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We report the first observation of substitutional silicon atoms in single-layer hexagonal boron nitride (h-BN) using aberration corrected scanning transmission electron microscopy (STEM). The medium angle annular dark field (MAADF) images…

Materials Science · Physics 2020-01-29 Mohammad Reza Ahmadpour Monazam , Ursula Ludacka , Hannu-Pekka Komsa , Jani Kotakoski

Optically active spin defects in van der Waals materials are promising platforms for modern quantum technologies. Here we investigate the coherent dynamics of strongly interacting ensembles of negatively charged boron-vacancy…

The signature of defects in the optical spectra of hexagonal boron nitride (BN) is investigated using many body perturbation theory. A single BN-sheet serves as a model for different layered BN- nanostructures and crystals. In the sheet we…

Mesoscale and Nanoscale Physics · Physics 2011-05-03 C. Attaccalite , M. Bockstedte , A. Marini , A. Rubio , L. Wirtz

The defect-mediated hexagonal boron nitride (hBN) supercell display the visible optical spectra and electronic characteristics. The defects in the hBN supercell include the atomic vacancy, antisite, antisite vacancy, and substitution of a…

Materials Science · Physics 2019-12-13 Sheng Yu , Bagher Tabibi , Qiliang Li , Felix Jaetae Seo

The $V_N N_B$ defect in hexagonal boron nitride (h-BN), comprising a nitrogen vacancy adjacent to a nitrogen-for-boron substitution, is modelled in regard to its possible usefulness in a nanophotonics device. The modelling is done on both a…

Materials Science · Physics 2020-10-21 A. Sajid , Jeffrey R. Reimers , Rika Kobayashi , Michael J. Ford

Crystal defects in the two-dimensional insulator hexagonal boron nitride (hBN) can host localised electronic states that are candidates for applications in quantum technology, yet the precise chemical and structural nature of the defects…

Materials Science · Physics 2019-12-18 A Sajid , Kristian S Thygesen , Jeffrey R Reimers , Michael J Ford

Hexagonal boron nitride (hBN) has emerged as a promising material platform for nanophotonics and quantum sensing, hosting optically-active defects with exceptional properties such as high brightness and large spectral tuning. However,…

Defect color centers in hexagonal boron nitride (hBN) have gained significant interest as single-photon emitters and spin qubits for applications in a wide range of quantum technologies. As the integration of these solid-state quantum…

Materials Science · Physics 2025-01-23 Madhava Krishna Prasad , Jonathan Paul Goss , Jonathan David Mar

We present a first-principles computational study of the thermodynamics of carbon defects in hexagonal boron nitride (hBN). The defects considered are carbon monomers, dimers, trimers, and larger carbon clusters, as well as complexes of…

Materials Science · Physics 2022-01-28 Marek Maciaszek , Lukas Razinkovas , Audrius Alkauskas

Folded regions are commonly encountered in a number of hexagonal boron nitride (h-BN) based bulk and nanostructured materials. Two types of structural modifications occur in folded h-BN layers: local curvature at the folded edges and…

Materials Science · Physics 2022-11-21 Anthony Impellizzeri , Michele Amato , Chris P. Ewels , Alberto Zobelli

A quantum memory is a crucial keystone for enabling large-scale quantum networks. Applicable to the practical implementation, specific properties, i.e., long storage time, selective efficient coupling with other systems, and a high memory…

Quantum Physics · Physics 2024-05-08 Chanaprom Cholsuk , Asli Cakan , Sujin Suwanna , Tobias Vogl

Optically addressable spin defects in wide-bandage semiconductors as promising systems for quantum information and sensing applications have attracted more and more attention recently. Spin defects in two-dimensional materials are supposed…

Defects in crystals can have a transformative effect on the properties and functionalities of solid-state systems. Dopants in semiconductors are core components in electronic and optoelectronic devices. The control of single color centers…

Among two-dimensional atomic crystals, hexagonal boron nitride (hBN) is one of the most remarkable materials to fabricate heterostructures revealing unusual properties. We perform first-principles calculations to determine whether…

Mesoscale and Nanoscale Physics · Physics 2014-04-09 Sohee Park , Changwon Park , Gunn Kim

Highly correlated orbitals coupled with phonons in two-dimension are identified for paramagnetic and optically active boron vacancy in hexagonal boron nitride by first principles methods which are responsible for recently observed optically…

Mesoscale and Nanoscale Physics · Physics 2019-10-18 Viktor Ivády , Gergely Barcza , Gergő Thiering , Song Li , Hanen Hamdi , Örs Legeza , Jyh-Pin Chou , Adam Gali

Boron vacancies in hexagonal boron nitride (hBN) are among the most extensively studied optically active spin defects in van der Waals crystals, due to their promising potential to develop two-dimensional (2D) quantum sensors. In this…

We investigate the electronic structures of some defective boron nitride nanotubes (BNNTs) under transverse electric fields within density-functional theory. (16,0) BNNTs with antisite, carbon substitution, single vacancy, and Stone-Wales…

Materials Science · Physics 2008-07-11 Shuanglin Hu , Zhenyu Li , X. C. Zeng , Jinlong Yang

Charged defects in 2D materials have emerging applications in quantum technologies such as quantum emitters and quantum computation. Advancement of these technologies requires rational design of ideal defect centers, demanding reliable…

Materials Science · Physics 2017-12-13 Feng Wu , Galatas Andrew , Ravishankar Sundararaman , Dario Rocca , Yuan Ping

The formation energies and transition energy levels of native defects in hexagonal BN have been studied by first-principles calculations based on hybrid density functional theory (DFT) together with an empirical dispersion correction of…

Materials Science · Physics 2015-06-15 V. Wang , R. J. Liu , H. P. He , C. M. Yang , L. Ma

The research focuses on the explanation of a phenomenon observed in the spectra of electron nuclear resonance (ENDOR) pertaining to nitrogen atoms adjacent to the boron vacancy (VB) defect in hexagonal boron nitride (hBN). The phenomenon is…

Materials Science · Physics 2025-02-13 G. V. Mamin , E. V. Dmitrieva , F. F. Murzakhanov , I. N. Gracheva , V. A. Soltamov , M. R. Gafurov