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During the last few years, it has become more and more clear that functionals of the meta generalized gradient approximation (MGGA) are more accurate than GGA functionals for the geometry and energetics of electronic systems. However, MGGA…

Materials Science · Physics 2019-11-04 Fabien Tran , Jan Doumont , Peter Blaha , Miguel A. L. Marques , Silvana Botti , Albert P. Bartók

The $\vartheta$-MGGA class of density functionals is formally reformulated as Hessian-level meta-generalized gradient approximations (HL-MGGAs). In contrast to standard meta-GGAs that rely on the orbital-dependent kinetic-energy density or…

Chemical Physics · Physics 2026-04-09 Pooria Dabbaghi , Juan Maria García Lastra , Piotr de Silva

We present the self-consistent implementation of current-dependent (hybrid) meta generalized gradient approximation (mGGA) density functionals using London atomic orbitals. A previously proposed generalized kinetic energy density is…

We present a study of the equilibrium properties of $sp$-bonded solids within the pseudopotential approach, employing recently proposed generalized gradient approximation (GGA) exchange correlation functionals. We analyze the effects of the…

Condensed Matter · Physics 2016-08-31 Yumin Juan , Efthimios Kaxiras

We present a new nonempirical density functional generalized gradient approximation (GGA) that gives significant improvements for lattice constants, crystal structures, and metal surface energies over the most popular Perdew-Burke-Ernzerhof…

Materials Science · Physics 2009-11-11 Zhigang Wu , Ronald E. Cohen

The Jacob's ladder of density functional theory (DFT) proposes the compelling view that by extending the form of successful approximations -- being guided by exact conditions and selected (least empirical) norms -- upper rungs will do…

Materials Science · Physics 2025-02-25 Jacques K. Desmarais , Alessandro Erba , Giovanni Vignale , Stefano Pittalis

A simple, novel, non-empirical, constraint-based orbital-free generalized gradient approximation (GGA) non-interacting kinetic energy density functional is presented along with illustrative applications. The innovation is adaptation of…

Chemical Physics · Physics 2018-08-01 K. Luo , V. V. Karasiev , S. B. Trickey

A meta generalized gradient level screened range-separated hybrid functional is developed for solid-state electronic structure theory. Assessment of the present range-separated hybrid functional for solid-state lattice constants and band…

Materials Science · Physics 2018-03-13 Subrata Jana , Abhilash Patra , Prasanjit Samal

Computationally-efficient semilocal approximations of density functional theory at the level of the local spin density approximation (LSDA) or generalized gradient approximation (GGA) poorly describe weak interactions. We show improved…

We discuss self-consistently obtained ground-state electronic properties of monolayers of graphene and a number of beyond graphene compounds, including films of transition-metal dichalcogenides (TMDs), using the recently proposed strongly…

Materials Science · Physics 2017-04-27 I. G. Buda , C. Lane , B. Barbiellini , A. Ruzsinszky , J. Sun , A. Bansil

We present a global hybrid meta-generalized gradient approximation (meta-GGA) with three empirical parameters, as well as its underlying semilocal meta-GGA and a meta-GGA with only one empirical parameter. All of them are based on the new…

Using the recently developed version of the GW method employing the one-site approximation and self-consistent quasiparticle basis set we calculated the electronic structure of 3d and 4d transition metals at experimental atomic volumes. The…

Strongly Correlated Electrons · Physics 2007-08-16 K. D. Belashchenko , V. P. Antropov , N. E. Zein

We test Laplacian-level meta-generalized gradient approximation (meta-GGA) non-interacting kinetic energy functionals based on the fourth-order gradient expansion (GE4). We consider several well known Laplacian-level meta-GGAs from…

Chemical Physics · Physics 2014-03-19 S. Laricchia , L. A. Constantin , E. Fabiano , F. Della Sala

Density functional calculations on atoms are often used for determining accurate initial guesses as well as generating various types of pseudopotential approximations and efficient atomic-orbital basis sets for polyatomic calculations. To…

Computational Physics · Physics 2023-10-30 Susi Lehtola

The semilocal meta generalized gradient approximation (MGGA) for the exchange-correlation functional of Kohn-Sham (KS) density functional theory can yield accurate ground-state energies simultaneously for atoms, molecules, surfaces, and…

Chemical Physics · Physics 2012-05-04 Jianwei Sun , Bing Xiao , Adrienn Ruzsinszky

One of the standard generalized-gradient approximations (GGAs) in use in modern electronic-structure theory, PBE, and a recently proposed modification designed specifically for solids, PBEsol, are identified as particular members of a…

Materials Science · Physics 2015-05-13 Luana S. Pedroza , Antonio J. R. da Silva , Klaus Capelle

Several recent studies have shown that SCAN, a functional belonging to the meta-generalized gradient approximation (MGGA) family, leads to significantly overestimated magnetic moments in itinerant ferromagnetic metals. However, this…

GW approximation is one of the most popular parameter-free many-body methods that goes beyond the limitations of the standard density functional theory (DFT) to determine the excitation spectra for moderately correlated materials and in…

Materials Science · Physics 2023-12-12 Kristjan Haule , Subhasish Mandal

We used our previously implemented GW approximation (GWA) based on the all-electron full-potential projector augmented wave (PAW) method to study the optical properties of small, medium and large-band-gap semiconductors: Si, GaAs, AlAs,…

Materials Science · Physics 2016-08-31 B. Arnaud , M. Alouani

Semilocal density functionals for the exchange-correlation energy are needed for large electronic systems. The Tao-Perdew-Staroverov-Scuseria (TPSS) meta-generalized gradient approximation (meta-GGA) is semilocal and usefully accurate, but…

Materials Science · Physics 2009-06-30 John P. Perdew , Adrienn Ruzsinszky , Gabor I. Csonka , Lucian A. Constantin , Jianwei Sun
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