFT) methods in describing the interactions of CO2 with model alkali-earth-metal (AEM, Ca and Li) decorated carbon structures, namely…

Materials Science · Physics 2013-01-15 Claudio Cazorla , Stephen A. Shevlin

Atomic Force Microscopy (AFM) combined with electrical modes provides a powerful contactless approach to characterize material electrical properties at the nanoscale. However, conventional electrostatic models often overlook dynamic charge…

Mesoscale and Nanoscale Physics · Physics 2025-08-26 Mario Navarro-Rodriguez , Paul Philip Schmidt , Regina Hoffmann-Vogel , Andres M. Somoza , Elisa Palacios-Lidon

Non-local electrodynamic models are developed for describing metallic surfaces for a diffusive metal. The electric field noise at a distance z_0 from the surface is evaluated and compared with data from ion chips that show anomalous heating…

Quantum Physics · Physics 2009-11-13 Carsten Henkel , Baruch Horovitz