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We calculate the two-photon absorption in bulk and single layer hexagonal boron nitride (hBN) both by an ab-initio real-time Bethe-Salpeter approach and by a the real-space solution of the excitonic problem in tight-binding formalism. The…

Materials Science · Physics 2018-10-17 Claudio Attaccalite , Myrta Grüning , Hakim Amara , Sylvain Latil , François Ducastelle

Single-layer $\it{h}$-BN is known to have edges with unique magnetism, however, in the commonly fabricated multilayer $\text{AA}^{\prime}$-$\it{h}$-BN, edge relaxations occur that create interlayer bonds and eliminate the unpaired electrons…

Materials Science · Physics 2020-10-28 Mehmet Dogan , Marvin L. Cohen

Using Density Functional Theory (DFT) method we compute linear optical absorption spectra and nonlinear optical susceptibilities of hydrogen passivated armchair and zigzag Phosphorous Nanoribbons (aPNR and zPNR) as well as \alpha-phase…

Mesoscale and Nanoscale Physics · Physics 2018-07-02 Sima Shekarforoush , Daryoush Shiri , Farhad Khoeini

This study investigates into the adsorption sensing capabilities of single-walled (5,5) boron nitride nanotubes (BNNTs) towards environmental pollutant gas molecules, including CH2, SO2, NH3, H2Se, CO2 and CS2. Employing a linear…

Computational Physics · Physics 2025-11-07 Chaithanya Purushottam Bhat , Joy Mukherjee , Antara Banerjee , Debashis Bandyopadhyay

We show that ordered monolayers of organic molecules stabilized by hydrogen bonding on the surface of exfoliated few-layer hexagonal boron nitride (hBN) flakes may be incorporated into van der Waals heterostructures with integral few-layer…

Cubic boron nitride (cBN) is a wide-bandgap polymorph of boron nitride whose optical response remains only partially understood due to the coexistence of indirect electronic transitions and strong exciton-phonon coupling. Using…

Materials Science · Physics 2026-04-21 Ashwin Pillai , Elena Cannuccia , Aurelien Manchon , Fulvio Paleari , Claudio Attaccalite

The excitonic states of transition metal dichacolgenide (TMD) monolayers are heavily influenced by their external dielectric environment based on the substrate used. In this work, various wide bandgap dielectric materials, namely hexagonal…

Atomically thin two-dimensional (2D) hexagonal boron nitride (hBN) has emerged as an essential material for the encapsulation layer in van der Waals heterostructures and efficient deep ultra-violet optoelectronics. This is primarily due to…

Applied Physics · Physics 2024-09-16 Suk Hyun Kim , Kyeong Ho Park , Young Gie Lee , Seong Jun Kang , Yongsup Park , Young Duck Kim

By investigating the optoelectronic properties of prototypical graphene/hexagonal boron nitride (h-BN) heterostructures, we demonstrate how a nanostructured combination of these materials can lead to a dramatic enhancement of light-matter…

In many atomically thin materials their optical absorption is dominated by excitonic transitions. It was recently found that optical selection rules in these materials are influenced by the band topology near the valleys. We propose that…

Mesoscale and Nanoscale Physics · Physics 2020-10-12 Gaofeng Xu , Tong Zhou , Benedikt Scharf , Igor Žutić

Efficient solid-state photon emitters with longer operating lifetimes in the ultraviolet (UV) wavelength range are crucial for optoelectronic devices. However, finding suitable material candidates has been a significant challenge. Here, we…

Mesoscale and Nanoscale Physics · Physics 2024-09-04 Pushpendra Yadav , Amit Agarwal , Sitangshu Bhattacharya

We investigate the impact of the encapsulation with hexagonal boron nitride (h-BN) on the Raman spectrum of few layer black phosphorus. The encapsulation results in a significant reduction of the line width of the Raman modes of black…

Mesoscale and Nanoscale Physics · Physics 2017-11-23 J. M. Urban , M. Baranowski , A. Surrente , D. Wlodarczyk , A. Suchocki , G. Long , Y. Wang , L. Klopotowski , N. Wang , D. K. Maude , P. Plochocka

Hexagonal boron nitride (hBN) has emerged as a promising ultrathin host of single photon emitters (SPEs) with favorable quantum properties at room temperature, making it a highly desirable element for integrated quantum photonic networks.…

We have calculated the absorption characteristics of different hybrid systems consisting of Ag, Ag2 or Ag3 atomic clusters and poly(methacrylic acid) (PMAA) using the time-dependent density-functional theory. The polymer is found to have an…

Materials Science · Physics 2015-05-18 Laura Koponen , Lasse O. Tunturivuori , Martti J. Puska , Y. Hancock

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla

Employing the density-functional theory with local density approximation, we show that the fully hydrogenated monolayer-hexagonal boron nitride (H$_2$BN) has a direct-band gap of 2.96 eV in the blue-light region while the pristine…

Superconductivity · Physics 2021-10-04 Takat B. Rawal , Ling-Hua Chang , Hao-Dong Liu , Hong-Yan Lu , C. S. Ting

Monolayers of hexagonal boron nitride (h-BN) can in principle be identified by a Raman signature, consisting of an upshift in the frequency of the E2g vibrational mode with respect to the bulk value, but the origin of this shift (intrinsic…

Materials Science · Physics 2018-03-23 Jorge Ontaneda , Anjali Singh , Umesh V. Waghmare , Ricardo Grau-Crespo

Hexagonal boron nitride (h-BN) is a prominent member in the growing family of two-dimensional materials with potential applications ranging from being an atomically smooth support for other 2D materials to templating growth of molecular…

We study defect energy levels in hexagonal boron-nitride with varying number of layers using a fragment many-body $GW$ formalism, taking as examples the paradigmatic carbon-dimer and $C_BV_N$ defects. We show that a single layer can be…

Materials Science · Physics 2022-10-12 David Amblard , Gabriele D'Avino , Ivan Duchemin , Xavier Blase

The absorption spectra of single-layer GaSe and GaTe in the hexagonal phase feature exciton peaks with distinct polarization selectivity. We investigate these distinct features from first-principle calculations using the GW-BSE formalisms.…

Materials Science · Physics 2018-05-11 Gabriel Antonius , Diana Y. Qiu , Steven G. Louie
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