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We show that the middle-range exchange-correlation hybrid of Henderson, Izmaylov, Scuseria and Savin (HISS) performs extremely well for elemental and binary semiconductors with narrow or visible spectrum band gaps, as well as some wider gap…

Materials Science · Physics 2012-04-27 Melissa J. Lucero , Thomas M. Henderson , Gustavo E. Scuseria

In the effective-mass approximation, the step-like crystal potential of a wurtzite semiconductor heterostucture should be supplemented by Dirac delta-function heterointerface terms. They stem from the difference in the Bloch functions of…

Mesoscale and Nanoscale Physics · Physics 2015-05-05 Eduard Takhtamirov

To obtain accurate independent-particle descriptions for ferromagnetic two-dimensional van der Waals materials, we apply the quasiparticle self-consistent $GW$ (QSGW) method to VI$_3$, CrI$_3$, CrGeTe$_3$, and Fe$_3$GeTe$_2$. QSGW provides…

Strongly Correlated Electrons · Physics 2020-06-09 Y. Lee , Takao Kotani , Liqin Ke

The exfoliation of layered magnetic materials generates atomically thin flakes characterized by an ultrahigh surface sensitivity, which makes their magnetic properties tunable via external stimuli, such as electrostatic gating and proximity…

We analyze the scenario of modulating the potential strength of bound atoms in an optical honeycomb lattice patterned by an electric field to emulate uniaxial strain. This modulation can be achieved by a combination of the strength of the…

Materials Science · Physics 2023-03-06 A. López , B. Montañes , E. Medina

We propose global hybrid approximations of the exchange-correlation (XC) energy functional which reproduce well the modified fourth-order gradient expansion of the exchange energy in the semiclassical limit of many-electron neutral atoms…

Chemical Physics · Physics 2015-01-22 E. Fabiano , L. A. Constantin , P. Cortona , F. Della Sala

A translationally invariant formulation of the Hartree-Fock (HF) $\Gamma$-point approximation is presented. This formulation is achieved through introduction of the Minimum Image Convention (MIC) at the level of primitive two-electron…

Materials Science · Physics 2016-08-16 C. J. Tymczak , Valéry T. Weber , Eric Schwegler , Matt Challacombe

We propose a short- and long-range corrected (SLC) hybrid scheme employing 100% Hartree-Fock (HF) exchange at both zero and infinite interelectronic distances, wherein three SLC hybrid density functionals with the D3 dispersion corrections…

Chemical Physics · Physics 2016-11-23 Chih-Wei Wang , Kerwin Hui , Jeng-Da Chai

A recently proposed approach for performing electronic-structure calculations on crystalline insulators in terms of localized orthogonal orbitals is applied to the oxides of lithium and sodium, Li2O and Na2O. Cohesive energies, lattice…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

We propose a practical way to overcome the ubiquitous problem of the overestimation of the zero-bias and zero-temperature conductance, which is associated to the use of local approximations to the exchange-correlation functional in…

Materials Science · Physics 2009-11-13 Y. Garcia , JC. Sancho-Garcia

We calculate the optical spectra of silicon and germanium in the adiabatic time-dependent density functional formalism, making use of kinetic energy density-dependent (meta-GGA) exchange-correlation functionals. We find excellent agreement…

Strongly Correlated Electrons · Physics 2011-11-16 V. U. Nazarov , G. Vignale

The metal-insulator transition and the problem of d-electron delocalization are investigated in the pyrite system NiS_{2-x}Se_x under pressure using density functional theory (DFT). We test several approximations, including the generalized…

Strongly Correlated Electrons · Physics 2009-11-18 C. Schuster

Density functional theory has been an essential analysis tool for both theoretical and experimental chemists since accurate hybrid functionals were developed. Here we propose a local hybrid method derived from the optimized effective…

Chemical Physics · Physics 2017-03-24 Jaewook Kim , Kwangwoo Hong , Sang-Yeon Hwang , Seongok Ryu , Sunghwan Choi , Woo Youn Kim

The modern semilocal exchange potential is an accurate and efficient approximation to the exact exchange potential of density functional theory. We tried to combine it with the dynamical mean-field theory to derive a new first-principles…

Strongly Correlated Electrons · Physics 2016-09-09 Li Huang , Haiyan Lu

Motivated by the possibility of creating non-Abelian fields using cold atoms in optical lattices, we explore the richness and complexity of non-interacting two-dimensional electron gases (2DEGs) in a lattice, subjected to such fields. In…

Mesoscale and Nanoscale Physics · Physics 2008-04-17 Indubala I. Satija , Daniel C. Dakin , J. Y. Vaishnav , Charles W. Clark

We develop a quantum kinetic theory of two-dimensional electron gases in which exchange is treated self-consistently at the Hartree-Fock level and enters as a nonlocal, momentum-dependent field in phase space. By starting from the Coulomb…

Mesoscale and Nanoscale Physics · Physics 2026-03-30 J. L. Figueiredo , J. T. Mendonça , H. Terças

Following Hollins et al. [J. Phys.: Condens. Matter 29, 04LT01 (2017)], we invert the electronic ground state densities for various semiconducting and insulating solids calculated using several density functional approximations within the…

Chemical Physics · Physics 2025-11-05 Visagan Ravindran , Nikitas I. Gidopoulos , Stewart J. Clark

The evaluation of exact (Hartree--Fock, HF) exchange operator is a crucial ingredient for the accurate description of electronic structure in periodic systems through ab initio and hybrid density functional approaches. An efficient…

Chemical Physics · Physics 2020-10-28 Xiao Wang , Cannada A. Lewis , Edward F. Valeev

The metal-semiconductor contact is a major factor limiting the shrinking of transistor dimension to further increase device performance. In-plane edge contacts have the potential to achieve lower contact resistance due to stronger orbital…

Mesoscale and Nanoscale Physics · Physics 2019-02-15 Wushi Dong , Peter B. Littlewood

The modified Becke-Johnson meta-GGA potential of density functional theory has been shown to be the best exchange-correlation potential to determine band gaps of crystalline solids. However, it cannot be consistently used for the electronic…

Mesoscale and Nanoscale Physics · Physics 2020-04-02 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti